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Tuning the Dimensions of C60‐Based Needlelike Crystals in Blended Thin Films

Swinnen, A., Haeldermans, I., vande Ven, M., D'Haen, J., Vanhoyland, G., Aresu, S., D'Olieslaeger, M., Manca, J.·2006·Advanced Functional Materials

Abstract

A new ordered structure of the C 60 derivative PCBM ([6‐6]‐phenyl C 61‐butyric acid methyl ester) is obtained in thin films based on the blend PCBM:regioregular P3HT (poly(3‐hexylthiophene)). Rapid formation of needlelike crystalline PCBM structures of a few micrometers up to 100 μm in size is demonstrated by submitting the blended thin films to an appropriate thermal treatment. These structures can grow out to a 2D network of PCBM needles and, in specific cases, to spectacular PCBM fans. Key parameters to tune the dimensions and spatial distribution of the PCBM needles are blend ratio and annealing conditions. The as‐obtained blended films and crystals are probed using atomic force microscopy, transmission electron microscopy, selected area electron diffraction, optical microscopy, and confocal fluorescence microscopy. Based on the analytical results, the growth mechanism of the PCBM structures within the film is described in terms of diffusion of PCBM towards the PCBM crystals, leaving highly crystalline P3HT behind in the surrounding matrix.

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Metadata

Authors
Swinnen, A., Haeldermans, I., vande Ven, M., D'Haen, J., Vanhoyland, G., Aresu, S., D'Olieslaeger, M., & Manca, J.
Venue
Advanced Functional Materials
Publisher
Wiley
Published
2006-02-21
Volume
16
Issue
6
Pages
760-765
ISSN
  • 1616-301X (ISSN-L)
  • 1616-3028
OpenAlex
W2120120657
Cited by
205
References
0
FWCI
11.47
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Tuning the Dimensions of C60‐Based Needlelike Crystals in Blended Thin Films. https://app.cochat.ai/papers/10.1002/adfm.200500812
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Swinnen, A., Haeldermans, I., vande Ven, M., D'Haen, J., Vanhoyland, G., Aresu, S., D'Olieslaeger, M., & Manca, J. (2006). Tuning the Dimensions of C60‐Based Needlelike Crystals in Blended Thin Films. Advanced Functional Materials. https://doi.org/10.1002/adfm.200500812

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