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Microporous Metal–Organic Frameworks with High Gas Sorption and Separation Capacity
Abstract
The design, synthesis, and structural characterization of two microporous metal–organic framework structures, [M(bdc)(ted)0.5]·2 DMF·0.2 H 2 O (M = Zn (1), Cu (2); H 2 bdc = 1,4‐benzenedicarboxylic acid; ted = triethylenediamine; DMF: N,N‐dimethylformamide) is reported. The pore characteristics and gas sorption properties of these compounds are investigated at cryogenic temperatures, room temperature, and higher temperatures by experimentally measuring argon, hydrogen, and selected hydrocarbon adsorption/desorption isotherms. These studies show that both compounds are highly porous with a pore volume of 0.65 (1) and 0.52 cm 3 g– 1 (2). The amount of the hydrogen uptake, 2.1 wt % (1) and 1.8 wt % (2) at 77 K (1 atm; 1 atm = 101 325 Pa), places them among the group of metal–organic frameworks (MOFs) having the highest H 2 sorption capacity. [Zn(bdc)(ted)0.5]·2 DMF·0.2 H 2 O adsorbs a very large amount of hydrocarbons, including methanol, ethanol, dimethylether (DME), n‐hexane, cyclohexane, and benzene, giving the highest sorption values among all metal–organic based porous materials reported to date. In addition, these materials hold great promise for gas separation.
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Sing, K. S. W. (1985) · Pure and Applied Chemistry · doi:10.1351/pac198557040603 · Cited by 24,485
Cited by
Metal–Organic Frameworks for Separations
Li, J.-R., Sculley, J., & Zhou, H.-C. (2012) · Chemical Reviews · doi:10.1021/cr200190s · Cited by 6,323
Self-citationHydrogen storage in metal–organic frameworks
Murray, L. J., Dincă, M., & Long, J. R. (2009) · Chemical Society Reviews · doi:10.1039/b802256a · Cited by 4,532
Water Stability and Adsorption in Metal–Organic Frameworks
Burtch, N. C., Jasuja, H., & Walton, K. S. (2014) · Chemical Reviews · doi:10.1021/cr5002589 · Cited by 2,730
Lan, A., Li, K., Wu, H., Olson, D. H., Emge, T. J., Ki, W., Hong, M., & Li, J. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200804853 · Cited by 1,237
Self-citationZhang, J.-P., & Chen, X.-M. (2008) · Journal of the American Chemical Society · doi:10.1021/ja800550a · Cited by 502
Metadata
- Authors
- Lee, J. Y., Olson, D. H., Pan, L., Emge, T. J., & Li, J.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2007-04-03
- Volume
- 17
- Issue
- 8
- Pages
- 1255-1262
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W2076106456
- Cited by
- 341
- References
- 1
- FWCI
- 21.02
- Type
- journal article
- Language
- en
- Open access
- closed
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- Lee, J. Y., Olson, D. H., Pan, L., Emge, T. J., & Li, J. (2007). Microporous Metal–Organic Frameworks with High Gas Sorption and Separation Capacity. Advanced Functional Materials. https://doi.org/10.1002/adfm.200600944
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