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A Self‐Healing Poly(Dimethyl Siloxane) Elastomer
Abstract
Self‐healing functionality is imparted to a poly(dimethyl siloxane) (PDMS) elastomer. This new material is produced by the incorporation of a microencapsulated PDMS resin and a microencapsulated crosslinker into the PDMS matrix. A protocol based on the recovery of tear strength is introduced to assess the healing efficiency for these compliant polymers. While most PDMS elastomers possess some ability to re‐mend through surface cohesion, the mechanism is generally insufficient to produce significant recovery of initial material strength under ambient conditions. Self‐healing PDMS specimens, however, routinely recover between 70–100 % of the original tear strength. Moreover, the addition of microcapsules increases the tear strength of the PDMS. The effect of microcapsule concentration on healing efficiency is also investigated.
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Cited by
Self-Healing Polymers and Composites
Blaiszik, B. J., Kramer, S. L. B., Olugebefola, S. C., Moore, J. S., Sottos, N. R., & White, S. R. (2010) · Annual Review of Materials Research · doi:10.1146/annurev-matsci-070909-104532 · Cited by 1,505
Self-citationApproaches to Sustainable and Continually Recyclable Cross-Linked Polymers
Fortman, D. J., Brutman, J. P., De Hoe, G. X., Snyder, R. L., Dichtel, W. R., & Hillmyer, M. A. (2018) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.8b02355 · Cited by 559
Self-Healing Polymeric Materials Using Epoxy/Mercaptan as the Healant
Yuan, Y. C., Rong, M. Z., Zhang, M. Q., Chen, J., Yang, G. C., & Li, X. M. (2008) · Macromolecules · doi:10.1021/ma800028d · Cited by 444
Linear/Network Poly(ε-caprolactone) Blends Exhibiting Shape Memory Assisted Self-Healing (SMASH)
Rodriguez, E. D., Luo, X., & Mather, P. T. (2011) · ACS Applied Materials & Interfaces · doi:10.1021/am101012c · Cited by 381
Huang, L., Yi, N., Wu, Y., Zhang, Y., Zhang, Q., Huang, Y., Ma, Y., & Chen, Y. (2013) · Advanced Materials · doi:10.1002/adma.201204768 · Cited by 329
Metadata
- Authors
- Keller, M. W., White, S. R., & Sottos, N. R.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2007-08-17
- Volume
- 17
- Issue
- 14
- Pages
- 2399-2404
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W2055040487
- Cited by
- 419
- References
- 0
- FWCI
- 13.35
- Type
- journal article
- Language
- en
- Open access
- closed
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- Keller, M. W., White, S. R., & Sottos, N. R. (2007). A Self‐Healing Poly(Dimethyl Siloxane) Elastomer. Advanced Functional Materials. https://doi.org/10.1002/adfm.200700086
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