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Structure and Electrochemical Performance of Carbide‐Derived Carbon Nanopowders

Open access
Pérez, Carlos R., Yeon, Sun‐Hwa, Ségalini, Julie, Presser, Volker, Taberna, Pierre‐Louis, Simon, Patrice, Gogotsi, Yury·2013·Advanced Functional Materials

Abstract

Microporous carbon materials are widely used in gas storage, sorbents, supercapacitor electrodes, water desalination, and catalyst supports. While these microporous carbons usually have a particle size in the 1–100 μm range, here the synthesis of porous carbide‐derived carbon (CDC) with particle diameters around 30 nm by extraction of titanium from nanometer‐sized titanium carbide (TiC) powder at temperatures of 200 °C and above is reported. Nanometer‐sized CDCs prepared at 200–400 °C show a disordered structure and the presence of CN sp 1 bonds. Above 400 °C, the CN bond disappears with the structure transition to disordered carbon similar to that observed after synthesis from carbide micropowders. Compared to CDCs produced from micrometer‐sized TiC, nano‐CDC has a broader pore size distribution due to interparticle porosity and a large contribution from the surface layers. The material shows excellent electrochemical performance due to its easily accessible pores and a large specific surface area.

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Metadata

Authors
Pérez, C. R., Yeon, S., Ségalini, J., Presser, V., Taberna, P., Simon, P., & Gogotsi, Y.
Venue
Advanced Functional Materials
Publisher
Wiley
Published
2012-07-06
Volume
23
Issue
8
Pages
1081-1089
ISSN
  • 1616-301X (ISSN-L)
  • 1616-3028
OpenAlex
W1971649542
Cited by
182
References
3
FWCI
7.89
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Structure and Electrochemical Performance of Carbide‐Derived Carbon Nanopowders. https://app.cochat.ai/papers/10.1002/adfm.201200695
The paper
Pérez, C. R., Yeon, S., Ségalini, J., Presser, V., Taberna, P., Simon, P., & Gogotsi, Y. (2013). Structure and Electrochemical Performance of Carbide‐Derived Carbon Nanopowders. Advanced Functional Materials. https://doi.org/10.1002/adfm.201200695

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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