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Cited by 1,006

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From Black Phosphorus to Phosphorene: Basic Solvent Exfoliation, Evolution of Raman Scattering, and Applications to Ultrafast Photonics

Guo, Zhinan, Zhang, Han, Lu, Shunbin, Wang, Zhiteng, Tang, Siying, Shao, Jundong, Sun, Zhengbo, Xie, Hanhan, Wang, Huaiyu, Yu, Xue‐Feng, Chu, Paul K.·2015·Advanced Functional Materials

Abstract

Although phosphorene has attracted much attention in electronics and optoelectronics as a new type of two‐dimensional material, in‐depth investigations and applications have been limited by the current synthesis techniques. Herein, a basic N‐methyl‐2‐pyrrolidone (NMP) liquid exfoliation method is described to produce phosphorene with excellent water stability, controllable size and layer number, as well as in high yield. Phosphorene samples composed of one to four layers exhibit layer‐dependent Raman scattering characteristics thus providing a fast and efficient means for the in situ determination of the thickness (layer number) of phosphorene. The linear and nonlinear ultrafast absorption behavior of the as‐exfoliated phosphorene is investigated systematically by UV–vis–NIR absorption and Z‐scan measurements. By taking advantage of their unique nonlinear absorption, ultrashort pulse generation applicable to optical saturable absorbers is demonstrated. In addition to a unique fabrication technique, our work also reveals the large potential of phosphorene in ultrafast photonics.

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Metadata

Authors
Guo, Z., Zhang, H., Lu, S., Wang, Z., Tang, S., Shao, J., Sun, Z., Xie, H., Wang, H., Yu, X., & Chu, P. K.
Venue
Advanced Functional Materials
Publisher
Wiley
Published
2015-10-21
Volume
25
Issue
45
Pages
6996-7002
ISSN
  • 1616-301X (ISSN-L)
  • 1616-3028
OpenAlex
W1764528596
Cited by
1,006
References
6
FWCI
37.30
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: From Black Phosphorus to Phosphorene: Basic Solvent Exfoliation, Evolution of Raman Scattering, and Applications to Ultrafast Photonics. https://app.cochat.ai/papers/10.1002/adfm.201502902
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Guo, Z., Zhang, H., Lu, S., Wang, Z., Tang, S., Shao, J., Sun, Z., Xie, H., Wang, H., Yu, X., & Chu, P. K. (2015). From Black Phosphorus to Phosphorene: Basic Solvent Exfoliation, Evolution of Raman Scattering, and Applications to Ultrafast Photonics. Advanced Functional Materials. https://doi.org/10.1002/adfm.201502902

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