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A Self‐Standing High‐Performance Hydrogen Evolution Electrode with Nanostructured NiCo2O4/CuS Heterostructures

An, Li, Huang, Liang, Zhou, Panpan, Yin, Jie, Liu, Hongyan, Xi, Pinxian·2015·Advanced Functional Materials

Abstract

An efficient self‐standing 3D hydrogen evolution cathode has been developed by coating nickel cobaltite (NiCo 2 O 4)/CuS nanowire heterostructures on a carbon fiber paper (CFP). The obtained CFP/NiCo 2 O 4/CuS electrode shows exceptional hydrogen evolution reaction (HER) performance and excellent durability in acidic conditions. Remarkably, as an integrated 3D hydrogen‐evolving cathode operating in acidic electrolytes, CFP/NiCo 2 O 4/CuS maintains its activity more than 50 h and exhibits an onset overpotential of 31.1 mV, an exchange current density of 0.246 mA cm−2, and a Tafel slope of 41 mV dec−1. Compared to other non‐Pt electrocatalysts reported to date, CFP/NiCo 2 O 4/CuS exhibits the highest HER activity and can be used in HER to produce H 2 with nearly quantitative faradaic yield in acidic aqueous media with stable activity. Furthermore, by using CFP/NiCo 2 O 4/CuS as a self‐standing electrode in a water electrolyzer, a current density of 18 mA cm−2 can be achieved at a voltage of 1.5 V which can be driven by a single‐cell battery. This strategy provides an effective, durable, and non‐Pt electrode for water splitting and hydrogen generation.

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Metadata

Authors
An, L., Huang, L., Zhou, P., Yin, J., Liu, H., & Xi, P.
Venue
Advanced Functional Materials
Publisher
Wiley
Published
2015-10-07
Volume
25
Issue
43
Pages
6814-6822
ISSN
  • 1616-301X (ISSN-L)
  • 1616-3028
OpenAlex
W1887176141
Cited by
244
References
21
FWCI
7.33
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: A Self‐Standing High‐Performance Hydrogen Evolution Electrode with Nanostructured NiCo2O4/CuS Heterostructures. https://app.cochat.ai/papers/10.1002/adfm.201503784
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An, L., Huang, L., Zhou, P., Yin, J., Liu, H., & Xi, P. (2015). A Self‐Standing High‐Performance Hydrogen Evolution Electrode with Nanostructured NiCo2O4/CuS Heterostructures. Advanced Functional Materials. https://doi.org/10.1002/adfm.201503784

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