Self-Supported Nanoporous Cobalt Phosphide Nanowire Arrays: An Efficient 3D Hydrogen-Evolving Cathode over the Wide Range of pH 0–14

Tian, Jingqi; Liu, Qian; Asiri, Abdullah M.; Sun, Xuping

doi:10.1021/ja503372r

Cited by 2,373Electrocatalysts for Energy ConversionCO2 Reduction Techniques and CatalystsHydrogen Storage and Materials

Self-Supported Nanoporous Cobalt Phosphide Nanowire Arrays: An Efficient 3D Hydrogen-Evolving Cathode over the Wide Range of pH 0–14

Tian, Jingqi, Liu, Qian, Asiri, Abdullah M., Sun, Xuping·2014·Journal of the American Chemical Society

DOI 10.1021/ja503372r

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Abstract

In this Communication, we report the topotactic fabrication of self-supported nanoporous cobalt phosphide nanowire arrays on carbon cloth (CoP/CC) via low-temperature phosphidation of the corresponding Co(OH)F/CC precursor. The CoP/CC, as a robust integrated 3D hydrogen-evolving cathode, shows a low onset overpotential of 38 mV and a small Tafel slope of 51 mV dec(-1), and it maintains its catalytic activity for at least 80,00 s in acidic media. It needs overpotentials (η) of 67, 100, and 204 mV to attain current densities of 10, 20, and 100 mA cm(-2), respectively. Additionally, this electrode offers excellent catalytic performance and durability under neutral and basic conditions.

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The improved electrocatalytic kinetics for the HER mechanism of PCN1@800 nanoparticles follow the Volmer-Heyrovsky pathway.
“Those results indicated improved electrocatalytic kinetics for the HER mechanism of PCN1@800 nanoparticles followed the Volmer-Heyrovesky pathway [29].”
From Unveiling N-doped carbon nitride aerogel for efficient electrocatalytic water splitting application (2025) · cites this paper as [29]
Noble metal oxides (IrO2 and RuO2) are state-of-the-art electrocatalysts for OER but not good for HER.
“Similarly, noble metal oxides (IrO2 and RuO2) are state-of-the-art electrocatalysts for OER but not good for HER.7”
From Electronic Structure Tuning in Ni3FeN/r-GO Aerogel toward Bifunctional Electrocatalyst for Overall Water Splitting (2018) · cites this paper as [7]
Platinum (Pt)-based catalysts exhibit high performance for HER but only moderate activity for OER.
“Platinum (Pt)-based catalysts exhibit high-performance for HER but only moderate activity for OER.”
From Electronic Structure Tuning in Ni3FeN/r-GO Aerogel toward Bifunctional Electrocatalyst for Overall Water Splitting (2018) · cites this paper as [7]

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Authors: Tian, J., Liu, Q., Asiri, A. M., & Sun, X.
Affiliations: Chinese Academy of Sciences (CN)
King Abdulaziz University (SA)
Corresponding author: Sun, Xuping
ORCID: Tian, Jingqi
Liu, Qian
Asiri, Abdullah M.
Sun, Xuping
Venue: Journal of the American Chemical Society
Publisher: American Chemical Society (ACS)
Published: 2014-05-15
Volume: 136
Issue: 21
Pages: 7587-7590
ISSN: 0002-7863 (ISSN-L)
1520-5126
DOI: 10.1021/ja503372r
OpenAlex: W2334952434
Cited by: 2,373
References: 48
Citations by year: 2026: 53 · 2025: 94 · 2024: 121 · 2023: 127 · 2022: 156 · 2021: 185 · 2020: 248 · 2019: 300 · 2018: 345 · 2017: 314 · 2016: 242 · 2015: 137 · 2014: 50
FWCI: 81.70
Type: journal article
Language: en
Open access: closed
Locations: Journal of the American Chemical Society (publishedVersion)
PubMed (publishedVersion)
Funders: National Natural Science Foundation of China (21175129)
Ministry of Science and Technology of the People's Republic of China (2011CB935800)
Topics: Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
Physical Sciences › Materials Science › Materials Chemistry › Hydrogen Storage and Materials
Keywords: cobalt phosphide, nanowire arrays, hydrogen evolution reaction, electrocatalysis, binder-free electrodes, carbon cloth, pH tolerance, three-dimensional electrodes, overpotential

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Self-Supported Nanoporous Cobalt Phosphide Nanowire Arrays: An Efficient 3D Hydrogen-Evolving Cathode over the Wide Range of pH 0–14

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