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Cited by 280

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Full‐Color Delayed Fluorescence Materials Based on Wedge‐Shaped Phthalonitriles and Dicyanopyrazines: Systematic Design, Tunable Photophysical Properties, and OLED Performance

Park, In Seob, Lee, Sae Youn, Adachi, Chihaya, Yasuda, Takuma·2016·Advanced Functional Materials

Abstract

Purely organic light‐emitting materials, which can harvest both singlet and triplet excited states to offer high electron‐to‐photon conversion efficiencies, are essential for the realization of high‐performance organic light‐emitting diodes (OLEDs) without using precious metal elements. Donor–acceptor architectures with an intramolecular charge‐transfer excited state have been proved to be a promising system for achieving these requirements through a mechanism of thermally activated delayed fluorescence (TADF). Here, luminescent wedge‐shaped molecules, which comprise a central phthalonitrile or 2,3‐dicyanopyrazine acceptor core coupled with various donor units, are reported as TADF emitters. This set of materials allows systematic fine‐tuning of the band gap and exhibits TADF emissions that cover the entire visible range from blue to red. Full‐color TADF‐OLEDs with high maximum external electroluminescence quantum efficiencies of up to 18.9% have been demonstrated by using these phthalonitrile and 2,3‐dicyanopyrazine‐based TADF emitters.

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Metadata

Authors
Park, I. S., Lee, S. Y., Adachi, C., & Yasuda, T.
Venue
Advanced Functional Materials
Publisher
Wiley
Published
2016-02-12
Volume
26
Issue
11
Pages
1813-1821
ISSN
  • 1616-301X (ISSN-L)
  • 1616-3028
OpenAlex
W2272746360
Cited by
280
References
1
FWCI
22.26
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Full‐Color Delayed Fluorescence Materials Based on Wedge‐Shaped Phthalonitriles and Dicyanopyrazines: Systematic Design, Tunable Photophysical Properties, and OLED Performance. https://app.cochat.ai/papers/10.1002/adfm.201505106
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Park, I. S., Lee, S. Y., Adachi, C., & Yasuda, T. (2016). Full‐Color Delayed Fluorescence Materials Based on Wedge‐Shaped Phthalonitriles and Dicyanopyrazines: Systematic Design, Tunable Photophysical Properties, and OLED Performance. Advanced Functional Materials. https://doi.org/10.1002/adfm.201505106

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