Recent advances in organic thermally activated delayed fluorescence materials

Organic electroluminescent diodes

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Aggregation-Induced Emission: Together We Shine, United We Soar!

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Highly efficient organic light-emitting diodes from delayed fluorescence

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Molecular Fluorescence

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Efficient blue organic light-emitting diodes employing thermally activated delayed fluorescence

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Ultrapure Blue Thermally Activated Delayed Fluorescence Molecules: Efficient HOMO–LUMO Separation by the Multiple Resonance Effect

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Reversible, Metal-Free Hydrogen Activation

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Thermally Activated Delayed Fluorescence Materials Towards the Breakthrough of Organoelectronics

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Organic light-emitting diodes employing efficient reverse intersystem crossing for triplet-to-singlet state conversion

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Electron Transport Materials for Organic Light-Emitting Diodes

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Convergent Dendrons and Dendrimers: from Synthesis to Applications

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Design of Efficient Thermally Activated Delayed Fluorescence Materials for Pure Blue Organic Light Emitting Diodes

Zhang, Q., Li, J., Shizu, K., Huang, S., Hirata, S., Miyazaki, H., & Adachi, C. (2012) · Journal of the American Chemical Society · doi:10.1021/ja306538w · Cited by 1,609 · see citing works

The theory of impurity conduction

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Highly efficient blue electroluminescence based on thermally activated delayed fluorescence

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High-efficiency organic light-emitting diodes with fluorescent emitters

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Efficient up-conversion of triplet excitons into a singlet state and its application for organic light emitting diodes

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Recent Development of Chemosensors Based on Cyanine Platforms

Sun, W. C., Guo, S., Hu, C., Fan, J., & Peng, X. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00001 · Cited by 1,112 · see citing works

Sky‐Blue Organic Light Emitting Diode with 37% External Quantum Efficiency Using Thermally Activated Delayed Fluorescence from Spiroacridine‐Triazine Hybrid

Lin, T., Chatterjee, T., Tsai, W., Lee, W., Wu, M. C., Jiao, M., Pan, K., Yi, C., Chung, C., Wong, K., et al. (2016) · Advanced Materials · doi:10.1002/adma.201601675 · Cited by 1,031 · see citing works

Triplet Harvesting with 100% Efficiency by Way of Thermally Activated Delayed Fluorescence in Charge Transfer OLED Emitters

Dias, F. B., Bourdakos, K. N., Jankus, V., Moss, K. C., Kamtekar, K. T., Bhalla, V., Santos, J., Bryce, M. R., & Monkman, A. P. (2013) · Advanced Materials · doi:10.1002/adma.201300753 · Cited by 1,005 · see citing works

Purely organic electroluminescent material realizing 100% conversion from electricity to light

Kaji, H., Suzuki, H., Fukushima, T., Shizu, K., Suzuki, K., Kubo, S., Komino, T., Oiwa, H., Suzuki, F., Wakamiya, A., et al. (2015) · Nature Communications · doi:10.1038/ncomms9476 · Cited by 994 · see citing works

Anthraquinone-Based Intramolecular Charge-Transfer Compounds: Computational Molecular Design, Thermally Activated Delayed Fluorescence, and Highly Efficient Red Electroluminescence

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Crystallization-Induced Phosphorescence of Pure Organic Luminogens at Room Temperature

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Thermally Activated Delayed Fluorescence from Sn 4+ –Porphyrin Complexes and Their Application to Organic Light Emitting Diodes — A Novel Mechanism for Electroluminescence

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A Twisting Donor‐Acceptor Molecule with an Intercrossed Excited State for Highly Efficient, Deep‐Blue Electroluminescence

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Dicarba-closo-dodecaboranes C2B10H12 and their derivatives

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The Importance of Vibronic Coupling for Efficient Reverse Intersystem Crossing in Thermally Activated Delayed Fluorescence Molecules

Gibson, J., Monkman, A. P., & Penfold, T. J. (2016) · ChemPhysChem · doi:10.1002/cphc.201600662 · Cited by 727 · see citing works

Employing ∼100% Excitons in OLEDs by Utilizing a Fluorescent Molecule with Hybridized Local and Charge‐Transfer Excited State

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Modern Molecular Photochemistry of Organic Molecules

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High‐Efficiency Fluorescent Organic Light‐Emitting Devices Using Sensitizing Hosts with a Small Singlet–Triplet Exchange Energy

Zhang, D., Duan, L., Li, C., et al. (2014) · Advanced Materials · doi:10.1002/adma.201401476 · Cited by 668 · see citing works

Efficient green thermally activated delayed fluorescence (TADF) from a phenoxazine–triphenyltriazine (PXZ–TRZ) derivative

Tanaka, H., Shizu, K., Miyazaki, H., & Adachi, C. (2012) · Chemical Communications · doi:10.1039/c2cc36237f · Cited by 654 · see citing works

Organic Materials for Deep Blue Phosphorescent Organic Light‐Emitting Diodes

Yook, K. S., & Lee, J. Y. (2012) · Advanced Materials · doi:10.1002/adma.201200627 · Cited by 638 · see citing works

Solution processable small molecules for organic light-emitting diodes

Duan, L., Hou, L., Lee, T., et al. (2010) · Journal of Materials Chemistry · doi:10.1039/b926348a · Cited by 614 · see citing works

Highly Efficient Near‐Infrared Delayed Fluorescence Organic Light Emitting Diodes Using a Phenanthrene‐Based Charge‐Transfer Compound

Wang, S., Yan, X., Cheng, Z., Zhang, H., Liu, Y., & Wang, Y. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201506687 · Cited by 607 · see citing works

Impact of Donor−Acceptor Geometry and Metal Chelation on Photophysical Properties and Applications of Triarylboranes

Hudson, Z. M., & Wang, S. (2009) · Accounts of Chemical Research · doi:10.1021/ar900072u · Cited by 603 · see citing works

Enhanced Electroluminescence Efficiency in a Spiro‐Acridine Derivative through Thermally Activated Delayed Fluorescence

Méhes, G., Nomura, H., Zhang, Q., Nakagawa, T., & Adachi, C. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201206289 · Cited by 586 · see citing works

Nearly 100% Internal Quantum Efficiency in Undoped Electroluminescent Devices Employing Pure Organic Emitters

Zhang, Q., Tsang, D. P., Kuwabara, H., Hatae, Y., Li, B., Takahashi, T., Lee, S. Y., Yasuda, T., & Adachi, C. (2015) · Advanced Materials · doi:10.1002/adma.201405474 · Cited by 580 · see citing works

Organic Light‐Emitting Diodes with 30% External Quantum Efficiency Based on a Horizontally Oriented Emitter

Kim, S.-Y., Jeong, W., Mayr, C., et al. (2013) · Advanced Functional Materials · doi:10.1002/adfm.201300104 · Cited by 575 · see citing works

Analysis of exciton annihilation in high-efficiency sky-blue organic light-emitting diodes with thermally activated delayed fluorescence

Masui, K., Nakanotani, H., & Adachi, C. (2013) · Organic Electronics · doi:10.1016/j.orgel.2013.07.010 · Cited by 568 · see citing works

A Highly Efficient Universal Bipolar Host for Blue, Green, and Red Phosphorescent OLEDs

Chou, H., & Cheng, C. (2010) · Advanced Materials · doi:10.1002/adma.201000061 · Cited by 560 · see citing works

Organic electroluminescent device having a hole conductor as an emitting layer

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Sterically shielded blue thermally activated delayed fluorescence emitters with improved efficiency and stability

Zhang, D., Cai, M., Zhang, Y., Zhang, D., & Duan, L. (2016) · Materials Horizons · doi:10.1039/c5mh00258c · Cited by 552 · see citing works

Third-generation organic electroluminescence materials

Adachi, C. (2014) · Japanese Journal of Applied Physics · doi:10.7567/jjap.53.060101 · Cited by 547 · see citing works

Novel Thermally Activated Delayed Fluorescence Materials–Thioxanthone Derivatives and Their Applications for Highly Efficient OLEDs

Wang, H., Xie, L., Peng, Q., Meng, L., Wang, Y., Yi, Y., & Wang, P. (2014) · Advanced Materials · doi:10.1002/adma.201401393 · Cited by 544 · see citing works

Luminous Butterflies: Efficient Exciton Harvesting by Benzophenone Derivatives for Full‐Color Delayed Fluorescence OLEDs

Lee, S. Y., Yasuda, T., Yang, Y. S., Zhang, Q., & Adachi, C. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201402992 · Cited by 541 · see citing works

Fluoride Ion Recognition by Chelating and Cationic Boranes

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E-Type Delayed Fluorescence of a Phosphine-Supported Cu 2 (μ-NAr 2 ) 2 Diamond Core: Harvesting Singlet and Triplet Excitons in OLEDs

Deaton, J. C., Switalski, S. C., Kondakov, D. Y., Young, R. H., Pawlik, T. D., Giesen, D. J., Harkins, S. B., Miller, A. J. M., Mickenberg, S. F., & Peters, J. C. (2010) · Journal of the American Chemical Society · doi:10.1021/ja1004575 · Cited by 500 · see citing works

Highly Efficient Organic Light‐Emitting Diode Based on a Hidden Thermally Activated Delayed Fluorescence Channel in a Heptazine Derivative

Li, J., Nakagawa, T., MacDonald, J., Zhang, Q., Nomura, H., Miyazaki, H., & Adachi, C. (2013) · Advanced Materials · doi:10.1002/adma.201300575 · Cited by 500 · see citing works

One‐Step Borylation of 1,3‐Diaryloxybenzenes Towards Efficient Materials for Organic Light‐Emitting Diodes

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Electronic Processes in Organic Semiconductors

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White‐Light Emission Strategy of a Single Organic Compound with Aggregation‐Induced Emission and Delayed Fluorescence Properties

Xie, Z., Chen, C., Xu, S., Li, J., Zhang, Y., Liu, S., Xu, J., & Chi, Z. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201502180 · Cited by 489 · see citing works

Exciplex‐Forming Co‐host for Organic Light‐Emitting Diodes with Ultimate Efficiency

Park, Y., Lee, S., Kim, K., et al. (2013) · Advanced Functional Materials · doi:10.1002/adfm.201300547 · Cited by 488 · see citing works

A Hybridized Local and Charge‐Transfer Excited State for Highly Efficient Fluorescent OLEDs: Molecular Design, Spectral Character, and Full Exciton Utilization

Li, W., Pan, Y., Yao, L., et al. (2014) · Advanced Optical Materials · doi:10.1002/adom.201400154 · Cited by 479 · see citing works

Triplet-singlet emission in fluid solutions. Phosphorescence of eosin

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Aggregation‐Induced Delayed Fluorescence Based on Donor/Acceptor‐Tethered Janus Carborane Triads: Unique Photophysical Properties of Nondoped OLEDs

Furue, R., Nishimoto, T., Park, I. S., Lee, J.-Y., & Yasuda, T. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201603232 · Cited by 465 · see citing works

Triplet Harvesting in Hybrid White Organic Light‐Emitting Diodes

Schwartz, G., Reineke, S., Rosenow, T. C., Walzer, K., & Leo, K. (2009) · Advanced Functional Materials · doi:10.1002/adfm.200801503 · Cited by 461 · see citing works

Electroluminescence based on thermally activated delayed fluorescence generated by a spirobifluorene donor–acceptor structure

Nakagawa, T., Ku, S.-Y., Wong, K., & Adachi, C. (2012) · Chemical Communications · doi:10.1039/c2cc31468a · Cited by 456 · see citing works

A Fluorescent Organic Light‐Emitting Diode with 30% External Quantum Efficiency

Sun, J. W., Lee, J., Moon, C., et al. (2014) · Advanced Materials · doi:10.1002/adma.201401407 · Cited by 444 · see citing works

Fluorescent probes for bioimaging applications

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Progress and perspective of polymer white light-emitting devices and materials

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An Organic Molecule with Asymmetric Structure Exhibiting Aggregation‐Induced Emission, Delayed Fluorescence, and Mechanoluminescence

Xu, S., Liu, T., Mu, Y., Wang, Y., Chi, Z., Lo, C., Liu, S., Zhang, Y., Lien, A., & Xu, J. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201409767 · Cited by 419 · see citing works

External Quantum Efficiency Above 20% in Deep Blue Phosphorescent Organic Light‐Emitting Diodes

Jeon, S. O., Jang, S. E., Son, H. S., et al. (2011) · Advanced Materials · doi:10.1002/adma.201004372 · Cited by 412 · see citing works

Stable Blue Thermally Activated Delayed Fluorescent Organic Light‐Emitting Diodes with Three Times Longer Lifetime than Phosphorescent Organic Light‐Emitting Diodes

Kim, M., Jeon, S. K., Hwang, S., & Lee, J. Y. (2015) · Advanced Materials · doi:10.1002/adma.201500267 · Cited by 404 · see citing works

A New Molecular Design Based on Thermally Activated Delayed Fluorescence for Highly Efficient Organic Light Emitting Diodes

Rajamalli, P., Senthilkumar, N., Gandeepan, P., Huang, P.-Y., Huang, M., Ren‐Wu, C., Yang, C.-Y., Chiu, M.-J., Chu, L., Lin, H., et al. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b10950 · Cited by 404 · see citing works

Thermally Activated Delayed Fluorescence Materials Based on Homoconjugation Effect of Donor–Acceptor Triptycenes

Kawasumi, K., Wu, T., Zhu, T., et al. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b07932 · Cited by 391 · see citing works

Design and Synthesis of New Circularly Polarized Thermally Activated Delayed Fluorescence Emitters

Feuillastre, S., Pauton, M., Gao, L., et al. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b00850 · Cited by 375 · see citing works

High-efficiency organic light-emitting diodes utilizing thermally activated delayed fluorescence from triazine-based donor–acceptor hybrid molecules

Lee, S. Y., Yasuda, T., Nomura, H., & Adachi, C. (2012) · Applied Physics Letters · doi:10.1063/1.4749285 · Cited by 365 · see citing works

Dibenzo[ a,j ]phenazine‐Cored Donor–Acceptor–Donor Compounds as Green‐to‐Red/NIR Thermally Activated Delayed Fluorescence Organic Light Emitters

Data, P., Pander, P., Okazaki, M., Takeda, Y., Minakata, S., & Monkman, A. P. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201600113 · Cited by 364 · see citing works

A versatile thermally activated delayed fluorescence emitter for both highly efficient doped and non-doped organic light emitting devices

Tsai, W., Huang, M.-H., Lee, W., Hsu, Y.-J., Pan, K., Huang, Y., Ting, H., Sarma, M., Ho, Y., Hu, H., et al. (2015) · Chemical Communications · doi:10.1039/c5cc05022g · Cited by 358 · see citing works

Promising operational stability of high-efficiency organic light-emitting diodes based on thermally activated delayed fluorescence

Nakanotani, H., Masui, K., Nishide, J.-I., et al. (2013) · Scientific Reports · doi:10.1038/srep02127 · Cited by 352 · see citing works

Chemical Degradation in Organic Light‐Emitting Devices: Mechanisms and Implications for the Design of New Materials

Schmidbauer, S., Hohenleutner, A., & König, B. (2013) · Advanced Materials · doi:10.1002/adma.201205022 · Cited by 349 · see citing works

Prediction and Design of Efficient Exciplex Emitters for High‐Efficiency, Thermally Activated Delayed‐Fluorescence Organic Light‐Emitting Diodes

Liu, X., Chen, Z., Zheng, C., Liu, C.-L., Lee, C., Li, F., Ou, X., & Zhang, X. (2015) · Advanced Materials · doi:10.1002/adma.201405062 · Cited by 346 · see citing works

Highly Efficient Blue‐Emitting Cyclometalated Platinum(II) Complexes by Judicious Molecular Design

Hang, X., Fleetham, T. B., Turner, E., et al. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201302541 · Cited by 341 · see citing works

Photo-Triggered Click Chemistry for Biological Applications

Herner, A., & Lin, Q. (2015) · Topics in Current Chemistry · doi:10.1007/s41061-015-0002-2 · Cited by 339 · see citing works

Twisted Intramolecular Charge Transfer State for Long-Wavelength Thermally Activated Delayed Fluorescence

Tanaka, H., Shizu, K., Nakanotani, H., & Adachi, C. (2013) · Chemistry of Materials · doi:10.1021/cm402428a · Cited by 334 · see citing works

Oxadiazole- and triazole-based highly-efficient thermally activated delayed fluorescence emitters for organic light-emitting diodes

Lee, J., Shizu, K., Tanaka, H., Nomura, H., Yasuda, T., & Adachi, C. (2013) · Journal of Materials Chemistry C · doi:10.1039/c3tc30699b · Cited by 330 · see citing works

Thermally Activated Delayed Fluorescence of Fluorescein Derivative for Time-Resolved and Confocal Fluorescence Imaging

Xiong, X., Song, F., Wang, J., Zhang, Y., Xue, Y., Sun, L., Jiang, N., Gao, P., Tian, L., & Peng, X. (2014) · Journal of the American Chemical Society · doi:10.1021/ja502292p · Cited by 326 · see citing works

Efficient Polymer White‐Light‐Emitting Devices for Solid‐State Lighting

Wu, H., Zhou, G., Zou, J., et al. (2009) · Advanced Materials · doi:10.1002/adma.200900638 · Cited by 325 · see citing works

Carbazole Dendrimers as Solution‐Processable Thermally Activated Delayed‐Fluorescence Materials

Albrecht, K., Matsuoka, K., Fujita, K., & Yamamoto, K. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201500203 · Cited by 324 · see citing works

Dual Intramolecular Charge-Transfer Fluorescence Derived from a Phenothiazine-Triphenyltriazine Derivative

Tanaka, H., Shizu, K., Nakanotani, H., et al. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp501017f · Cited by 321 · see citing works

Evaporation‐ and Solution‐Process‐Feasible Highly Efficient Thianthrene‐9,9′,10,10′‐Tetraoxide‐Based Thermally Activated Delayed Fluorescence Emitters with Reduced Efficiency Roll‐Off

Xie, G., Li, X., Chen, D., Wang, Z., Cai, X., Chen, D., Li, Y., Liu, K., Cao, Y., & Su, S. (2015) · Advanced Materials · doi:10.1002/adma.201503225 · Cited by 318 · see citing works

Highly Efficient TADF OLEDs: How the Emitter–Host Interaction Controls Both the Excited State Species and Electrical Properties of the Devices to Achieve Near 100% Triplet Harvesting and High Efficiency

Jankus, V., Data, P., Graves, D., McGuinness, C., Santos, J., Bryce, M. R., Dias, F. B., & Monkman, A. P. (2014) · Advanced Functional Materials · doi:10.1002/adfm.201400948 · Cited by 317 · see citing works

Triarylboron‐Based Fluorescent Organic Light‐Emitting Diodes with External Quantum Efficiencies Exceeding 20 %

Suzuki, K., Kubo, S., Shizu, K., Fukushima, T., Wakamiya, A., Murata, Y., Adachi, C., & Kaji, H. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201508270 · Cited by 309 · see citing works

High efficiency pure blue thermally activated delayed fluorescence molecules having 10H-phenoxaborin and acridan units

Numata, M., Yasuda, T., & Adachi, C. (2015) · Chemical Communications · doi:10.1039/c5cc00307e · Cited by 304 · see citing works

High Efficiency in a Solution‐Processed Thermally Activated Delayed‐Fluorescence Device Using a Delayed‐Fluorescence Emitting Material with Improved Solubility

Cho, Y. J., Yook, K. S., & Lee, J. Y. (2014) · Advanced Materials · doi:10.1002/adma.201402188 · Cited by 301 · see citing works

Low power upconversion using MLCT sensitizers

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Rational Design of TADF Polymers Using a Donor–Acceptor Monomer with Enhanced TADF Efficiency Induced by the Energy Alignment of Charge Transfer and Local Triplet Excited States

Nobuyasu, R. S., Ren, Z., Griffiths, G. C., et al. (2016) · Advanced Optical Materials · doi:10.1002/adom.201500689 · Cited by 290 · see citing works

Efficient organic light-emitting diodes through up-conversion from triplet to singlet excited states of exciplexes

Goushi, K., & Adachi, C. (2012) · Applied Physics Letters · doi:10.1063/1.4737006 · Cited by 286 · see citing works

High-efficiency deep-blue organic light-emitting diodes based on a thermally activated delayed fluorescence emitter

Wu, S., Aonuma, M., Zhang, Q., et al. (2013) · Journal of Materials Chemistry C · doi:10.1039/c3tc31936a · Cited by 286 · see citing works

Thermally Activated Delayed Fluorescence Polymers for Efficient Solution‐Processed Organic Light‐Emitting Diodes

Lee, S. Y., Yasuda, T., Komiyama, H., Lee, J., & Adachi, C. (2016) · Advanced Materials · doi:10.1002/adma.201505026 · Cited by 286 · see citing works

Full‐Color Delayed Fluorescence Materials Based on Wedge‐Shaped Phthalonitriles and Dicyanopyrazines: Systematic Design, Tunable Photophysical Properties, and OLED Performance

Park, I. S., Lee, S. Y., Adachi, C., & Yasuda, T. (2016) · Advanced Functional Materials · doi:10.1002/adfm.201505106 · Cited by 280 · see citing works

Using Guest–Host Interactions To Optimize the Efficiency of TADF OLEDs

dos Santos, P. L., Ward, J. S., Bryce, M. R., et al. (2016) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b01542 · Cited by 277 · see citing works

Engineering of Mixed Host for High External Quantum Efficiency above 25% in Green Thermally Activated Delayed Fluorescence Device

Kim, B. S., & Lee, J. Y. (2014) · Advanced Functional Materials · doi:10.1002/adfm.201303730 · Cited by 269 · see citing works

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