The DOI matches its Crossref record; 74 of the 74 references it cites were found in a registry or an index.
Amorphous Cobalt–Iron Hydroxide Nanosheet Electrocatalyst for Efficient Electrochemical and Photo‐Electrochemical Oxygen Evolution
Abstract
Finding efficient electrocatalysts for oxygen evolution reaction (OER) that can be effectively integrated with semiconductors is significantly challenging for solar‐driven photo‐electrochemical (PEC) water splitting. Herein, amorphous cobalt–iron hydroxide (CoFeH) nanosheets are synthesized by facile electrodeposition as an efficient catalyst for both electrochemical and PEC water oxidation. As a result of the high electrochemically active surface area and the amorphous nature, the optimized amorphous CoFeH nanosheets exhibit superior OER catalytic activity in alkaline environment with a small overpotential (280 mV) to achieve significant oxygen evolution (j = 10 mA cm−2) and a low Tafel slope (28 mV dec−1). Furthermore, CoFeH nanosheets are simply integrated with BiVO 4 semiconductor to construct CoFeH/BiVO 4 photoanodes that exhibit a significantly enhanced photocurrent density of 2.48 mA cm−2 (at 1.23 V vs reversible hydrogen electrode (RHE)) and a much lower onset potential of 0.23 V (vs RHE) for PEC‐OER. Careful electrochemical and optical studies reveal that the improved OER kinetics and high‐quality interface at the CoFeH/BiVO 4 junction, as well as the excellent optical transparency of CoFeH nanosheets, contribute to the high PEC performance. This study establishes amorphous CoFeH nanosheets as a highly competitive candidate for electrochemical and PEC water oxidation and provides general guidelines for designing efficient PEC systems.
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Cited by
Recent Progress on Multimetal Oxide Catalysts for the Oxygen Evolution Reaction
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Metadata
- Authors
- Liu, W., Liu, H., Dang, L., Zhang, H., Wu, X., Yang, B., Li, Z., Zhang, X., Lei, L., & Jin, S.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2017-03-07
- Volume
- 27
- Issue
- 14
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W2592758909
- Cited by
- 357
- References
- 74
- FWCI
- 13.52
- Type
- journal article
- Language
- en
- Open access
- closed
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- Liu, W., Liu, H., Dang, L., Zhang, H., Wu, X., Yang, B., Li, Z., Zhang, X., Lei, L., & Jin, S. (2017). Amorphous Cobalt–Iron Hydroxide Nanosheet Electrocatalyst for Efficient Electrochemical and Photo‐Electrochemical Oxygen Evolution. Advanced Functional Materials. https://doi.org/10.1002/adfm.201603904
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