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Freestanding Metallic 1T MoS2 with Dual Ion Diffusion Paths as High Rate Anode for Sodium‐Ion Batteries

Geng, Xiumei, Jiao, Yucong, Han, Yang, Mukhopadhyay, Alolika, Yang, Lei, Zhu, Hongli·2017·Advanced Functional Materials

Abstract

This work studies for the first time the metallic 1T MoS 2 sandwich grown on graphene tube as a freestanding intercalation anode for promising sodium‐ion batteries (SIBs). Sodium is earth‐abundant and readily accessible. Compared to lithium, the main challenge of sodium‐ion batteries is its sluggish ion diffusion kinetic. The freestanding, porous, hollow structure of the electrode allows maximum electrolyte accessibility to benefit the transportation of Na+ ions. Meanwhile, the metallic MoS 2 provides excellent electron conductivity. The obtained 1T MoS 2 electrode exhibits excellent electrochemical performance: a high reversible capacity of 313 mAh g−1 at a current density of 0.05 A g−1 after 200 cycles and a high rate capability of 175 mAh g−1 at 2 A g−1. The underlying mechanism of high rate performance of 1T MoS 2 for SIBs is the high electrical conductivity and excellent ion accessibility. This study sheds light on using the 1T MoS 2 as a novel anode for SIBs.

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Metadata

Authors
Geng, X., Jiao, Y., Han, Y., Mukhopadhyay, A., Yang, L., & Zhu, H.
Venue
Advanced Functional Materials
Publisher
Wiley
Published
2017-08-25
Volume
27
Issue
40
ISSN
  • 1616-301X (ISSN-L)
  • 1616-3028
OpenAlex
W2746395301
Cited by
317
References
3
FWCI
15.55
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Freestanding Metallic 1T MoS2 with Dual Ion Diffusion Paths as High Rate Anode for Sodium‐Ion Batteries. https://app.cochat.ai/papers/10.1002/adfm.201702998
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Geng, X., Jiao, Y., Han, Y., Mukhopadhyay, A., Yang, L., & Zhu, H. (2017). Freestanding Metallic 1T MoS2 with Dual Ion Diffusion Paths as High Rate Anode for Sodium‐Ion Batteries. Advanced Functional Materials. https://doi.org/10.1002/adfm.201702998

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