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All‐Inorganic Bismuth‐Based Perovskite Quantum Dots with Bright Blue Photoluminescence and Excellent Stability
Abstract
Lead halide perovskite quantum dots (QDs) possess color‐tunable and narrow‐band emissions and are very promising for lighting and display applications, but they suffer from lead toxicity and instability. Although lead‐free Bi‐based and Sn‐based perovskite QDs (CsSnX 3, Cs 2 SnX 6, and (CH 3 NH 3)3 Bi 2 X 9) are reported, they all show low photoluminescence quantum yield (PLQY) and poor stability. Here, the synthesis of Cs 3 Bi 2 Br 9 perovskite QDs with high PLQY and excellent stability is reported. Via a green and facile process using ethanol as the antisolvent, as‐synthesized Cs 3 Bi 2 Br 9 QDs show a blue emission at 410 nm with a PLQY up to 19.4%. The whole series of Cs 3 Bi 2 X 9 (X = Cl, Br, and I) QDs by mixing precursors can cover the photoluminescence emission range from 393 to 545 nm. Furthermore, Cs 3 Bi 2 Br 9 QDs show excellent photostability and moisture stability due to the all‐inorganic nature and the surface passivation by BiOBr, which enables the one‐pot synthesis of Cs 3 Bi 2 Br 9 QD/silica composite. A lead‐free perovskite white light‐emitting diode is fabricated by simply combining the composite of Cs 3 Bi 2 Br 9 QD/silica with Y 3 Al 5 O 12 phosphor. As a new member of lead‐free perovskite QDs, Cs 3 Bi 2 Br 9 QDs open up a new route for the fabrication of optoelectronic devices due to their excellent stability and photophysical characteristics.
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Quantum Dot Light‐Emitting Diodes Based on Inorganic Perovskite Cesium Lead Halides (CsPbX3)
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Self-citationEmergence of colloidal quantum-dot light-emitting technologies
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Self-citationThe surface science of nanocrystals
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Mondal, N., De, A., & Samanta, A. (2019) · ACS Energy Letters · doi:10.1021/acsenergylett.8b01909 · Cited by 435
Dai, Y., Poidevin, C., Ochoa‐Hernández, C., Auer, A. A., & Tüysüz, H. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.201915034 · Cited by 269
Recent Advances in Perovskite Photodetectors for Image Sensing
Li, L., Ye, S., Qu, J., Zhou, F., Song, J., & Shen, G. (2021) · Small · doi:10.1002/smll.202005606 · Cited by 235
Europium-Doped Lead-Free Cs 3 Bi 2 Br 9 Perovskite Quantum Dots and Ultrasensitive Cu 2+ Detection
Ding, N., Zhou, D., Pan, G., Xu, W., Chen, X., Li, D., Zhang, X., Zhu, J., Ji, Y., & Song, H. (2019) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.9b00038 · Cited by 171
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Metadata
- Authors
- Leng, M., Yang, Y., Zeng, K., Chen, Z., Tan, Z., Li, S., Li, J., Xu, B., Li, D., Hautzinger, M. P., Fu, Y., Zhai, T., Xu, L., Niu, G., Jin, S., & Tang, J.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2017-11-27
- Volume
- 28
- Issue
- 1
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W2770281321
- Cited by
- 533
- References
- 50
- FWCI
- 18.01
- Type
- journal article
- Language
- en
- Open access
- closed
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- Leng, M., Yang, Y., Zeng, K., Chen, Z., Tan, Z., Li, S., Li, J., Xu, B., Li, D., Hautzinger, M. P., Fu, Y., Zhai, T., Xu, L., Niu, G., Jin, S., & Tang, J. (2018). All‐Inorganic Bismuth‐Based Perovskite Quantum Dots with Bright Blue Photoluminescence and Excellent Stability. Advanced Functional Materials. https://doi.org/10.1002/adfm.201704446
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