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Cited by 533

The DOI matches its Crossref record; 50 of the 50 references it cites were found in a registry or an index.

All‐Inorganic Bismuth‐Based Perovskite Quantum Dots with Bright Blue Photoluminescence and Excellent Stability

Leng, Meiying, Yang, Ying, Zeng, Kai, Chen, Zhengwu, Tan, Zhifang, Li, Shunran, Li, Jinghui, Xu, Bing, Li, Dengbing, Hautzinger, Matthew P., Fu, Yongping, Zhai, Tianyou, Xu, Ling, Niu, Guangda, Jin, Song, Tang, Jiang·2018·Advanced Functional Materials

Abstract

Lead halide perovskite quantum dots (QDs) possess color‐tunable and narrow‐band emissions and are very promising for lighting and display applications, but they suffer from lead toxicity and instability. Although lead‐free Bi‐based and Sn‐based perovskite QDs (CsSnX 3, Cs 2 SnX 6, and (CH 3 NH 3)3 Bi 2 X 9) are reported, they all show low photoluminescence quantum yield (PLQY) and poor stability. Here, the synthesis of Cs 3 Bi 2 Br 9 perovskite QDs with high PLQY and excellent stability is reported. Via a green and facile process using ethanol as the antisolvent, as‐synthesized Cs 3 Bi 2 Br 9 QDs show a blue emission at 410 nm with a PLQY up to 19.4%. The whole series of Cs 3 Bi 2 X 9 (X = Cl, Br, and I) QDs by mixing precursors can cover the photoluminescence emission range from 393 to 545 nm. Furthermore, Cs 3 Bi 2 Br 9 QDs show excellent photostability and moisture stability due to the all‐inorganic nature and the surface passivation by BiOBr, which enables the one‐pot synthesis of Cs 3 Bi 2 Br 9 QD/silica composite. A lead‐free perovskite white light‐emitting diode is fabricated by simply combining the composite of Cs 3 Bi 2 Br 9 QD/silica with Y 3 Al 5 O 12 phosphor. As a new member of lead‐free perovskite QDs, Cs 3 Bi 2 Br 9 QDs open up a new route for the fabrication of optoelectronic devices due to their excellent stability and photophysical characteristics.

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Metadata

Authors
Leng, M., Yang, Y., Zeng, K., Chen, Z., Tan, Z., Li, S., Li, J., Xu, B., Li, D., Hautzinger, M. P., Fu, Y., Zhai, T., Xu, L., Niu, G., Jin, S., & Tang, J.
Venue
Advanced Functional Materials
Publisher
Wiley
Published
2017-11-27
Volume
28
Issue
1
ISSN
  • 1616-301X (ISSN-L)
  • 1616-3028
OpenAlex
W2770281321
Cited by
533
References
50
FWCI
18.01
Type
journal article
Language
en
Open access
closed

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Leng, M., Yang, Y., Zeng, K., Chen, Z., Tan, Z., Li, S., Li, J., Xu, B., Li, D., Hautzinger, M. P., Fu, Y., Zhai, T., Xu, L., Niu, G., Jin, S., & Tang, J. (2018). All‐Inorganic Bismuth‐Based Perovskite Quantum Dots with Bright Blue Photoluminescence and Excellent Stability. Advanced Functional Materials. https://doi.org/10.1002/adfm.201704446

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