The DOI matches its Crossref record; 37 of the 37 references it cites were found in a registry or an index.
Single‐Atom Engineering of Directional Charge Transfer Channels and Active Sites for Photocatalytic Hydrogen Evolution
Abstract
Efficiency of layered photocatalysts such as graphitic carbon nitride (g‐CN) is still too low due to the poor utilization of photoexcited‐charge carriers. The major drawback is that the weak van der Waals force among g‐CN layers is unfavorable for the charge transfer between the adjacent layers and the intrinsically π‐conjugated planes with inefficient random in‐plane charge migration. Herein, an atomically dispersed Pd layered photocatalyst with both bridged sites of adjacent layers and surface‐sites of g‐CN is demonstrated, providing directional charge‐transfer channels and targeting active sites for photocatalytic water reduction. Both theoretical prediction and empirical characterizations are conducted to achieve the successful synthesis of single‐atom engineered Pd/g‐CN hybrid and the excellent separation of charge transfer as well as the efficient photocatalytic hydrogen evolution, much better than that of the optimized Pt/g‐CN benchmark. The finding in this work provides a rational way for tailoring the performance and engineering of single‐atomic noble metal.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
A metal-free polymeric photocatalyst for hydrogen production from water under visible light
Wang, X., Maeda, K., Thomas, A., Takanabe, K., Xin, G., Carlsson, J. M., Domen, K., & Antonietti, M. (2009) · Nature Materials · doi:10.1038/nmat2317 · Cited by 12,532
Ong, W.-J., Tan, L.-L., Ng, Y. H., Yong, S.-T., & Chai, S.-P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00075 · Cited by 7,147
Tkatchenko, A., & Scheffler, M. (2009) · Physical Review Letters · doi:10.1103/physrevlett.102.073005 · Cited by 6,286
Polymeric Photocatalysts Based on Graphitic Carbon Nitride
Cao, S., Low, J., Yu, J., & Jaroniec, M. (2015) · Advanced Materials · doi:10.1002/adma.201500033 · Cited by 3,674
Self-citationGraphene‐Like Carbon Nitride Nanosheets for Improved Photocatalytic Activities
Niu, P., Zhang, L., Liu, G., & Cheng, H. (2012) · Advanced Functional Materials · doi:10.1002/adfm.201200922 · Cited by 3,539
Photochemical route for synthesizing atomically dispersed palladium catalysts
Liu, P., Zhao, Y., Qin, R., Mo, S., Chen, G., Gu, L., Chevrier, D. M., Zhang, P., Guo, Q., Zang, D., et al. (2016) · Science · doi:10.1126/science.aaf5251 · Cited by 2,003
Graphitic Carbon Nitride Polymers toward Sustainable Photoredox Catalysis
Zheng, Y., Lin, L., Wang, B., & Wang, X. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201501788 · Cited by 1,432
Single‐Atom Pt as Co‐Catalyst for Enhanced Photocatalytic H2 Evolution
Li, X., Bi, W., Zhang, L., Tao, S., Chu, W., Zhang, Q., Luo, Y., Wu, C., & Xie, Y. (2016) · Advanced Materials · doi:10.1002/adma.201505281 · Cited by 1,426
Ran, J., Ma, T. Y., Gao, G., Du, X.-W., & Qiao, S. Z. (2015) · Energy & Environmental Science · doi:10.1039/c5ee02650d · Cited by 1,326
Hierarchical Porous O‐Doped g‐C3N4 with Enhanced Photocatalytic CO2 Reduction Activity
Fu, J., Zhu, B., Jiang, C., Cheng, B., You, W., & Yu, J. (2017) · Small · doi:10.1002/smll.201603938 · Cited by 1,291
Self-citation
Cited by
Single-Atom Catalysts across the Periodic Table
Kaiser, S. K., Chen, Z., Faust Akl, D., Mitchell, S., & Pérez-Ramírez, J. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00576 · Cited by 1,367
Heterogeneous Single-Atom Photocatalysts: Fundamentals and Applications
Gao, C., Low, J., Long, R., Kong, T., Zhu, J., & Xiong, Y. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00840 · Cited by 1,050
Kuang, P., Wang, Y., Zhu, B., Xia, F., Tung, C., Wu, J., Chen, H. M., & Yu, J. (2021) · Advanced Materials · doi:10.1002/adma.202008599 · Cited by 585
Self-citationSingle-atom catalysts for photocatalytic energy conversion
Xue, Z.-H., Luan, D., Zhang, H., & (David) Lou, X. W. (2022) · Joule · doi:10.1016/j.joule.2021.12.011 · Cited by 567
Xiao, X., Gao, Y., Zhang, L., Zhang, J., Zhang, Q., Li, Q., Bao, H., Zhou, J., Miao, S., Chen, N., et al. (2020) · Advanced Materials · doi:10.1002/adma.202003082 · Cited by 528
Metadata
- Authors
- Cao, S., Li, H., Tong, T., Chen, H., Yu, A., Yu, J., & Chen, H. M.
- Venue
- Advanced Functional Materials
- Publisher
- Wiley
- Published
- 2018-06-19
- Volume
- 28
- Issue
- 32
- ISSN
- 1616-301X (ISSN-L)
- 1616-3028
- OpenAlex
- W2809031301
- Cited by
- 438
- References
- 37
- FWCI
- 11.20
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Single‐Atom Engineering of Directional Charge Transfer Channels and Active Sites for Photocatalytic Hydrogen Evolution. https://app.cochat.ai/papers/10.1002/adfm.201802169
- The paper
- Cao, S., Li, H., Tong, T., Chen, H., Yu, A., Yu, J., & Chen, H. M. (2018). Single‐Atom Engineering of Directional Charge Transfer Channels and Active Sites for Photocatalytic Hydrogen Evolution. Advanced Functional Materials. https://doi.org/10.1002/adfm.201802169
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
