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Reversible Photoinduced Shape Changes of Crystalline Organic Nanorods
Abstract
Crystalline nanorods composed of 9-anthracene carboxylic acid (9-AC) are synthesized using nanoporous Al2O3 templates. When a segment of an isolated rod is exposed to UV-light, localized solid-state photodimerization of the 9-AC molecules induces micrometer-scale bending (see figure). The nanorod reverts back to its original shape after several minutes in the dark at room temperature. The reversible photoinduced shape change could be repeated multiple times.
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Citations
Cites
Light-induced shape-memory polymers
Lendlein, A., Jiang, H., Jünger, O., & Langer, R. (2005) · Nature · doi:10.1038/nature03496 · Cited by 2,006
Photomechanical actuation in polymer–nanotube composites
Ahir, S. V., & Terentjev, E. M. (2005) · Nature Materials · doi:10.1038/nmat1391 · Cited by 423
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Irie, M., Fukaminato, T., Matsuda, K., & Kobatake, S. (2014) · Chemical Reviews · doi:10.1021/cr500249p · Cited by 2,725
A review of stimuli-responsive polymers for smart textile applications
Hu, J., Meng, H., Li, G., & Ibekwe, S. I. (2012) · Smart Materials and Structures · doi:10.1088/0964-1726/21/5/053001 · Cited by 639
Photoinduced Twisting of a Photochromic Diarylethene Crystal
Kitagawa, D., Nishi, H., & Kobatake, S. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201304670 · Cited by 288
Anthony, S. P. (2012) · ChemPlusChem · doi:10.1002/cplu.201200073 · Cited by 278
Light-induced crawling of crystals on a glass surface
Uchida, E., Azumi, R., & Norikane, Y. (2015) · Nature Communications · doi:10.1038/ncomms8310 · Cited by 267
Metadata
- Authors
- Al‐Kaysi, R. O., & Bardeen, C. J.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2007-04-04
- Volume
- 19
- Issue
- 9
- Pages
- 1276-1280
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2001796910
- Cited by
- 218
- References
- 2
- FWCI
- 24.56
- Type
- journal article
- Language
- en
- Open access
- closed
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
