The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Efficient Synthesis of Sterically‐Stabilized Nano‐Objects via RAFT Dispersion Polymerization of Benzyl Methacrylate in Alcoholic Media
Abstract
Synthesis of diblock copolymer nano-objects: alcohol is a good idea! RAFT dispersion polymerization of benzyl methacrylate in alcohol using weak polyelectrolyte-based chain transfer agents allows the facile synthesis of sterically stabilized diblock copolymer nano-objects with very high monomer conversions. Such syntheses are usually problematic when conducted in water due to electrostatic repulsion between highly charged stabilizer chains, which impedes in situ self-assembly. Construction of a detailed phase diagram facilitates reproducible syntheses of well-defined diblock copolymer spheres, worms or vesicles, since it allows mixed phase regions to be avoided. Aqueous electrophoresis studies confirm that these nano-objects can acquire substantial surface charge when transferred to aqueous solution due to ionization (or protonation) of the polyacid (or polybase) stabilizer chains.
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Cites
Blanazs, A., Armes, S. P., & Ryan, A. J. (2009) · Macromolecular Rapid Communications · doi:10.1002/marc.200800713 · Cited by 1,500
Self-citationOn the origins of morphological complexity in block copolymer surfactants
Jain, S., & Bates, F. S. (2003) · Science · doi:10.1126/science.1082193 · Cited by 1,217
Controlled/living radical polymerization in aqueous media: homogeneous and heterogeneous systems
Qiu, J., Charleux, B., & Matyjaszewski, K. (2001) · Progress in Polymer Science · doi:10.1016/s0079-6700(01)00033-8 · Cited by 595
Cited by
Controlled/Living Radical Polymerization in Dispersed Systems: An Update
Zetterlund, P. B., Thickett, S. C., Perrier, S., Bourgeat-Lami, E., & Lansalot, M. (2015) · Chemical Reviews · doi:10.1021/cr500625k · Cited by 485
Rieger, J. (2015) · Macromolecular Rapid Communications · doi:10.1002/marc.201500028 · Cited by 349
Thermo-responsive Diblock Copolymer Worm Gels in Non-polar Solvents
Fielding, L. A., Lane, J. A., Derry, M. J., Mykhaylyk, O. O., & Armes, S. P. (2014) · Journal of the American Chemical Society · doi:10.1021/ja501756h · Cited by 309
Self-citationYeow, J., Xu, J., & Boyer, C. (2015) · ACS Macro Letters · doi:10.1021/acsmacrolett.5b00523 · Cited by 266
Metadata
- Authors
- Semsarilar, M., Jones, E. R., Blanazs, A., & Armes, S. P.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2012-05-18
- Volume
- 24
- Issue
- 25
- Pages
- 3378-3382
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2106947391
- Cited by
- 198
- References
- 3
- FWCI
- 8.60
- Type
- journal article
- Language
- en
- Open access
- closed
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- Semsarilar, M., Jones, E. R., Blanazs, A., & Armes, S. P. (2012). Efficient Synthesis of Sterically‐Stabilized Nano‐Objects via RAFT Dispersion Polymerization of Benzyl Methacrylate in Alcoholic Media. Advanced Materials. https://doi.org/10.1002/adma.201200925
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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