The DOI matches its Crossref record; 72 of the 72 references it cites were found in a registry or an index.
Polymerization-Induced Self-Assembly Using Visible Light Mediated Photoinduced Electron Transfer–Reversible Addition–Fragmentation Chain Transfer Polymerization
Abstract
The ruthenium-based photoredox catalyst, Ru(bpy) 3 Cl 2, was employed to activate reversible addition–fragmentation chain transfer (RAFT) dispersion polymerization via a photoinduced electron transfer (PET) process under visible light (λ = 460 nm, 0.7 mW/cm 2 ). Poly(oligo(ethylene glycol) methyl ether methacrylate) was chain extended with benzyl methacrylate to afford in situ self-assembled polymeric nanoparticles with various morphologies. The effect of different intrinsic reaction parameters, such as catalyst concentration, total solids content, and cosolvent addition was investigated with respect to the formation of different nanoparticle morphologies, including spherical micelles, worm-like micelles, and vesicles. Importantly, highly pure worm-like micelles were readily isolated due to the in situ formation of highly viscous gels. Finally, “ON/OFF” control over the dispersion polymerization was demonstrated by online Fourier transform near-infrared (FTNIR) spectroscopy, allowing for temporal control over the nanoparticle morphology.
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Cites
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On the origins of morphological complexity in block copolymer surfactants
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Self-citationIon-Induced Morphological Changes in “Crew-Cut” Aggregates of Amphiphilic Block Copolymers
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Mechanistic Insights for Block Copolymer Morphologies: How Do Worms Form Vesicles?
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Control of a Living Radical Polymerization of Methacrylates by Light
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Cited by
McKenzie, T. G., Fu, Q., Uchiyama, M., Satoh, K., Xu, J., Boyer, C., Kamigaito, M., & Qiao, G. G. (2016) · Advanced Science · doi:10.1002/advs.201500394 · Cited by 283
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Metadata
- Authors
- Yeow, J., Xu, J., & Boyer, C.
- Venue
- ACS Macro Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-08-27
- Volume
- 4
- Issue
- 9
- Pages
- 984-990
- ISSN
- 2161-1653 (ISSN-L)
- OpenAlex
- W2279591162
- Cited by
- 266
- References
- 72
- FWCI
- 22.03
- Type
- journal article
- Language
- en
- Open access
- closed
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