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25th Anniversary Article: MXenes: A New Family of Two‐Dimensional Materials

Naguib, Michael, Mochalin, Vadym N., Barsoum, Michel W., Gogotsi, Yury·2014·Advanced Materials

Abstract

Recently a new, large family of two‐dimensional (2D) early transition metal carbides and carbonitrides, called MXenes, was discovered. MXenes are produced by selective etching of the A element from the MAX phases, which are metallically conductive, layered solids connected by strong metallic, ionic, and covalent bonds, such as Ti 2 AlC, Ti 3 AlC 2, and Ta 4 AlC 3. MXenes ­combine the metallic conductivity of transition metal carbides with the hydrophilic nature of their hydroxyl or oxygen terminated surfaces. In essence, they behave as “conductive clays”. This article reviews progress—both ­experimental and theoretical—on their synthesis, structure, properties, intercalation, delamination, and potential applications. MXenes are expected to be good candidates for a host of applications. They have already shown promising performance in electrochemical energy storage systems. A detailed outlook for future research on MXenes is also presented.

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Metadata

Authors
Naguib, M., Mochalin, V. N., Barsoum, M. W., & Gogotsi, Y.
Venue
Advanced Materials
Publisher
Wiley
Published
2013-12-19
Volume
26
Issue
7
Pages
992-1005
ISSN
  • 0935-9648 (ISSN-L)
  • 1521-4095
OpenAlex
W2155175869
Cited by
6,414
References
2
FWCI
46.92
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: 25th Anniversary Article: MXenes: A New Family of Two‐Dimensional Materials. https://app.cochat.ai/papers/10.1002/adma.201304138
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Naguib, M., Mochalin, V. N., Barsoum, M. W., & Gogotsi, Y. (2014). 25th Anniversary Article: MXenes: A New Family of Two‐Dimensional Materials. Advanced Materials. https://doi.org/10.1002/adma.201304138

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