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Wet‐Chemical Synthesis of Hollow Red‐Phosphorus Nanospheres with Porous Shells as Anodes for High‐Performance Lithium‐Ion and Sodium‐Ion Batteries
Abstract
Large‐volume‐expansion‐induced material pulverization severely limits the electrochemical performance of red phosphorous (P) for energy‐storage applications. Hollow nanospheres with porous shells are recognized as an ideal structure to resolve these issues. However, a chemical synthetic approach for preparing nanostructured red P is always of great challenge and hollow nanosphere structures of red P have not yet been fabricated. Herein, a wet solvothermal method to successfully fabricate hollow P nanospheres (HPNs) with porous shells via a gas‐bubble‐directed formation mechanism is developed. More importantly, due to the merits of the porous and hollow structures, these HPNs reveal the highest capacities (based on the weight of electrode materials) of 1285.7 mA h g−1 for lithium‐ion batteries and 1364.7 mA h g−1 for sodium‐ion batteries at 0.2 C, and excellent long‐cycling performance.
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Citations
Cited by
Toward Practical High-Energy and High-Power Lithium Battery Anodes: Present and Future
Wang, C., Yang, C., & Zheng, Z. (2022) · Advanced Science · doi:10.1002/advs.202105213 · Cited by 337
Wang, R., Wang, L., Liu, R., Li, X., Wu, Y., & Ran, F. (2024) · ACS Nano · doi:10.1021/acsnano.3c08712 · Cited by 336
Recent progress in phosphorus based anode materials for lithium/sodium ion batteries
Liu, W., Zhi, H., & Yu, X. (2019) · Energy Storage Materials · doi:10.1016/j.ensm.2018.05.020 · Cited by 308
Extracting oxygen anions from ZnMn2O4: Robust cathode for flexible all-solid-state Zn-ion batteries
Zhang, H., Wang, J., Liu, Q., He, W., Lai, Z., Zhang, X., Yu, M., Tong, Y., & Lu, X. (2019) · Energy Storage Materials · doi:10.1016/j.ensm.2018.12.019 · Cited by 299
Metadata
- Authors
- Zhou, J., Liu, X., Cai, W., Zhu, Y., Liang, J., Zhang, K., Lan, Y., Jiang, Z., Wang, G., & Qian, Y.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2017-05-26
- Volume
- 29
- Issue
- 29
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2617180263
- Cited by
- 252
- References
- 0
- FWCI
- 14.66
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhou, J., Liu, X., Cai, W., Zhu, Y., Liang, J., Zhang, K., Lan, Y., Jiang, Z., Wang, G., & Qian, Y. (2017). Wet‐Chemical Synthesis of Hollow Red‐Phosphorus Nanospheres with Porous Shells as Anodes for High‐Performance Lithium‐Ion and Sodium‐Ion Batteries. Advanced Materials. https://doi.org/10.1002/adma.201700214
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