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Construction of Complex Co3O4@Co3V2O8 Hollow Structures from Metal–Organic Frameworks with Enhanced Lithium Storage Properties

Open access
Lu, Yan, Yu, Le, Wu, Minghong, Wang, Yong, Lou, Xiong Wen (David)·2018·Advanced Materials

Abstract

A novel metal–organic‐framework‐engaged strategy is demonstrated for the preparation of multishelled Co 3 O 4@Co 3 V 2 O 8 hybrid nanoboxes. This strategy relies on the unique reaction of zeolitic imidazolate framework‐67 with the vanadium source of vanadium oxytriisopropoxide. Benefitting from the synthetic versatility, a series of nanostructures can be realized including triple‐shelled and double‐shelled Co 3 O 4@Co 3 V 2 O 8 nanoboxes and single‐shelled Co 3 V 2 O 8 nanoboxes. When evaluated as electrode materials for lithium‐ion batteries, these unique hollow structures demonstrate remarkable lithium storage properties. For example, the triple‐shelled Co 3 O 4@Co 3 V 2 O 8 nanoboxes retain a high capacity of 948 mAh g−1 after 100 cycles at 100 mA g−1.

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Metadata

Authors
Lu, Y., Yu, L., Wu, M., Wang, Y., & Lou, X. W. (.
Venue
Advanced Materials
Publisher
Wiley
Published
2017-11-24
Volume
30
Issue
1
ISSN
  • 0935-9648 (ISSN-L)
  • 1521-4095
OpenAlex
W2769182458
Cited by
302
References
0
FWCI
18.01
Type
journal article
Language
en
Open access
bronze

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CoChat. (2026). Citation check: Construction of Complex Co3O4@Co3V2O8 Hollow Structures from Metal–Organic Frameworks with Enhanced Lithium Storage Properties. https://app.cochat.ai/papers/10.1002/adma.201702875
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Lu, Y., Yu, L., Wu, M., Wang, Y., & Lou, X. W. (. (2018). Construction of Complex Co3O4@Co3V2O8 Hollow Structures from Metal–Organic Frameworks with Enhanced Lithium Storage Properties. Advanced Materials. https://doi.org/10.1002/adma.201702875

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