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Cited by 222

The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.

Influence of Radiation on the Properties and the Stability of Hybrid Perovskites

Open access
Lang, Felix, Shargaieva, Oleksandra, Brus, Viktor V., Neitzert, Heinz C., Rappich, Jörg, Nickel, Norbert H.·2018·Advanced Materials

Abstract

Organic–inorganic perovskites are well suited for optoelectronic applications. In particular, perovskite single and perovskite tandem solar cells with silicon are close to their market entry. Despite their swift rise in efficiency to more than 21%, solar cell lifetimes are way below the needed 25 years. In fact, comparison of the time when the device performance has degraded to 80% of its initial value (T80 lifetime) of numerous solar cells throughout the literature reveals a strongly reduced stability under illumination. Herein, the various detrimental effects are discussed. Most notably, moisture‐ and heat‐related degradation can be mitigated easily by now. Recently, however, several photoinduced degradation mechanisms have been observed. Under illumination, mixed perovskites tend to phase segregate, while, further, oxygen catalyzes deprotonation of the organic cations. Additionally, during illumination photogenerated charge can be trapped in the NH antibonding orbitals causing dissociation of the organic cation. On the other hand, organic–inorganic perovskites exhibit a high radiation hardness that is superior to crystalline silicon. Here, the proposed degradation mechanisms reported in the literature are thoroughly reviewed and the microscopic mechanisms and their implications for solar cells are discussed.

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Metadata

Authors
Lang, F., Shargaieva, O., Brus, V. V., Neitzert, H. C., Rappich, J., & Nickel, N. H.
Venue
Advanced Materials
Publisher
Wiley
Published
2017-11-20
Volume
30
Issue
3
ISSN
  • 0935-9648 (ISSN-L)
  • 1521-4095
OpenAlex
W2771001224
Cited by
222
References
6
FWCI
7.94
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Influence of Radiation on the Properties and the Stability of Hybrid Perovskites. https://app.cochat.ai/papers/10.1002/adma.201702905
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Lang, F., Shargaieva, O., Brus, V. V., Neitzert, H. C., Rappich, J., & Nickel, N. H. (2018). Influence of Radiation on the Properties and the Stability of Hybrid Perovskites. Advanced Materials. https://doi.org/10.1002/adma.201702905

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