The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Influence of Radiation on the Properties and the Stability of Hybrid Perovskites
Open accessAbstract
Organic–inorganic perovskites are well suited for optoelectronic applications. In particular, perovskite single and perovskite tandem solar cells with silicon are close to their market entry. Despite their swift rise in efficiency to more than 21%, solar cell lifetimes are way below the needed 25 years. In fact, comparison of the time when the device performance has degraded to 80% of its initial value (T80 lifetime) of numerous solar cells throughout the literature reveals a strongly reduced stability under illumination. Herein, the various detrimental effects are discussed. Most notably, moisture‐ and heat‐related degradation can be mitigated easily by now. Recently, however, several photoinduced degradation mechanisms have been observed. Under illumination, mixed perovskites tend to phase segregate, while, further, oxygen catalyzes deprotonation of the organic cations. Additionally, during illumination photogenerated charge can be trapped in the NH antibonding orbitals causing dissociation of the organic cation. On the other hand, organic–inorganic perovskites exhibit a high radiation hardness that is superior to crystalline silicon. Here, the proposed degradation mechanisms reported in the literature are thoroughly reviewed and the microscopic mechanisms and their implications for solar cells are discussed.
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Stranks, S. D., Eperon, G. E., Grancini, G., Menelaou, C., Alcocer, M. J. P., Leijtens, T., Herz, L. M., Petrozza, A., & Snaith, H. J. (2013) · Science · doi:10.1126/science.1243982 · Cited by 10,413
Kim, H.-S., Lee, C.-R., Im, J.-H., Lee, K.-B., Moehl, T., Marchioro, A., Moon, S.-J., Humphry-Baker, R., Yum, J.-H., Moser, J. E., et al. (2012) · Scientific Reports · doi:10.1038/srep00591 · Cited by 8,092
Deschler, F., Price, M., Pathak, S., Klintberg, L. E., Jarausch, D.-D., Higler, R., Hüttner, S., Leijtens, T., Stranks, S. D., Snaith, H. J., et al. (2014) · The Journal of Physical Chemistry Letters · doi:10.1021/jz5005285 · Cited by 1,753
Lead iodide perovskite light-emitting field-effect transistor
Chin, X. Y., Cortecchia, D., Yin, J., Bruno, A., & Soci, C. (2015) · Nature Communications · doi:10.1038/ncomms8383 · Cited by 767
Achieving long-term stable perovskite solar cells via ion neutralization
Back, H., Kim, G., Kim, J., Kong, J., Kim, T. K., Kang, H., Kim, H., Lee, J., Lee, S., & Lee, K. (2016) · Energy & Environmental Science · doi:10.1039/c6ee00612d · Cited by 337
Structured Organic–Inorganic Perovskite toward a Distributed Feedback Laser
Saliba, M., Wood, S. M., Patel, J. B., Nayak, P. K., Huang, J., Alexander‐Webber, J. A., Wenger, B., Stranks, S. D., Hörantner, M. T., Wang, J. T., et al. (2016) · Advanced Materials · doi:10.1002/adma.201502608 · Cited by 297
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Wei, Y., Cheng, Z., & Lin, J. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00740c · Cited by 1,206
Controlled n‐Doping in Air‐Stable CsPbI2Br Perovskite Solar Cells with a Record Efficiency of 16.79%
Han, Y., Zhao, H., Duan, C., Yang, S., Yang, Z., Liu, Z., & Liu, S. (. (2020) · Advanced Functional Materials · doi:10.1002/adfm.201909972 · Cited by 367
Ran, J., Wang, B., Wu, Y., Liu, D., Mora Perez, C., Vasenko, A. S., & Prezhdo, O. V. (2023) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.3c01231 · Cited by 51
Metadata
- Authors
- Lang, F., Shargaieva, O., Brus, V. V., Neitzert, H. C., Rappich, J., & Nickel, N. H.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2017-11-20
- Volume
- 30
- Issue
- 3
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2771001224
- Cited by
- 222
- References
- 6
- FWCI
- 7.94
- Type
- journal article
- Language
- en
- Open access
- green
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