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Ultrahigh Piezoelectric Properties in Textured (K,Na)NbO3‐Based Lead‐Free Ceramics

Li, Peng, Zhai, Jiwei, Shen, Bo, Zhang, Shujun, Li, Xiaolong, Zhu, Fangyuan, Zhang, Xingmin·2018·Advanced Materials

Abstract

High‐performance lead‐free piezoelectric materials are in great demand for next‐generation electronic devices to meet the requirement of environmentally sustainable society. Here, ultrahigh piezoelectric properties with piezoelectric coefficients (d33 ≈700 pC N−1, d33* ≈980 pm V−1) and planar electromechanical coupling factor (kp ≈76%) are achieved in highly textured (K,Na)NbO 3 (KNN)‐based ceramics. The excellent piezoelectric properties can be explained by the strong anisotropic feature, optimized engineered domain configuration in the textured ceramics, and facilitated polarization rotation induced by the intermediate phase. In addition, the nanodomain structures with decreased domain wall energy and increased domain wall mobility also contribute to the ultrahigh piezoelectric properties. This work not only demonstrates the tremendous potential of KNN‐based ceramics to replace lead‐based piezoelectrics but also provides a good strategy to design high‐performance piezoelectrics by controlling appropriate phase and crystallographic orientation.

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Metadata

Authors
Li, P., Zhai, J., Shen, B., Zhang, S., Li, X., Zhu, F., & Zhang, X.
Venue
Advanced Materials
Publisher
Wiley
Published
2018-01-10
Volume
30
Issue
8
ISSN
  • 0935-9648 (ISSN-L)
  • 1521-4095
OpenAlex
W2783730404
Cited by
555
References
32
FWCI
24.49
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Ultrahigh Piezoelectric Properties in Textured (K,Na)NbO3‐Based Lead‐Free Ceramics. https://app.cochat.ai/papers/10.1002/adma.201705171
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Li, P., Zhai, J., Shen, B., Zhang, S., Li, X., Zhu, F., & Zhang, X. (2018). Ultrahigh Piezoelectric Properties in Textured (K,Na)NbO3‐Based Lead‐Free Ceramics. Advanced Materials. https://doi.org/10.1002/adma.201705171

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