The DOI matches its Crossref record; 41 of the 41 references it cites were found in a registry or an index.
Co(OH)2 Nanoparticle‐Encapsulating Conductive Nanowires Array: Room‐Temperature Electrochemical Preparation for High‐Performance Water Oxidation Electrocatalysis
Abstract
It is highly desired but still remains challenging to design and develop a Co‐based nanoparticle‐encapsulated conductive nanoarray at room temperature for high‐performance water oxidation electrocatalysis. Here, it is reported that room‐temperature anodization of a Co(TCNQ)2 (TCNQ = tetracyanoquinodimethane) nanowire array on copper foam at alkaline pH leads to in situ electrochemcial oxidation of TCNQ− into water‐insoluable TCNQ nanoarray embedding Co(OH)2 nanoparticles. Such Co(OH)2‐TCNQ/CF shows superior catalytic activity for water oxidation and demands only a low overpotential of 276 mV to drive a geometrical current density of 25 mA cm−2 in 1.0 m KOH. Notably, it also demonstrates strong long‐term electrochemical durability with its activity being retrained for at least 25 h, a high turnover frequency of 0.97 s−1 at an overpotential of 450 mV and 100% Faradic efficiency. This study provides an exciting new method for the rational design and development of a conductive TCNQ‐based nanoarray as an interesting 3D material for advanced electrochemical applications.
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Self-citationRecent Progress in MXene‐Based Materials: Potential High‐Performance Electrocatalysts
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Self-citationIridium-based nanomaterials for electrochemical water splitting
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Metadata
- Authors
- Wu, D., Wei, Y., Ren, X., Ji, X., Liu, Y., Guo, X., Liu, Z., Asiri, A. M., Wei, Q., & Sun, X.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2018-01-15
- Volume
- 30
- Issue
- 9
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2782942357
- Cited by
- 353
- References
- 41
- FWCI
- 14.93
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wu, D., Wei, Y., Ren, X., Ji, X., Liu, Y., Guo, X., Liu, Z., Asiri, A. M., Wei, Q., & Sun, X. (2018). Co(OH)2 Nanoparticle‐Encapsulating Conductive Nanowires Array: Room‐Temperature Electrochemical Preparation for High‐Performance Water Oxidation Electrocatalysis. Advanced Materials. https://doi.org/10.1002/adma.201705366
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