The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Retracted: Colloidal Cobalt Phosphide Nanocrystals as Trifunctional Electrocatalysts for Overall Water Splitting Powered by a Zinc–Air Battery
Open accessAbstract
Highly efficient and stable electrocatalysts, particularly those that are capable of multifunctionality in the same electrolyte, are in high demand for the hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and oxygen reduction reaction (ORR). In this work, highly monodisperse CoP and Co 2 P nanocrystals (NCs) are synthesized using a robust solution‐phase method. The highly exposed (211) crystal plane and abundant surface phosphide atoms make the CoP NCs efficient catalysts toward ORR and HER, while metal‐rich Co 2 P NCs show higher OER performance owing to easier formation of plentiful Co 2 P@COOH heterojunctions. Density functional theory calculation results indicate that the desorption of OH* from cobalt sites is the rate‐limiting step for both CoP and Co 2 P in ORR and that the high content of phosphide can lower the reaction barrier. A water electrolyzer constructed with a CoP NC cathode and a Co 2 P NC anode can achieve a current density of 10 mA cm−2 at 1.56 V, comparable even to the noble metal‐based Pt/C and RuO 2/C pair. Furthermore, the CoP NCs are employed as an air cathode in a primary zinc–air battery, exhibiting a high power density of 62 mW cm−2 and good stability.
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Cites
Electrocatalysis for the oxygen evolution reaction: recent development and future perspectives
Suen, N.-T., Hung, S.-F., Quan, Q., Zhang, N., Xu, Y.-J., & Chen, H. M. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00328a · Cited by 6,307
Noble metal-free hydrogen evolution catalysts for water splitting
Zou, X., & Zhang, Y. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00448e · Cited by 5,955
Recent Advances in Electrocatalysts for Oxygen Reduction Reaction
Shao, M., Chang, Q., Dodelet, J.-P., & Chenitz, R. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00462 · Cited by 3,903
Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis
Hong, W. T., Risch, M., Stoerzinger, K. A., Grimaud, A., Suntivich, J., & Shao-Horn, Y. (2015) · Energy & Environmental Science · doi:10.1039/c4ee03869j · Cited by 2,089
Faber, M. S., & Jin, S. (2014) · Energy Environ. Sci. · doi:10.1039/c4ee01760a · Cited by 1,317
Plasma-Assisted Synthesis of NiCoP for Efficient Overall Water Splitting
Liang, H., Gandi, A. N., Anjum, D. H., Wang, X., Schwingenschlögl, U., & Alshareef, H. N. (2016) · Nano Letters · doi:10.1021/acs.nanolett.6b03803 · Cited by 1,237
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Cited by
Pu, Z., Liu, T., Amiinu, I. S., Cheng, R., Wang, P., Zhang, C., Ji, P., Hu, W., Liu, J., & Mu, S. (2020) · Advanced Functional Materials · doi:10.1002/adfm.202004009 · Cited by 604
Multifunctional Transition Metal‐Based Phosphides in Energy‐Related Electrocatalysis
Li, Y., Dong, Z., & Jiao, L. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201902104 · Cited by 603
Guo, H., Feng, Q., Zhu, J., Xu, J., Li, Q., Liu, S., Xu, K., Zhang, C., & Liu, T. (2019) · Journal of Materials Chemistry A · doi:10.1039/c8ta11400e · Cited by 306
Self-citationZou, H., Li, G., Duan, L., Kou, Z., & Wang, J. (2019) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2019.118100 · Cited by 159
Yu, J., Li, Z., Liu, T., Zhao, S., Guan, D., Chen, D., Shao, Z., & Ni, M. (2023) · Chemical Engineering Journal · doi:10.1016/j.cej.2023.141674 · Cited by 99
Metadata
- Authors
- Li, H., Li, Q., Wen, P., Williams, T. B., Adhikari, S., Dun, C., Lu, C., Itanze, D., Jiang, L., Carroll, D. L., Donati, G. L., Lundin, P. M., Qiu, Y., & Geyer, S. M.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2018-01-15
- Volume
- 30
- Issue
- 9
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2783624415
- Cited by
- 301
- References
- 8
- FWCI
- 11.25
- Type
- journal article
- Language
- en
- Status
- Retracted
- Open access
- green
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- Li, H., Li, Q., Wen, P., Williams, T. B., Adhikari, S., Dun, C., Lu, C., Itanze, D., Jiang, L., Carroll, D. L., Donati, G. L., Lundin, P. M., Qiu, Y., & Geyer, S. M. (2018). Retracted: Colloidal Cobalt Phosphide Nanocrystals as Trifunctional Electrocatalysts for Overall Water Splitting Powered by a Zinc–Air Battery. Advanced Materials. https://doi.org/10.1002/adma.201705796
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