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A High‐Rate and Stable Quasi‐Solid‐State Zinc‐Ion Battery with Novel 2D Layered Zinc Orthovanadate Array

Chao, Dongliang, Zhu, Changrong (Rose), Song, Ming, Liang, Pei, Zhang, Xiao, Tiep, Nguyen Huy, Zhao, Haofei, Wang, John, Wang, Rongming, Zhang, Hua, Fan, Hong Jin·2018·Advanced Materials

Abstract

Zinc‐ion batteries are under current research focus because of their uniqueness in low cost and high safety. However, it is still desirable to improve the rate performance by improving the Zn 2+ (de)intercalation kinetics and long‐cycle stability by eliminating the dendrite formation problem. Herein, the first paradigm of a high‐rate and ultrastable flexible quasi‐solid‐state zinc‐ion battery is constructed from a novel 2D ultrathin layered zinc orthovanadate array cathode, a Zn array anode supported by a conductive porous graphene foam, and a gel electrolyte. The nanoarray structure for both electrodes assures the high rate capability and alleviates the dendrite growth. The flexible Zn‐ion battery has a depth of discharge of ≈100% for the cathode and 66% for the anode, and delivers an impressive high‐rate of 50 C (discharge in 60 s), long‐term durability of 2000 cycles at 20 C, and unprecedented energy density ≈115 Wh kg−1, together with a peak power density ≈5.1 kW kg−1 (calculation includes masses of cathode, anode, and current collectors). First principles calculations and quantitative kinetics analysis show that the high‐rate and stable properties are correlated with the 2D fast ion‐migration pathways and the introduced intercalation pseudocapacitance.

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Metadata

Authors
Chao, D., Zhu, C. (., Song, M., Liang, P., Zhang, X., Tiep, N. H., Zhao, H., Wang, J., Wang, R., Zhang, H., & Fan, H. J.
Venue
Advanced Materials
Publisher
Wiley
Published
2018-07-02
Volume
30
Issue
32
Pages
e1803181-e1803181
ISSN
  • 0935-9648 (ISSN-L)
  • 1521-4095
OpenAlex
W2810845233
Cited by
713
References
1
FWCI
33.68
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: A High‐Rate and Stable Quasi‐Solid‐State Zinc‐Ion Battery with Novel 2D Layered Zinc Orthovanadate Array. https://app.cochat.ai/papers/10.1002/adma.201803181
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Chao, D., Zhu, C. (., Song, M., Liang, P., Zhang, X., Tiep, N. H., Zhao, H., Wang, J., Wang, R., Zhang, H., & Fan, H. J. (2018). A High‐Rate and Stable Quasi‐Solid‐State Zinc‐Ion Battery with Novel 2D Layered Zinc Orthovanadate Array. Advanced Materials. https://doi.org/10.1002/adma.201803181

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