Weavable, Conductive Yarn-Based NiCo//Zn Textile Battery with High Energy Density and Rate Capability
Abstract
With intrinsic safety and much higher energy densities than supercapacitors, rechargeable nickel/cobalt–zinc-based textile batteries are promising power sources for next generation personalized wearable electronics. However, high-performance wearable nickel/cobalt–zinc-based batteries are rarely reported because there is a lack of industrially weavable and knittable highly conductive yarns. Here, we use scalably produced highly conductive yarns uniformly covered with zinc (as anode) and nickel cobalt hydroxide nanosheets (as cathode) to fabricate rechargeable yarn batteries. They possess a battery level capacity and energy density, as well as a supercapacitor level power density. They deliver high specific capacity of 5 mAh cm –3 and energy densities of 0.12 mWh cm –2 and 8 mWh cm –3 (based on the whole solid battery). They exhibit ultrahigh rate capabilities of 232 C (liquid electrolyte) and 116 C (solid electrolyte), which endows the batteries excellent power densities of 32.8 mW cm –2 and 2.2 W cm –3 (based on the whole solid battery). These are among the highest values reported so far. A wrist band battery is further constructed by using a large conductive cloth woven from the conductive yarns by a commercial weaving machine. It powers various electronic devices successfully, enabling dual functions of wearability and energy storage.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
Wearable biosensors face many fundamental challenges and technological gaps related to the scope, validation, stability and accuracy, along with power, communication and security/privacy issues.
“Wearable biosensors face many fundamental challenges and technological gaps related to the scope, validation, stability and accuracy, along with power (Box 1)1,42,157-167, communication (Box 2)1,168 and security/privacy issues (Box 3)1,169-172”
From Wearable biosensors for healthcare monitoring (2019) · cites this paper as [160]
Cites
Laser Scribing of High-Performance and Flexible Graphene-Based Electrochemical Capacitors
El‐Kady, M. F., Strong, V., Dubin, S., & Kaner, R. B. (2012) · Science · doi:10.1126/science.1216744 · Cited by 4,014 · see citing works
Reversible aqueous zinc/manganese oxide energy storage from conversion reactions
Pan, H., Shao, Y., Yan, P., et al. (2016) · Nature Energy · doi:10.1038/nenergy.2016.39 · Cited by 3,091 · see citing works
Recent advances in zinc–air batteries
Li, Y., & Dai, H. (2014) · Chemical Society Reviews · doi:10.1039/c4cs00015c · Cited by 2,326 · see citing works
Yuan, C., Li, J., Hou, L., Zhang, X., Shen, L., & Lou, X. W. (2012) · Advanced Functional Materials · doi:10.1002/adfm.201200994 · Cited by 1,690 · see citing works
Aqueous Rechargeable Li and Na Ion Batteries
Kim, H., Hong, J., Park, K., Kim, H., Kim, S., & Kang, K. (2014) · Chemical Reviews · doi:10.1021/cr500232y · Cited by 1,494 · see citing works
Yu, D., Goh, K., Wang, H., Li, W., Jiang, W., Zhang, Q., Dai, L., & Chen, Y. (2014) · Nature Nanotechnology · doi:10.1038/nnano.2014.93 · Cited by 1,438 · see citing works
Zhou, C., Zhang, Y., Li, Y., et al. (2013) · Nano Letters · doi:10.1021/nl400378j · Cited by 1,347 · see citing works
3D Printing of Interdigitated Li‐Ion Microbattery Architectures
Sun, K., Wei, T., Ahn, B. Y., Seo, J. Y., Dillon, S. J., & Lewis, J. A. (2013) · Advanced Materials · doi:10.1002/adma.201301036 · Cited by 1,342 · see citing works
Coaxial wet-spun yarn supercapacitors for high-energy density and safe wearable electronics
Kou, L., Huang, T., Zheng, B., Han, Y., Zhao, X., Gopalsamy, K., Sun, H., & Gao, C. (2014) · Nature Communications · doi:10.1038/ncomms4754 · Cited by 1,134 · see citing works
Yang, P., Ding, Y. L., Lin, Z., et al. (2014) · Nano Letters · doi:10.1021/nl404008e · Cited by 1,080 · see citing works
Lu, X., Yu, M., Wang, G., et al. (2012) · Advanced Materials · doi:10.1002/adma.201203410 · Cited by 952 · see citing works
Fiber Supercapacitors Made of Nanowire‐Fiber Hybrid Structures for Wearable/Flexible Energy Storage
Bae, J., Song, M. K., Park, Y. J., Kim, J. M., Liu, M., & Wang, Z. L. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201006062 · Cited by 856 · see citing works
Twisting Carbon Nanotube Fibers for Both Wire‐Shaped Micro‐Supercapacitor and Micro‐Battery
Ren, J., Li, L., Chen, C., Chen, X., Cai, Z., Qiu, L., Wang, Y., Zhu, X., & Peng, H. (2012) · Advanced Materials · doi:10.1002/adma.201203445 · Cited by 787 · see citing works
Self-citationLu, X., Yu, M., Zhai, T., Wang, G., Xie, S., Liu, T., Liang, C., Tong, Y., & Li, Y. (2013) · Nano Letters · doi:10.1021/nl400760a · Cited by 718 · see citing works
Xu, J. P., Wang, Q., Wang, X., et al. (2013) · ACS Nano · doi:10.1021/nn401450s · Cited by 638 · see citing works
Pikul, J. H., Zhang, H., Cho, J., et al. (2013) · Nature Communications · doi:10.1038/ncomms2747 · Cited by 635 · see citing works
Fiber Supercapacitors Utilizing Pen Ink for Flexible/Wearable Energy Storage
Fu, Y., Cai, X. L., Wu, H., Lv, Z., Hou, S., Peng, M., Yu, X. H., & Zou, D. (2012) · Advanced Materials · doi:10.1002/adma.201202930 · Cited by 616 · see citing works
Liu, J., Guan, C., Zhou, C., Fan, Z. H., Ke, Q., Zhang, G., Liu, C., & Wang, J. (2016) · Advanced Materials · doi:10.1002/adma.201603038 · Cited by 564 · see citing works
Coaxial Fiber Supercapacitor Using All-Carbon Material Electrodes
Le, V. T., Kim, H., Ghosh, A., et al. (2013) · ACS Nano · doi:10.1021/nn4016345 · Cited by 530 · see citing works
Li, R., Wang, Y., Zhou, C., Wang, C., Ba, X. W., Li, Y., Huang, X., & Liu, J. (2015) · Advanced Functional Materials · doi:10.1002/adfm.201502265 · Cited by 494 · see citing works
Self-citationAn Aqueous Rechargeable Zn//Co 3 O 4 Battery with High Energy Density and Good Cycling Behavior
Wang, X., Wang, F., Wang, L., et al. (2016) · Advanced Materials · doi:10.1002/adma.201505370 · Cited by 494 · see citing works
Flexible and Weaveable Capacitor Wire Based on a Carbon Nanocomposite Fiber
Ren, J., Bai, W., Guan, G., et al. (2013) · Advanced Materials · doi:10.1002/adma.201302498 · Cited by 480 · see citing works
Advanced Ti‐Doped Fe2O3@PEDOT Core/Shell Anode for High‐Energy Asymmetric Supercapacitors
Zeng, Y., Han, Y., Zhao, Y., Zeng, Y., Yu, M., Liu, Y., Tang, H., Tong, Y., & Lu, X. (2015) · Advanced Energy Materials · doi:10.1002/aenm.201402176 · Cited by 472 · see citing works
Huang, Y., Hu, H., Huang, Y., Zhu, M., Meng, W., Liu, C., Pei, Z., Hao, C., Wang, Z., & Zhi, C. (2015) · ACS Nano · doi:10.1021/acsnano.5b00860 · Cited by 457 · see citing works
Self-citationAn Integrated “Energy Wire” for both Photoelectric Conversion and Energy Storage
Chen, T., Qiu, L., Yang, Z., et al. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201207023 · Cited by 441 · see citing works
Fiber‐Based Flexible All‐Solid‐State Asymmetric Supercapacitors for Integrated Photodetecting System
Wang, X., Liu, B., Liu, R., et al. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201307581 · Cited by 432 · see citing works
All Metal Nitrides Solid‐State Asymmetric Supercapacitors
Zhu, C., Yang, P., Chao, D., et al. (2015) · Advanced Materials · doi:10.1002/adma.201501838 · Cited by 418 · see citing works
Wang, H., Liang, Y., Gong, M., Li, Y., Chang, W., Mefford, J. T., Zhou, J., Wang, J., Regier, T., Wei, F., et al. (2012) · Nature Communications · doi:10.1038/ncomms1921 · Cited by 411 · see citing works
A Flexible Alkaline Rechargeable Ni/Fe Battery Based on Graphene Foam/Carbon Nanotubes Hybrid Film
Liu, J., Chen, M., Zhang, L., et al. (2014) · Nano Letters · doi:10.1021/nl503852m · Cited by 378 · see citing works
Magnetic-Assisted, Self-Healable, Yarn-Based Supercapacitor
Huang, Y., Huang, Y., Zhu, M., Meng, W., Pei, Z., Liu, C., Hu, H., & Zhi, C. (2015) · ACS Nano · doi:10.1021/acsnano.5b01602 · Cited by 372 · see citing works
Self-citationThe state of the oxygen at the surface of polycrystalline cobalt oxide
Jimenez, V. M., Jr., Fernández, A., Espinós, J. P., & González-Elipe, A. R. (1995) · Journal of Electron Spectroscopy and Related Phenomena · doi:10.1016/0368-2048(94)02238-0 · Cited by 345 · see citing works
Guan, C., Zhao, W., Hu, Y., et al. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201601034 · Cited by 295 · see citing works
Tao, J., Liu, N., Ma, W., Ding, L., Li, L., Su, J., & Gao, Y. (2013) · Scientific Reports · doi:10.1038/srep02286 · Cited by 287 · see citing works
Liu, N., Ma, W., Tao, J., et al. (2013) · Advanced Materials · doi:10.1002/adma.201301311 · Cited by 285 · see citing works
Yu, D., Goh, K., Zhang, Q., et al. (2014) · Advanced Materials · doi:10.1002/adma.201403061 · Cited by 262 · see citing works
Lee, D. U., Fu, J., Park, M. G., Liu, H., Kashkooli, A. G., & Chen, Z. (2016) · Nano Letters · doi:10.1021/acs.nanolett.5b04788 · Cited by 252 · see citing works
Zeng, Y., Lin, Z., Meng, Y. Z., et al. (2016) · Advanced Materials · doi:10.1002/adma.201603304 · Cited by 250 · see citing works
Highly Flexible, Printed Alkaline Batteries Based on Mesh‐Embedded Electrodes
Gaikwad, A. M., Whiting, G. L., Steingart, D. A., & Arias, A. C. (2011) · Advanced Materials · doi:10.1002/adma.201100894 · Cited by 248 · see citing works
Xu, C., Liao, J., Yang, C., et al. (2016) · Nano Energy · doi:10.1016/j.nanoen.2016.07.035 · Cited by 237 · see citing works
Yu, M., Han, Y., Cheng, X., et al. (2015) · Advanced Materials · doi:10.1002/adma.201500493 · Cited by 197 · see citing works
Xia, C., Chen, W., Wang, X., Hedhili, M. N., Wei, N., & Alshareef, H. N. (2015) · Advanced Energy Materials · doi:10.1002/aenm.201401805 · Cited by 174 · see citing works
Thread‐like Supercapacitors Based on One‐Step Spun Nanocomposite Yarns
Meng, Q., Wang, K. Y., Guo, W. H., et al. (2014) · Small · doi:10.1002/smll.201303419 · Cited by 158 · see citing works
High Performance Zn/LiFePO4 Aqueous Rechargeable Battery for Large Scale Applications
Yesibolati, M. N., Umirov, N., Koishybay, A., et al. (2014) · Electrochimica Acta · doi:10.1016/j.electacta.2014.11.168 · Cited by 153 · see citing works
See, D. M., & White, R. E. (1997) · Journal of Chemical & Engineering Data · doi:10.1021/je970140x · Cited by 141 · see citing works
Lee, J. H., Lee, H. J., Lim, S. Y., Chae, K. H., Park, S. H., Chung, K. Y., Deniz, E., & Choi, J. W. (2016) · Advanced Functional Materials · doi:10.1002/adfm.201605225 · Cited by 85 · see citing works
An aqueous rechargeable lithium battery based on doping and intercalation mechanisms
Wang, G. J., Yang, L., Qu, Q. T., et al. (2009) · Journal of Solid State Electrochemistry · doi:10.1007/s10008-009-0869-3 · Cited by 72 · see citing works
Fabrication of micro lithium-ion battery with 3D anode and 3D cathode by using polymer wall
Yoshima, K., Munakata, H., & Kanamura, K. (2012) · Journal of Power Sources · doi:10.1016/j.jpowsour.2012.02.045 · Cited by 67 · see citing works
Sun, J., Wang, J., Li, Z., Niu, L., Hong, W. L., & Yang, S. (2014) · Journal of Power Sources · doi:10.1016/j.jpowsour.2014.10.172 · Cited by 57 · see citing works
Self-citationHigh-performance aqueous battery with double hierarchical nanoarrays
Wu, X., Lu, Z., Zhu, W. D., et al. (2014) · Nano Energy · doi:10.1016/j.nanoen.2014.07.026 · Cited by 29 · see citing works
Flagged first, then by citations
Cited by
Sorted by citations
Wearable biosensors for healthcare monitoring
Kim, J., Campbell, A. S., de Ávila, B. E.-F., & Wang, J. (2019) · Nature Biotechnology · doi:10.1038/s41587-019-0045-y · Cited by 3,373 · see citing works
- Authors
- Huang, Y., Ip, W. S., Lau, Y. Y., Sun, J., Zeng, J., Yeung, N. S. S., Ng, W. S., Li, H., Pei, Z., Xue, Q., Wang, Y., Yu, J., Hu, H., & Zhi, C.
- Affiliations
- City University of Hong Kong (HK)
- University of Jinan (CN)
- Harbin Institute of Technology (CN)
- Hong Kong Polytechnic University (HK)
- Corresponding author
- Zhi, Chunyi
- ORCID
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-08-18
- Volume
- 11
- Issue
- 9
- Pages
- 8953-8961
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2749247702
- Cited by
- 352
- References
- 49
- Citations by year
- 2026: 8 · 2025: 16 · 2024: 31 · 2023: 34 · 2022: 37 · 2021: 48 · 2020: 66 · 2019: 61 · 2018: 47 · 2017: 4
- FWCI
- 20.24
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- ACS Nano (publishedVersion)
- PubMed (publishedVersion)
- PolyU Institutional Research Archive (Hong Kong Polytechnic University) (submittedVersion)
- Funders
- Research Grants Council, University Grants Committee (N_CityU123/15)
- Jinan University (1009411)
- City University of Hong Kong (PJ7004645)
- National Natural Science Foundation of China (N_CityU123/15)
- Hong Kong Polytechnic University (1-BBA3)
- Shenzhen Science and Technology Innovation Committee (JCYJ20130401145617276, R-IND4903)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Advanced battery technologies research
- Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Supercapacitor Materials and Fabrication
- Physical Sciences › Engineering › Biomedical Engineering › Advanced Sensor and Energy Harvesting Materials
- Keywords
- conductive yarns, nickel-cobalt hydroxide, zinc anode, wearable electronics, energy density, rate capability, solid electrolytes
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review