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Synthesis and Applications of Graphdiyne‐Based Metal‐Free Catalysts
Open accessAbstract
The development of carbon materials offers the hope for obtaining inexpensive and high‐performance alternatives to substitute noble‐metal catalysts for their sustainable application. Graphdiyne, the rising‐star carbon allotrope, is a big family with many members, and first realized the coexistence of sp‐ and sp 2‐hybridized carbon atoms in a 2D planar structure. Different from the prevailing carbon materials, its nonuniform distribution in the electronic structure and wide tunability in bandgap show many possibilities and special inspirations to construct new‐concept metal‐free catalysts, and provide many opportunities for achieving a catalytic activity comparable with that of noble‐metal catalysts. Herein, the recent progress in synthetic methodologies, theoretical predictions, and experimental investigations of graphdiyne for metal‐free catalysts is systematically summarized. Some new perspectives of the opportunities and challenges in developing high‐performance graphdiyne‐based metal‐free catalysts are demonstrated.
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Cites
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Anchoring zero valence single atoms of nickel and iron on graphdiyne for hydrogen evolution
Xue, Y., Huang, B., Yi, Y., Guo, Y., Zuo, Z., Li, Y., Jia, Z., Liu, H., & Li, Y. (2018) · Nature Communications · doi:10.1038/s41467-018-03896-4 · Cited by 1,011
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Cited by
2D graphdiyne: An emerging carbon material
Fang, Y., Liu, Y., Qi, L., Xue, Y., & Li, Y. (2022) · Chemical Society Reviews · doi:10.1039/d1cs00592h · Cited by 520
Self-citationHuang, H., Yan, M., Yang, C., He, H., Jiang, Q., Yang, L., Lu, Z., Sun, Z., Xu, X., Bando, Y., et al. (2019) · Advanced Materials · doi:10.1002/adma.201903415 · Cited by 454
Two-Dimensional Carbon Graphdiyne: Advances in Fundamental and Application Research
Zheng, X., Chen, S., Li, J., Wu, H., Zhang, C., Zhang, D., Chen, X., Gao, Y., He, F., Hui, L., et al. (2023) · ACS Nano · doi:10.1021/acsnano.3c03849 · Cited by 283
Self-citationCyclo[18]carbon: Insight into Electronic Structure, Aromaticity, and Surface Coupling
Baryshnikov, G. V., Valiev, R. R., Kuklin, A. V., Sundholm, D., & Ågren, H. (2019) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.9b02815 · Cited by 170
A new carbon allotrope: Graphdiyne
Zheng, Z., Xue, Y., & Li, Y. (2022) · Trends in Chemistry · doi:10.1016/j.trechm.2022.05.006 · Cited by 73
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Metadata
- Authors
- Zuo, Z., Wang, D., Zhang, J., Lu, F., & Li, Y.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2018-09-27
- Volume
- 31
- Issue
- 13
- Pages
- e1803762-e1803762
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2893795324
- Cited by
- 194
- References
- 6
- FWCI
- 8.04
- Type
- journal article
- Language
- en
- Open access
- green
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