The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Tailor‐Made Microporous Metal–Organic Frameworks for the Full Separation of Propane from Propylene Through Selective Size Exclusion
Open accessAbstract
Adsorptive separation of olefin/paraffin mixtures by porous solids can greatly reduce the energy consumption associated with the currently employed cryogenic distillation technique. Here, the complete separation of propane and propylene by a designer microporous metal–organic framework material is reported. The compound, Y 6(OH)8(abtc)3(H 2 O)6(DMA)2 (Y‐abtc, abtc = 3,3′,5,5′‐azobenzene‐tetracarboxylates; DMA = dimethylammonium), is rationally designed through topology‐guided replacement of inorganic building units. Y‐abtc is both thermally and hydrothermally robust, and possesses optimal pore window size for propane/propylene separation. It adsorbs propylene with fast kinetics under ambient temperature and pressure, but fully excludes propane, as a result of selective size exclusion. Multicomponent column breakthrough experiments confirm that polymer‐grade propylene (99.5%) can be obtained by this process, demonstrating its true potential as an alternative sorbent for efficient separation of propane/propylene mixtures.
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Citations
Cites
Seven chemical separations to change the world
Sholl, D. S., & Lively, R. P. (2016) · Nature · doi:10.1038/532435a · Cited by 4,769
Cited by
Porous metal-organic frameworks for gas storage and separation: Status and challenges
Li, H., Li, L., Lin, R.-B., Zhou, W., Zhang, Z., Xiang, S., & Chen, B. (2019) · EnergyChem · doi:10.1016/j.enchem.2019.100006 · Cited by 891
Yang, L., Qian, S., Wang, X., Cui, X., Chen, B., & Xing, H. (2020) · Chemical Society Reviews · doi:10.1039/c9cs00756c · Cited by 746
Self-citationOrthogonal-array dynamic molecular sieving of propylene/propane mixtures
Zeng, H., Xie, M., Wang, T., Wei, R.-J., Xie, X.-J., Zhao, Y., Lu, W., & Li, D. (2021) · Nature · doi:10.1038/s41586-021-03627-8 · Cited by 622
Ye, Y., Xian, S., Cui, H., Tan, K., Gong, L., Liang, B., Pham, T., Pandey, H., Krishna, R., Lan, P. C., et al. (2022) · Journal of the American Chemical Society · doi:10.1021/jacs.1c10620 · Cited by 359
Self-citationSelective Ethane/Ethylene Separation in a Robust Microporous Hydrogen-Bonded Organic Framework
Zhang, X., Li, L., Wang, J.-X., Wen, H.-M., Krishna, R., Wu, H., Zhou, W., Chen, Z.-N., Li, B., Qian, G., et al. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.9b12428 · Cited by 331
Metadata
- Authors
- Wang, H., Dong, X., Colombo, V., Wang, Q., Liu, Y., Liu, W., Wang, X., Huang, X., Proserpio, D. M., Sironi, A., Han, Y., & Li, J.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2018-10-15
- Volume
- 30
- Issue
- 49
- Pages
- e1805088-e1805088
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2897241813
- Cited by
- 352
- References
- 1
- FWCI
- 10.93
- Type
- journal article
- Language
- en
- Open access
- bronze
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- CoChat. (2026). Citation check: Tailor‐Made Microporous Metal–Organic Frameworks for the Full Separation of Propane from Propylene Through Selective Size Exclusion. https://app.cochat.ai/papers/10.1002/adma.201805088
- The paper
- Wang, H., Dong, X., Colombo, V., Wang, Q., Liu, Y., Liu, W., Wang, X., Huang, X., Proserpio, D. M., Sironi, A., Han, Y., & Li, J. (2018). Tailor‐Made Microporous Metal–Organic Frameworks for the Full Separation of Propane from Propylene Through Selective Size Exclusion. Advanced Materials. https://doi.org/10.1002/adma.201805088
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