Formation of CX Bonds in CO2 Chemical Fixation Catalyzed by Metal−Organic Frameworks
Abstract
Abstract Transformation of CO2 based on metal−organic framework (MOF) catalysts is becoming a hot research topic, not only because it will help to reduce greenhouse gas emission, but also because it will allow for the production of valuable chemicals. In addition, a large number of impressive products have been synthesized by utilizing CO2. In fact, it is the formation of new covalent bonds between CO2 and substrate molecules that successfully result in CO2 solidly inserting into the products, and only four types of new CX bonds, including CH, CC, CN, and CO bonds, are observed in this exploration. An overview of recent progress in constructing CX bonds for CO2 conversion catalyzed by various MOF catalysts is provided. The catalytic mechanism of generating different CX bonds is further discussed according to both structural features of MOFs and the interactions among CO2, substrates, as well as MOFs. The future opportunities and challenges in this field are also tentatively covered.
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New covalent bonds between CO2 and substrate molecules can be formed by constructing C-H, C-O, C-N, and C-C bonds.
“new covalent bonds between CO2 and substrate molecules can be formed by constructing C–X bonds, including C–H, C–O, C–N, and C–C bonds.290”
From Technologies and perspectives for achieving carbon neutrality (2021) · cites this paper as [290]
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References 231 · Cited by 142
- Authors
- Hou, S., Dong, J., & Zhao, B.
- Affiliations
- Nankai University (CN)
- Corresponding author
- Zhao, Bin
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2019-06-19
- Volume
- 32
- Issue
- 3
- Pages
- e1806163-e1806163
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2953126464
- Cited by
- 142
- References
- 231
- Citations by year
- 2026: 10 · 2025: 10 · 2024: 22 · 2023: 21 · 2022: 24 · 2021: 32 · 2020: 21 · 2019: 2
- FWCI
- 1.11
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Advanced Materials (publishedVersion)
- PubMed (publishedVersion)
- Funders
- National Natural Science Foundation of China (21625103, 21571107, 21421001)
- Topics
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Chemistry › Inorganic Chemistry › Metal-Organic Frameworks: Synthesis and Applications
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Keywords
- metal-organic frameworks, C–X bond formation, C-H bond formation, C–C bond formation, C–N bond formation, C–O bond formation, catalytic mechanism, CO2 insertion, greenhouse gas emissions reduction
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