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Interfacial Electronic Structure Modulation of NiTe Nanoarrays with NiS Nanodots Facilitates Electrocatalytic Oxygen Evolution

Xue, Ziqian, Li, Xia, Liu, Qinglin, Cai, Mengke, Liu, Kang, Liu, Min, Ke, Zhuofeng, Liu, Xialin, Li, Guangqin·2019·Advanced Materials

Abstract

Interface engineering has been recognized as one of the most promising strategies for regulating the physical and chemical properties of materials. However, constructing well‐defined nanointerfaces with efficient oxygen evolution reaction (OER) still remains a challenge. Herein, cross columnar NiTe nanoarrays supported on nickel foam are prepared. Subsequently, NiTe/NiS nanointerfaces are constructed by an ion‐exchange process. Importantly, the electrocatalytic performance for the OER can be facilitated by coupling NiTe and NiS. As a result, NiTe/NiS shows excellent OER activity with an ultralow overpotential of only 257 mV at a current density of 100 mA cm−2, and a Tafel slope of 49 mV dec−1 in 1.0 m KOH. The calculated and experimental results reveal that the strong electron interaction on nanointerfaces induces electronic structure modulation, which optimizes the binding energy of *OOH intermediates, thus improving the OER performance.

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Metadata

Authors
Xue, Z., Li, X., Liu, Q., Cai, M., Liu, K., Liu, M., Ke, Z., Liu, X., & Li, G.
Venue
Advanced Materials
Publisher
Wiley
Published
2019-04-08
Volume
31
Issue
21
Pages
e1900430-e1900430
ISSN
  • 0935-9648 (ISSN-L)
  • 1521-4095
OpenAlex
W2938243996
Cited by
413
References
4
FWCI
11.90
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Interfacial Electronic Structure Modulation of NiTe Nanoarrays with NiS Nanodots Facilitates Electrocatalytic Oxygen Evolution. https://app.cochat.ai/papers/10.1002/adma.201900430
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Xue, Z., Li, X., Liu, Q., Cai, M., Liu, K., Liu, M., Ke, Z., Liu, X., & Li, G. (2019). Interfacial Electronic Structure Modulation of NiTe Nanoarrays with NiS Nanodots Facilitates Electrocatalytic Oxygen Evolution. Advanced Materials. https://doi.org/10.1002/adma.201900430

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