Cited by 735Electrocatalysts for Energy ConversionSupercapacitor Materials and FabricationFuel Cells and Related Materials

Carbon-based electrocatalysts for advanced energy conversion and storage

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Zhang, Jintao, Xia, Zhenhai, Dai, Liming·2015·Science Advances

Abstract

A review of the recent advances, along with perspectives and challenges, in the fast-growing field of carbon-based electrocatalysts.

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  • 3D porous graphene aerogels show great potential for application in water splitting because of their superior conductivity, good mechanical stability, high specific surface area, and multidimensional mass-transfer pathways.

    “Three-dimensional (3D) porous graphene aerogels show great potential for application in water splitting because of their superior conductivity, good mechanical stability, high specic surface area, and multidimensional mass-transfer pathways.10,11”

    From Tunable CoFe-based active sites on 3D heteroatom doped graphene aerogel electrocatalysts <i>via</i> annealing gas regulation for efficient water splitting (2018) · cites this paper as [11]

    The Introduction (page not available) links porous 3D carbon architectures and efficient transport to high-performance electrolysis, including reactions relevant to water splitting. The sections on heteroatom-doped graphene and 3D carbon nanostructures (pages not available) describe surface area, mechanical properties, and facilitated electron or ion transport, but do not establish this combination of properties or water-splitting potential specifically for porous graphene aerogels. (LLM, conf=0.84)

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  1. [1]Dunn B., Kamath H., Tarascon J.-M., Electrical energy storage for the grid: A battery of choices. Science 334, 928– 935 (2011). 22096188
  2. [2]Cheng F., Chen J., Metal–air batteries: From oxygen reduction electrochemistry to cathode catalysts. Chem. Soc. Rev. 41, 2172– 2192 (2012). 22254234
  3. [3]Zhang J., Li C. M., Nanoporous metals: Fabrication strategies and advanced electrochemical applications in catalysis, sensing and energy systems. Chem. Soc. Rev. 41, 7016– 7031 (2012). 22975622
  4. [5]Suntivich J., Gasteiger H. A., Yabuuchi N., Nakanishi H., Goodenough J. B., Shao-Horn Y., Design principles for oxygen-reduction activity on perovskite oxide catalysts for fuel cells and metal–air batteries. Nat. Chem. 3, 546– 550 (2011). 21697876
  5. [6]Jiao Y., Zheng Y., Jaroniec M., Qiao S. Z., Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions. Chem. Soc. Rev. 44, 2060– 2086 (2015). 25672249
  6. [7]Gong K., Du F., Xia Z., Durstock M., Dai L., Nitrogen-doped carbon nanotube arrays with high electrocatalytic activity for oxygen reduction. Science 323, 760– 764 (2009). 19197058
  7. [8]Dai L., Xue Y., Qu L., Choi H.-J., Baek J.-B., Metal-free catalysts for oxygen reduction reaction. Chem. Rev. 115, 4823– 4892 (2015). 25938707
  8. [9]Qu L., Liu Y., Baek J.-B., Dai L., Nitrogen-doped graphene as efficient metal-free electrocatalyst for oxygen reduction in fuel cells. ACS Nano 4, 1321– 1326 (2010). 20155972
  9. [10]Yang Z., Yao Z., Li G., Fang G., Nie H., Liu Z., Zhou X., Chen X., Huang S., Sulfur-doped graphene as an efficient metal-free cathode catalyst for oxygen reduction. ACS Nano 6, 205– 211 (2012). 22201338
  10. [11]Chen S., Bi J., Zhao Y., Yang L., Zhang C., Ma Y., Wu Q., Wang X., Hu Z., Nitrogen-doped carbon nanocages as efficient metal-free electrocatalysts for oxygen reduction reaction. Adv. Mater. 24, 5593– 5597 (2012). 22899547
  11. [12]Jeon I.-Y., Zhang S., Zhang L., Choi H.-J., Seo J.-M., Xia Z., Dai L., Baek J.-B., Edge-selectively sulfurized graphene nanoplatelets as efficient metal-free electrocatalysts for oxygen reduction reaction: The electron spin effect. Adv. Mater. 25, 6138– 6145 (2013). 24038522
  12. [13]Liu R., Wu D., Feng X., Müllen K., Nitrogen-doped ordered mesoporous graphitic arrays with high electrocatalytic activity for oxygen reduction. Angew. Chem. Int. Ed. 49, 2565– 2569 (2010). 20217877
  13. [16]Zheng Y., Jiao Y., Chen J., Liu J., Liang J., Du A., Zhang W., Zhu Z., Smith S. C., Jaroniec M., Lu G. Q., Qiao S. Z., Nanoporous graphitic-C3N4@carbon metal-free electrocatalysts for highly efficient oxygen reduction. J. Am. Chem. Soc. 133, 20116– 20119 (2011). 22082332
  14. [18]Yang L., Jiang S., Zhao Y., Zhu L., Chen S., Wang X., Wu Q., Ma J., Ma Y., Hu Z., Boron-doped carbon nanotubes as metal-free electrocatalysts for the oxygen reduction reaction. Angew. Chem. Int. Ed. 50, 7132– 7135 (2011). 21688363
  15. [19]Zheng Y., Jiao Y., Ge L., Jaroniec M., Qiao S. Z., Two-step boron and nitrogen doping in graphene for enhanced synergistic catalysis. Angew. Chem. Int. Ed. 52, 3110– 3116 (2013). 23341193
  16. [20]Wang S., Zhang L., Xia Z., Roy A., Chang D. W., Baek J.-B., Dai L., BCN graphene as efficient metal-free electrocatalyst for the oxygen reduction reaction. Angew. Chem. Int. Ed. 51, 4209– 4212 (2012). 22431416
  17. [21]Jeon I.-Y., Choi H.-J., Choi M., Seo J.-M., Jung S.-M., Kim M.-J., Zhang S., Zhang L., Xia Z., Dai L., Park N., Baek J.-B., Facile, scalable synthesis of edge-halogenated graphene nanoplatelets as efficient metal-free eletrocatalysts for oxygen reduction reaction. Sci. Rep. 3, 1810 (2013). 23736800 PMC3672906
  18. [23]Wang S., Yu D., Dai L., Polyelectrolyte functionalized carbon nanotubes as efficient metal-free electrocatalysts for oxygen reduction. J. Am. Chem. Soc. 133, 5182– 5185 (2011). 21413707
  19. [24]Wang S., Yu D., Dai L., Chang D. W., Baek J.-B., Polyelectrolyte-functionalized graphene as metal-free electrocatalysts for oxygen reduction. ACS Nano 5, 6202– 6209 (2011). 21780760
  20. [25]Shui J., Wang M., Du F., Dai L., N-doped carbon nanomaterials are durable catalysts for oxygen reduction reaction in acidic fuel cells. Sci. Adv. 1, e1400129 (2015). 26601132 PMC4644083
  21. [26]Liu J., Liu Y., Liu N., Han Y., Zhang X., Huang H., Lifshitz Y., Lee S.-T., Zhong J., Kang Z., Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway. Science 347, 970– 974 (2015). 25722405
  22. [28]Zhang S., Kang P., Ubnoske S., Brennaman M. K., Song N., House R. L., Glass J. T., Meyer T. J., Polyethylenimine-enhanced electrocatalytic reduction of CO2 to formate at nitrogen-doped carbon nanomaterials. J. Am. Chem. Soc. 136, 7845– 7848 (2014). 24779427
  23. [29]Xue Y., Liu J., Chen H., Wang R., Li D., Qu J., Dai L., Nitrogen-doped graphene foams as metal-free counter electrodes in high-performance dye-sensitized solar cells. Angew. Chem. Int. Ed. 51, 12124– 12127 (2012). 23124846
  24. [30]Zhang J., Zhao Z., Xia Z., Dai L., A metal-free bifunctional electrocatalyst for oxygen reduction and oxygen evolution reactions. Nat. Nanotechnol. 10, 444– 452 (2015). 25849787
  25. [31]Zhao Y., Nakamura R., Kamiya K., Nakanishi S., Hashimoto K., Nitrogen-doped carbon nanomaterials as non-metal electrocatalysts for water oxidation. Nat. Commun. 4, 2390 (2013). 23979080
  26. [32]Kumar B., Asadi M., Pisasale D., Sinha-Ray S., Rosen B. A., Haasch R., Abiade J., Yarin A. L., Salehi-Khojin A., Renewable and metal-free carbon nanofibre catalysts for carbon dioxide reduction. Nat. Commun. 4, 2819 (2013).
  27. [33]Zheng Y., Jiao Y., Jaroniec M., Qiao S. Z., Advancing the electrochemistry of the hydrogen-evolution reaction through combining experiment and theory. Angew. Chem. Int. Ed. 54, 52– 65 (2015). 25384712
  28. [34]Su D. S., Perathoner S., Centi G., Nanocarbons for the development of advanced catalysts. Chem. Rev. 113, 5782– 5816 (2013). 23721498
  29. [35]Dai L., Chang D. W., Baek J.-B., Lu W., Carbon nanomaterials for advanced energy conversion and storage. Small 8, 1130– 1166 (2012). 22383334
  30. [40]Zhang J., Guo C., Zhang L., Li C. M., Direct growth of flower-like manganese oxide on reduced graphene oxide towards efficient oxygen reduction reaction. Chem. Commun. 49, 6334–6336 (2013). 23745182
  31. [44]Suntivich J., May K. J., Gasteiger H. A., Goodenough J. B., Shao-Horn Y., A perovskite oxide optimized for oxygen evolution catalysis from molecular orbital principles. Science 334, 1383– 1385 (2011). 22033519
  32. [45]Ramani V., Kunz H. R., Fenton J. M., The polymer electrolyte fuel cell. Electrochem. Soc. Interface 13, 17 (2004).
  33. [46]Goodenough J. B., Evolution of strategies for modern rechargeable batteries. Acc. Chem. Res. 46, 1053– 1061 (2013). 22746097
  34. [47]Zhang H., Shen P. K., Recent development of polymer electrolyte membranes for fuel cells. Chem. Rev. 112, 2780– 2832 (2012). 22339373
  35. [51]Su D. S., Sun G., Nonprecious-metal catalysts for low-cost fuel cells. Angew. Chem. Int. Ed. 50, 11570–11572 (2011). 22031458
  36. [53]Bashyam R., Zelenay P., A class of non-precious metal composite catalysts for fuel cells. Nature 443, 63– 66 (2006). 16957726
  37. [55]Lefèvre M., Proietti E., Jaouen F., Dodelet J.-P., Iron-based catalysts with improved oxygen reduction activity in polymer electrolyte fuel cells. Science 324, 71– 74 (2009). 19342583
  38. [56]Zhao Y., Watanabe K., Hashimoto K., Self-supporting oxygen reduction electrocatalysts made from a nitrogen-rich network polymer. J. Am. Chem. Soc. 134, 19528– 19531 (2012). 23151016
  39. [58]Su D. S., Zhang J., Frank B., Thomas A., Wang X., Paraknowitsch J., Schlögl R., Metal-free heterogeneous catalysis for sustainable chemistry. ChemSusChem 3, 169– 180 (2010). 20127789
  40. [61]Kim H., Lee K., Woo S. I., Jung Y., On the mechanism of enhanced oxygen reduction reaction in nitrogen-doped graphene nanoribbons. Phys. Chem. Chem. Phys. 13, 17505– 17510 (2011). 21946759
  41. [62]Yuan W., Zhou Y., Li Y., Li C., Peng H., Zhang J., Liu Z., Dai L., Shi G., The edge- and basal-plane-specific electrochemistry of a single-layer graphene sheet. Sci. Rep. 3, 2248 (2013). 23896697 PMC3727060
  42. [63]Shen A., Zou Y., Wang Q., Dryfe R. A. W., Huang X., Dou S., Dai L., Wang S., Oxygen reduction reaction in a droplet on graphite: Direct evidence that the edge is more active than the basal plane. Angew. Chem. Int. Ed. 53, 10804– 10808 (2014). 25124986
  43. [64]Yu D., Zhang Q., Dai L., Highly efficient metal-free growth of nitrogen-doped single-walled carbon nanotubes on plasma-etched substrates for oxygen reduction. J. Am. Chem. Soc. 132, 15127– 15129 (2010). 20929222
  44. [70]Maldonado S., Stevenson K. J., Influence of nitrogen doping on oxygen reduction electrocatalysis at carbon nanofiber electrodes. J. Phys. Chem. B 109, 4707– 4716 (2005). 16851552
  45. [71]Wiggins-Camacho J. D., Stevenson K. J., Effect of nitrogen concentration on capacitance, density of states, electronic conductivity, and morphology of N-doped carbon nanotube electrodes. J. Phys. Chem. C 113, 19082 (2009).
  46. [73]Xiang Z., Cao D., Huang L., Shui J., Wang M., Dai L., Nitrogen-doped holey graphitic carbon from 2D covalent organic polymers for oxygen reduction. Adv. Mater. 26, 3315– 3320 (2014). 24664790
  47. [74]Xiang Z., Xue Y., Cao D., Huang L., Chen J.-F., Dai L., Highly efficient electrocatalysts for oxygen reduction based on 2D covalent organic polymers complexed with non-precious metals. Angew. Chem. Int. Ed. 53, 2433– 2437 (2014). 24477972
  48. [76]Sharifi T., Hu G., Jia X., Wågberg T., Formation of active sites for oxygen reduction reactions by transformation of nitrogen functionalities in nitrogen-doped carbon nanotubes. ACS Nano 6, 8904– 8912 (2012). 23020173
  49. [77]Wang Z., Jia R., Zheng J., Zhao J., Li L., Song J., Zhu Z., Nitrogen-promoted self-assembly of N-doped carbon nanotubes and their intrinsic catalysis for oxygen reduction in fuel cells. ACS Nano 5, 1677– 1684 (2011). 21309566
  50. [79]Chung H. T., Won J. H., Zelenay P., Active and stable carbon nanotube/nanoparticle composite electrocatalyst for oxygen reduction. Nat. Commun. 4, 1922 (2013). 23715281 PMC3674270
  51. [81]Sidik R. A., Anderson A. B., Subramanian N. P., Kumaraguru S. P., Popov B. N., O2 reduction on graphite and nitrogen-doped graphite: Experiment and theory. J. Phys. Chem. B 110, 1787– 1793 (2006). 16471746
  52. [83]Wang L., Ambrosi A., Pumera M., “Metal-free” catalytic oxygen reduction reaction on heteroatom-doped graphene is caused by trace metal impurities. Angew. Chem. Int. Ed. 52, 13818– 13821 (2013). 24490277
  53. [84]Wang L., Pumera M., Residual metallic impurities within carbon nanotubes play a dominant role in supposedly “metal-free” oxygen reduction reactions. Chem. Commun. 50, 12662– 12664 (2014). 25204561
  54. [85]Yang W., Fellinger T.-P., Antonietti M., Efficient metal-free oxygen reduction in alkaline medium on high-surface-area mesoporous nitrogen-doped carbons made from ionic liquids and nucleobases. J. Am. Chem. Soc. 133, 206– 209 (2011). 21155583
  55. [86]Liang J., Zheng Y., Chen J., Liu J., Hulicova-Jurcakova D., Jaroniec M., Qiao S. Z., Facile oxygen reduction on a three-dimensionally ordered macroporous graphitic C3N4/carbon composite electrocatalyst. Angew. Chem. Int. Ed. 51, 3892– 3896 (2012). 22389097
  56. [89]Wang S., Iyyamperumal E., Roy A., Xue Y., Yu D., Dai L., Vertically aligned BCN nanotubes as efficient metal-free electrocatalysts for the oxygen reduction reaction: A synergetic effect by co-doping with boron and nitrogen. Angew. Chem. Int. Ed. 50, 11756– 11760 (2011). 21990139
  57. [90]Zhao Y., Yang L., Chen S., Wang X., Ma Y., Wu Q., Jiang Y., Qian W., Hu Z., Can boron and nitrogen co-doping improve oxygen reduction reaction activity of carbon nanotubes? J. Am. Chem. Soc. 135, 1201– 1204 (2013). 23317479
  58. [91]Yu D., Xue Y., Dai L., Vertically aligned carbon nanotube arrays co-doped with phosphorus and nitrogen as efficient metal-free electrocatalysts for oxygen reduction. J. Phys. Chem. Lett. 3, 2863– 2870 (2012). 26704072
  59. [92]Choi C. H., Park S. H., Woo S. I., Binary and ternary doping of nitrogen, boron, and phosphorus into carbon for enhancing electrochemical oxygen reduction activity. ACS Nano 6, 7084– 7091 (2012). 22769428
  60. [95]Dai L., Functionalization of graphene for efficient energy conversion and storage. Acc. Chem. Res. 46, 31– 42 (2013). 23030244
  61. [96]Tang Q., Zhou Z., Chen Z., Graphene-related nanomaterials: Tuning properties by functionalization. Nanoscale 5, 4541– 4583 (2013). 23443470
  62. [97]Novoselov K. S., Fal’ko V. I., Colombo L., Gellert P. R., Schwab M. G., Kim K., A roadmap for graphene. Nature 490, 192– 200 (2012). 23060189
  63. [99]Feng L., Chen Y., Chen L., Easy-to-operate and low-temperature synthesis of gram-scale nitrogen-doped graphene and its application as cathode catalyst in microbial fuel cells. ACS Nano 5, 9611– 9618 (2011). 22029637
  64. [101]Zheng Y., Jiao Y., Jaroniec M., Jin Y., Qiao S. Z., Nanostructured metal-free electrochemical catalysts for highly efficient oxygen reduction. Small 8, 3550– 3566 (2012). 22893586
  65. [102]Wang X., Maeda K., Thomas A., Takanabe K., Xin G., Carlsson J. M., Domen K., Antonietti M., A metal-free polymeric photocatalyst for hydrogen production from water under visible light. Nat. Mater. 8, 76– 80 (2009). 18997776
  66. [104]Vinu A., Ariga K., Mori T., Nakanishi T., Hishita S., Golberg D., Bando Y., Preparation and characterization of well-ordered hexagonal mesoporous carbon nitride. Adv. Mater. 17, 1648 (2005).
  67. [107]Sun Y., Li C., Xu Y., Bai H., Yao Z., Shi G., Chemically converted graphene as substrate for immobilizing and enhancing the activity of a polymeric catalyst. Chem. Commun. 46, 4740– 4742 (2010). 20502842
  68. [108]Yang S., Feng X., Wang X., Müllen K., Graphene-based carbon nitride nanosheets as efficient metal-free electrocatalysts for oxygen reduction reactions. Angew. Chem. Int. Ed. 50, 5339– 5343 (2011). 21557411
  69. [109]Hummers W. S. Jr, Offeman R. E., Preparation of graphitic oxide. J. Am. Chem. Soc. 80, 1339 (1958).
  70. [110]Park S., Ruoff R. S., Chemical methods for the production of graphenes. Nat. Nanotechnol. 4, 217– 224 (2009). 19350030
  71. [112]Sheng Z.-H., Shao L., Chen J.-J., Bao W.-J., Wang F.-B., Xia X.-H., Catalyst-free synthesis of nitrogen-doped graphene via thermal annealing graphite oxide with melamine and its excellent electrocatalysis. ACS Nano 5, 4350– 4358 (2011). 21574601
  72. [116]Liu Z.-W., Peng F., Wang H.-J., Yu H., Zheng W.-X., Yang J., Phosphorus-doped graphite layers with high electrocatalytic activity for the O2 reduction in an alkaline medium. Angew. Chem. Int. Ed. 50, 3257– 3261 (2011). 21381161
  73. [119]Jeon I.-Y., Shin Y.-R., Sohn G.-J., Choi H.-J., Bae S.-Y., Mahmood J., Jung S.-M., Seo J.-M., Kim M.-J., Wook Chang D., Dai L., Baek J.-B., Edge-carboxylated graphene nanosheets via ball milling. Proc. Natl. Acad. Sci. U.S.A. 109, 5588– 5593 (2012). 22454492 PMC3326447
  74. [120]Jeon I.-Y., Choi H.-J., Ju M. J., Choi I. T., Lim K., Ko J., Kim H. K., Kim J. C., Lee J.-J., Shin D., Jung S.-M., Seo J.-M., Kim M.-J., Park N., Dai L., Baek J.-B., Direct nitrogen fixation at the edges of graphene nanoplatelets as efficient electrocatalysts for energy conversion. Sci. Rep. 3, 2260 (2013). 23877200 PMC3719072
  75. [123]Yu D., Goh K., Wang H., Wei L., Jiang W., Zhang Q., Dai L., Chen Y., Scalable synthesis of hierarchically structured carbon nanotube–graphene fibres for capacitive energy storage. Nat. Nanotechnol. 9, 555– 562 (2014). 24813695
  76. [125]Xue Y., Yu D., Dai L., Wang R., Li D., Roy A., Lu F., Chen H., Liu Y., Qu J., Three-dimensional B,N-doped graphene foam as a metal-free catalyst for oxygen reduction reaction. Phys. Chem. Chem. Phys. 15, 12220– 12226 (2013). 23770584
  77. [126]Zhang J., Zhao X. S., On the configuration of supercapacitors for maximizing electrochemical performance. ChemSusChem 5, 818– 841 (2012). 22550045
  78. [127]Yang D.-S., Bhattacharjya D., Inamdar S., Park J., Yu J.-S., Phosphorus-doped ordered mesoporous carbons with different lengths as efficient metal-free electrocatalysts for oxygen reduction reaction in alkaline media. J. Am. Chem. Soc. 134, 16127– 16130 (2012). 22966761
  79. [128]Silva R., Voiry D., Chhowalla M., Asefa T., Efficient metal-free electrocatalysts for oxygen reduction: Polyaniline-derived N- and O-doped mesoporous carbons. J. Am. Chem. Soc. 135, 7823– 7826 (2013). 23646856
  80. [129]Liu Z., Nie H., Yang Z., Zhang J., Jin Z., Lu Y., Xiao Z., Huang S., Sulfur–nitrogen co-doped three-dimensional carbon foams with hierarchical pore structures as efficient metal-free electrocatalysts for oxygen reduction reactions. Nanoscale 5, 3283– 3288 (2013). 23474547
  81. [130]Li Y., Zhou W., Wang H., Xie L., Liang Y., Wei F., Idrobo J.-C., Pennycook S. J., Dai H., An oxygen reduction electrocatalyst based on carbon nanotube graphene complexes. Nat. Nanotechnol. 7, 394– 400 (2012). 22635099
  82. [131]Kwon K., Sa Y. J., Cheon J. Y., Joo S. H., Ordered mesoporous carbon nitrides with graphitic frameworks as metal-free, highly durable, methanol-tolerant oxygen reduction catalysts in an acidic medium. Langmuir 28, 991– 996 (2011). 22122162
  83. [133]Armand M., Tarascon J.-M., Building better batteries. Nature 451, 652– 657 (2008). 18256660
  84. [136]Choi N.-S., Chen Z., Freunberger S. A., Ji X., Sun Y.-K., Amine K., Yushin G., Nazar L. F., Cho J., Bruce P. G., Challenges facing lithium batteries and electrical double-layer capacitors. Angew. Chem. Int. Ed. 51, 9994– 10024 (2012). 22965900
  85. [139]Kraytsberg A., Ein-Eli Y., Review on Li–air batteries—Opportunities, limitations and perspective. J. Power Sources 196, 886– 893 (2011).
  86. [144]Lim H.-D., Park K.-Y., Song H., Jang E. Y., Gwon H., Kim J., Kim Y. H., Lima M. D., Robles R. O., Lepró X., Baughman R. H., Kang K., Enhanced power and rechargeability of a Li–O2 battery based on a hierarchical-fibril CNT electrode. Adv. Mater. 25, 1348– 1352 (2013). 23255225
  87. [145]Zhang T., Zhou H., From Li–O2 to Li–air batteries: Carbon nanotubes/ionic liquid gels with a tricontinuous passage of electrons, ions, and oxygen. Angew. Chem. Int. Ed. 51, 11062–11067 (2012). 23023966
  88. [146]Xiao J., Mei D., Li X., Xu W., Wang D., Graff G. L., Bennett W. D., Nie Z., Saraf L. V., Aksay I. A., Liu J., Zhang J.-G., Hierarchically porous graphene as a lithium–air battery electrode. Nano Lett. 11, 5071– 5078 (2011). 21985448
  89. [147]Gerbig O., Merkle R., Maier J., Electron and ion transport in Li2O2. Adv. Mater. 25, 3129–3133 (2013). 23649710
  90. [148]Chen Y., Freunberger S. A., Peng Z., Fontaine O., Bruce P. G., Charging a Li–O2 battery using a redox mediator. Nat. Chem. 5, 489– 494 (2013). 23695630
  91. [149]Zhong L., Mitchell R. R., Liu Y., Gallant B. M., Thompson C. V., Huang J. Y., Mao S. X., Shao-Horn Y., In situ transmission electron microscopy observations of electrochemical oxidation of Li2O2. Nano Lett. 13, 2209– 2214 (2013). 23586606
  92. [150]Ottakam Thotiyl M. M., Freunberger S. A., Peng Z., Bruce P. G., The carbon electrode in nonaqueous Li-O2 cells. J. Am. Chem. Soc. 135, 494– 500 (2013). 23190204
  93. [151]Lu Y.-C., Shao-Horn Y., Probing the reaction kinetics of the charge reactions of nonaqueous Li-O2 batteries. J. Phys. Chem. Lett. 4, 93– 99 (2013). 26291218
  94. [152]Ryu W.-H., Yoon T.-H., Song S. H., Jeon S., Park Y.-J., Kim I.-D., Bifunctional composite catalysts using Co3O4 nanofibers immobilized on nonoxidized graphene nanoflakes for high-capacity and long-cycle Li-O2 batteries. Nano Lett. 13, 4190– 4197 (2013). 23924512
  95. [155]Shui J., Du F., Xue C., Li Q., Dai L., Vertically aligned N-doped coral-like carbon fiber arrays as efficient air electrodes for high-performance nonaqueous Li-O2 batteries. ACS Nano 8, 3015– 3022 (2014). 24568304
  96. [156]Sakaushi K., Fellinger T.-P., Antonietti M., Bifunctional metal-free catalysis of mesoporous noble carbons for oxygen reduction and evolution reactions. ChemSusChem 8, 1156– 1160 (2015). 25739370
  97. [159]Yoo E., Zhou H., Li–air rechargeable battery based on metal-free graphene nanosheet catalysts. ACS Nano 5, 3020– 3026 (2011). 21438513
  98. [160]Cao R., Thapa R., Kim H., Xu X., Gyu Kim M., Li Q., Park N., Liu M., Cho J., Promotion of oxygen reduction by a bio-inspired tethered iron phthalocyanine carbon nanotube-based catalyst. Nat. Commun. 4, 2076 (2013). 23797710
  99. [163]Gorlin Y., Jaramillo T. F., A bifunctional nonprecious metal catalyst for oxygen reduction and water oxidation. J. Am. Chem. Soc. 132, 13612– 13614 (2010). 20839797
  100. [164]Cheng F., Shen J., Peng B., Pan Y., Tao Z., Chen J., Rapid room-temperature synthesis of nanocrystalline spinels as oxygen reduction and evolution electrocatalysts. Nat. Chem. 3, 79– 84 (2011). 21160522
  101. [165]Chen Z., Yu A., Higgins D., Li H., Wang H., Chen Z., Highly active and durable core–corona structured bifunctional catalyst for rechargeable metal-air battery application. Nano Lett. 12, 1946– 1952 (2012). 22372510
  102. [166]Li B., Geng D., Lee X. S., Ge X., Chai J., Wang Z., Zhang J., Liu Z., Hor T. S. A., Zong Y., Eggplant-derived microporous carbon sheets: Towards mass production of efficient bifunctional oxygen electrocatalysts at low cost for rechargeable Zn–air batteries. Chem. Commun. 51, 8841– 8844 (2015). 25920952
  103. [167]Pan L., Yu G., Zhai D., Lee H. R., Zhao W., Liu N., Wang H., Tee B. C.-K., Shi Y., Cui Y., Bao Z., Hierarchical nanostructured conducting polymer hydrogel with high electrochemical activity. Proc. Natl. Acad. Sci. U.S.A. 109, 9287– 9292 (2012). 22645374 PMC3386113
  104. [168]Du G., Liu X., Zong Y., Hor T. S. A., Yu A., Liu Z., Co3O4 nanoparticle-modified MnO2 nanotube bifunctional oxygen cathode catalysts for rechargeable zinc–air batteries. Nanoscale 5, 4657– 4661 (2013). 23608821
  105. [175]Jiao Y., Zheng Y., Jaroniec M., Qiao S. Z., Origin of the electrocatalytic oxygen reduction activity of graphene-based catalysts: A roadmap to achieve the best performance. J. Am. Chem. Soc. 136, 4394– 4403 (2014). 24580116 PMC3986026

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Authors
Zhang, J., Xia, Z., & Dai, L.
Affiliations
  • Case Western Reserve University (US)
  • University of North Texas (US)
Corresponding author
Dai, Liming
Venue
Science Advances
Published
2015-08-07
Volume
1
Issue
7
Pages
e1500564-e1500564
ISSN
2375-2548 (ISSN-L)
OpenAlex
W2180059240
Cited by
735
References
6
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journal article
Language
en
Open access
Licence
cc-by-nc
Locations
  • Science Advances (publishedVersion, cc-by-nc)
  • PubMed Central (publishedVersion, cc-by-nc)
  • PubMed (publishedVersion)
  • University of North Texas Digital Library (University of North Texas) (submittedVersion)
Funders
  • National Science Foundation (ID0ELPAE2082, CMMI-1400274, CMMI-1266295, AIR-IIP-1343270, DMR-1106160)
  • Air Force Office of Scientific Research (ID0EIUAE2083, FA9550-12-1-0069, FA9550-12-1-0037, RQ20-CWRU-13-4)
Topics
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
  • Physical Sciences › Materials Science › Electronic, Optical and Magnetic Materials › Supercapacitor Materials and Fabrication
  • Physical Sciences › Engineering › Electrical and Electronic Engineering › Fuel Cells and Related Materials
Keywords
carbon-based electrocatalysts, metal-free electrocatalysts, oxygen reduction reaction, oxygen evolution reaction, fuel cells, metal-air batteries, carbon nanotubes, graphene, C60, graphite, electrochemical energy storage, electrochemical energy conversion

About these checks

Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.

Statistics and arithmetic are recomputed, not judged.

Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.

What counts as a claim ›How we measure confidence ›How we check this ›

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