Complex Hydrides for Energy Storage, Conversion, and Utilization

Synthesis and hydrolysis of NaZn(BH 4 ) 3 and its ammoniates

Wang, M., Ouyang, L., Peng, C., et al. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta05082h · Cited by 38

Synthesis, structure and dehydrogenation of zirconium borohydride octaammoniate

Huang, J., Tan, Y., Su, J., Gu, Q., Černý, R., Ouyang, L., Sun, D., Yu, X., & Zhu, M. (2014) · Chemical Communications · doi:10.1039/c4cc09317h · Cited by 37

From Exothermic to Endothermic Dehydrogenation – Interaction of Monoammoniate of Magnesium Amidoborane and Metal Hydrides

Chua, Y. S., Li, W., Wu, G., et al. (2012) · Chemistry of Materials · doi:10.1021/cm301662q · Cited by 37

Destabilisation of Ca(BH 4 ) 2 and Mg(BH 4 ) 2 via confinement in nanoporous Cu 2 S hollow spheres

Lai, Q., & Aguey‐Zinsou, K. (2017) · Sustainable Energy & Fuels · doi:10.1039/c7se00121e · Cited by 37

Complex hydrides as thermal energy storage materials: characterisation and thermal decomposition of Na 2 Mg 2 NiH 6

Humphries, T. D., Sheppard, D. A., Li, G., et al. (2018) · Journal of Materials Chemistry A · doi:10.1039/c8ta00822a · Cited by 37

Synthesis, structures and hydrogen storage properties of two new H-enriched compounds: Mg(BH4)2(NH3BH3)2 and Mg(BH4)2·(NH3)2(NH3BH3)

Chen, X., Yuan, F., Gu, Q., et al. (2013) · Dalton Transactions · doi:10.1039/c3dt52203b · Cited by 36

Stabilization of volatile Ti(BH 4 ) 3 by nano-confinement in a metal–organic framework

Callini, E., Szilágyi, P. Á., Paskevicius, M., Stadie, N. P., Réhault, J., Buckley, C. E., Borgschulte, A., & Züttel, A. (2015) · Chemical Science · doi:10.1039/c5sc03517a · Cited by 35

Mechanisms of reversible hydrogen storage in NaBH4 through NdF3 addition

Chong, L., Zou, J., Zeng, X., et al. (2013) · Journal of Materials Chemistry A · doi:10.1039/c3ta01105d · Cited by 35

A novel catalytic route for hydrogenation–dehydrogenation of 2LiH + MgB 2 via in situ formed core–shell Li x TiO 2 nanoparticles

Puszkiel, J., Riglos, M. V. C., Lopez, J., et al. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta03117c · Cited by 35

Porous Ni@C derived from bimetallic Metal–Organic Frameworks and its application for improving LiBH4 dehydrogenation

Meng, X., Wan, C., Wang, Y., et al. (2017) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2017.11.191 · Cited by 35

Metal cation-promoted hydrogen generation in activated aluminium borohydride ammoniates

Tang, Z., Tan, Y., Wu, H., et al. (2013) · Acta Materialia · doi:10.1016/j.actamat.2013.05.003 · Cited by 33

Air-stable metal hydride-polymer composites of Mg(NH2)2–LiH and TPX™

Cao, H., Georgopanos, P., Capurso, G., et al. (2018) · Materials Today Energy · doi:10.1016/j.mtener.2018.08.008 · Cited by 33

Fe 3 O 4 nanoclusters highly dispersed on a porous graphene support as an additive for improving the hydrogen storage properties of LiBH 4

Xu, G., Zhang, W., Zhang, Y., et al. (2018) · RSC Advances · doi:10.1039/c8ra02762e · Cited by 32

TiN catalyst for the reversible hydrogen storage performance of sodium alanate system

Li, L., Qiu, F., Wang, Y., et al. (2012) · Journal of Materials Chemistry · doi:10.1039/c2jm31388j · Cited by 31

Alkali and alkaline-earth metal borohydride hydrazinates: synthesis, structures and dehydrogenation

He, T., Wu, H., Chen, J., et al. (2013) · Physical Chemistry Chemical Physics · doi:10.1039/c3cp51473k · Cited by 31

Halide Free M(BH4)2 (M = Sr, Ba, and Eu) Synthesis, Structure, and Decomposition

Sharma, M., Didelot, E., Spyratou, A., Daku, L. M. L., Černý, R., & Hagemann, H. R. (2016) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.6b00931 · Cited by 31

Tuning the reaction mechanism and hydrogenation/dehydrogenation properties of 6Mg(NH2)29LiH system by adding LiBH4

Gizer, G., Puszkiel, J., Cao, H., Pistidda, C., Le, T. T., Dornheim, M., & Klassen, T. (2019) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2019.03.133 · Cited by 31

Effects of Al-based additives on the hydrogen storage performance of the Mg(NH2)2–2LiH system

Cao, H., Zhang, Y., Wang, J., et al. (2013) · Dalton Transactions · doi:10.1039/c3dt32165g · Cited by 30

Alkali metal – yttrium borohydrides: The link between coordination of small and large rare-earth

Sadikin, Y., Stare, K., Schouwink, P., Ley, M. B., Jensen, T. R., Meden, A., & Černý, R. (2014) · Journal of Solid State Chemistry · doi:10.1016/j.jssc.2014.12.018 · Cited by 30

Investigation on LiBH4-CaH2 composite and its potential for thermal energy storage

Li, Y., Li, P., & Qu, X. (2017) · Scientific Reports · doi:10.1038/srep41754 · Cited by 30

Synthesis and crystal structure analysis of complex hydride Mg(BH4)(NH2)

Noritake, T., Miwa, K., Aoki, M., et al. (2013) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2013.03.072 · Cited by 29

Nano-confined multi-synthesis of a Li–Mg–N–H nanocomposite towards low-temperature hydrogen storage with stable reversibility

Xia, G., Chen, X., Zhou, C., Zhang, C., Li, D., Gu, Q., Guo, Z., Liu, H., Liu, Z., & Yu, X. (2015) · Journal of Materials Chemistry A · doi:10.1039/c5ta00259a · Cited by 29

Changing the dehydrogenation pathway of LiBH 4 –MgH 2 via nanosized lithiated TiO 2

Puszkiel, J., Riglos, M. V. C., Karimi, F., et al. (2017) · Physical Chemistry Chemical Physics · doi:10.1039/c6cp08278e · Cited by 29

Dehydrogenation characteristics of LiAlH 4 improved by in-situ formed catalysts

Cai, J., Zang, L., Zhao, L., et al. (2016) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2016.06.004 · Cited by 28

Destabilization of lithium hydride and the thermodynamic assessment of the Li–Al–H system for solar thermal energy storage

Javadian, P., Sheppard, D. A., Jensen, T. R., et al. (2016) · RSC Advances · doi:10.1039/c6ra16983j · Cited by 27

Synthesis, structure and properties of new bimetallic sodium and potassium lanthanum borohydrides

Payandeh, S., Heere, M., Sørby, M. H., et al. (2016) · Dalton Transactions · doi:10.1039/c6dt03671f · Cited by 27

Influence of transition metals Fe, Co, Ni, Cu and Ti on the dehydrogenation characteristics of LiBH 4 : A first-principles investigation

Huang, Z., Wang, Y., Wang, D., et al. (2018) · Computational and Theoretical Chemistry · doi:10.1016/j.comptc.2018.04.017 · Cited by 26

Facile production of optically active hollow glass microspheres for photo-induced outgassing of stored hydrogen

Shetty, S., & Hall, M. M. (2011) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2011.04.195 · Cited by 25

NH3 Mediated or Ion Migration Reaction: The Case Study on Halide–Amide System

Cao, H., Wang, J., Chua, Y. S., et al. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp411551v · Cited by 25

A thermodynamic investigation of the LiBH 4 –NaBH 4 system

Dematteis, E. M., Roedern, E., Pinatel, E., et al. (2016) · RSC Advances · doi:10.1039/c6ra09301a · Cited by 25

Enhanced hydrogen storage properties of 2LiNH2/MgH2 through the addition of Mg(BH4)2

Qiu, S., Ma, X., Wang, E., et al. (2017) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2017.02.045 · Cited by 25

Halide substitution in Ca(BH 4 ) 2

Grove, H., Rude, L. H., Jensen, T. R., et al. (2013) · RSC Advances · doi:10.1039/c3ra46226a · Cited by 24

Synthesis and thermal stability of perovskite alkali metal strontium borohydrides

Møller, K. T., Ley, M. B., Schouwink, P., et al. (2015) · Dalton Transactions · doi:10.1039/c5dt03590b · Cited by 24

Experimental and Theoretical Analysis of Fast Lithium Ionic Conduction in a LiBH 4 –C 60 Nanocomposite

Teprovich, J. A., Colón-Mercado, H., Ward, P. A., et al. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp503797s · Cited by 24

In‐Situ and Real‐time Monitoring of Mechanochemical Preparation of Li2Mg(NH2BH3)4 and Na2Mg(NH2BH3)4 and Their Thermal Dehydrogenation

Biliškov, N., Borgschulte, A., Užarević, K., et al. (2017) · Chemistry - A European Journal · doi:10.1002/chem.201702665 · Cited by 24

Phase diagrams of the LiBH 4 –NaBH 4 –KBH 4 system

Dematteis, E. M., Pinatel, E., Corno, M., et al. (2017) · Physical Chemistry Chemical Physics · doi:10.1039/c7cp03816j · Cited by 23

Borohydrides: from sheet to framework topologies

Schouwink, P., Ley, M. B., Jensen, T. R., et al. (2014) · Dalton Transactions · doi:10.1039/c4dt00160e · Cited by 22

Immobilization of Aluminum Borohydride Hexammoniate in a Nanoporous Polymer Stabilizer for Enhanced Chemical Hydrogen Storage

Tang, Z., Tan, Y., Chen, X., Ouyang, L., Zhu, M., Sun, D., & Yu, X. (2013) · Angewandte Chemie · doi:10.1002/ange.201306083 · Cited by 21

Li5(BH4)3NH: Lithium-Rich Mixed Anion Complex Hydride

Wołczyk, A. R., Paik, B., Sato, T., et al. (2017) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.7b00821 · Cited by 21

Li2NH‐LiBH4: a Complex Hydride with Near Ambient Hydrogen Adsorption and Fast Lithium Ion Conduction

Wang, H., Cao, H., Zhang, W., et al. (2017) · Chemistry - A European Journal · doi:10.1002/chem.201703910 · Cited by 21

A transition-metal-free hydrogenation catalyst: Pore-confined sodium alanate for the hydrogenation of alkynes and alkenes

Bramwell, P. L., Gao, J., de Waal, B., et al. (2016) · Journal of Catalysis · doi:10.1016/j.jcat.2016.09.024 · Cited by 20

The effect of Sr(OH) 2 on the hydrogen storage properties of the Mg(NH 2 ) 2 –2LiH system

Cao, H., Wang, H., Pistidda, C., et al. (2017) · Physical Chemistry Chemical Physics · doi:10.1039/c7cp00748e · Cited by 20

Investigation of the thermochemical transformations in the LiAlH4–LiNH2 system

Dolotko, O., Kobayashi, T., Wiench, J. W., et al. (2011) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2011.05.163 · Cited by 19

New synthesis route for ternary transition metal amides as well as ultrafast amide–hydride hydrogen storage materials

Cao, H., Santoru, A., Pistidda, C., Richter, T. M. M., Chaudhary, A., Gizer, G., Niewa, R., Chen, P., Klassen, T., & Dornheim, M. (2016) · Chemical Communications · doi:10.1039/c6cc00719h · Cited by 19

Hydrogen generation properties and the hydrolysis mechanism of Zr(BH 4 ) 4 ·8NH 3

Wu, D., Ouyang, L., Liu, J., et al. (2017) · Journal of Materials Chemistry A · doi:10.1039/c7ta04308b · Cited by 19

Achieving High Dehydrogenation Kinetics and Reversibility of LiBH4 by Adding Nanoporous h-BN to Destabilize LiH

Zhu, J., Wang, H., Liu, J., et al. (2018) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.8b07086 · Cited by 19

Lithiated Primary Amine—A New Material for Hydrogen Storage

Chen, J., Wu, H., Wu, G., Xiong, Z., Wang, R., Fan, H., Zhou, W., Liu, B., Chua, Y. S., Ju, X., et al. (2014) · Chemistry - A European Journal · doi:10.1002/chem.201402543 · Cited by 18

Thermal properties and cycling performance of Ca(BH4)2/MgH2 composite for energy storage

Li, Y., Li, P., Tan, Q., et al. (2018) · Chemical Physics Letters · doi:10.1016/j.cplett.2018.04.011 · Cited by 18

Thermodynamics, kinetics and modeling studies of KH- RbH- and CsH-doped 2LiNH2/MgH2 hydrogen storage systems

Hayes, J., & Goudy, A. J. (2015) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2015.07.046 · Cited by 17

Complex transition metal hydrides incorporating ionic hydrogen: thermal decomposition pathway of Na 2 Mg 2 FeH 8 and Na 2 Mg 2 RuH 8

Humphries, T. D., Matsuo, M., Li, G., et al. (2015) · Physical Chemistry Chemical Physics · doi:10.1039/c5cp00258c · Cited by 17

Design and operation of an aluminium alloy tank using doped Na 3 AlH 6 in kg scale for hydrogen storage

Urbanczyk, R., Peinecke, K., Meggouh, M., Minne, P., Peil, S., Bathen, D., & Felderhoff, M. (2016) · Journal of Power Sources · doi:10.1016/j.jpowsour.2016.05.102 · Cited by 17

Synthesis and thermal decomposition of potassium tetraamidoboranealuminate, K[Al(NH2BH3)4]

Møller, K. T., Jo̷rgensen, M., Andreasen, J. G., et al. (2017) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2017.11.080 · Cited by 17

KNH 2 –KH: a metal amide–hydride solid solution

Santoru, A., Pistidda, C., Sørby, M. H., et al. (2016) · Chemical Communications · doi:10.1039/c6cc05777b · Cited by 16

Experimental study on hydrogen storage properties of Li–Mg–N–H based tank

Yan, M. Y., Sun, F., Liu, X. P., et al. (2014) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2014.03.054 · Cited by 15

Synergistic effects of des tabilization, catalysis and nanoconfinement on dehydrogenation of LiBH4

Zhao, Y., Liu, H., Liu, Y., et al. (2016) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2016.03.102 · Cited by 15

Effect of the structural evolution on the ionic conductivity of Li-N-H system during the dehydrogenation

Paik, B., Matsuo, M., Sato, T., et al. (2016) · Applied Physics Letters · doi:10.1063/1.4952601 · Cited by 15

Preparation of Li-Mg-N-H hydrogen storage materials for an auxiliary power unit

Hu, J., Fichtner, M., & Baricco, M. (2017) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2017.06.021 · Cited by 15

Synthesis, Thermal Behavior, and Dehydrogenation Kinetics Study of Lithiated Ethylenediamine

Chen, J., Wu, G., Xiong, Z., et al. (2014) · Chemistry - A European Journal · doi:10.1002/chem.201403047 · Cited by 14

Effects of doping FeCl 3 on hydrogen storage properties of Li-N-H system

Zhang, W., Wang, H., Cao, H., et al. (2017) · Progress in Natural Science Materials International · doi:10.1016/j.pnsc.2016.12.017 · Cited by 14

Effects of Stoichiometry on the H 2 ‐Storage Properties of Mg(NH 2 ) 2 –LiH–LiBH 4 Tri‐Component Systems

Wang, H., Cao, H., Pistidda, C., et al. (2017) · Chemistry - An Asian Journal · doi:10.1002/asia.201700287 · Cited by 14

Insights into the Rb–Mg–N–H System: an Ordered Mixed Amide/Imide Phase and a Disordered Amide/Hydride Solid Solution

Santoru, A., Pistidda, C., Brighi, M., et al. (2018) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.7b03232 · Cited by 14

Destabilization of LiBH4 by SrF2 for reversible hydrogen storage

Zhao, S., Wang, C. Y., Liu, D., et al. (2018) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2018.01.154 · Cited by 14

Effects of graphite content and compaction pressure on hydrogen desorption properties of Mg(NH2)2–2LiH based tank

Yan, M.-Y., Sun, F., Liu, X., et al. (2015) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2014.12.173 · Cited by 13

Ternary Amides Containing Transition Metals for Hydrogen Storage: A Case Study with Alkali Metal Amidozincates

Cao, H., Richter, T. M. M., Pistidda, C., et al. (2015) · ChemSusChem · doi:10.1002/cssc.201500990 · Cited by 13

Kinetic alteration of the 6Mg(NH 2 ) 2 –9LiH–LiBH 4 system by co-adding YCl 3 and Li 3 N

Cao, H., Zhang, W., Pistidda, C., et al. (2017) · Physical Chemistry Chemical Physics · doi:10.1039/c7cp06826c · Cited by 13

Structural prediction, analysis and decomposition mechanism of solid M(NH 2 BH 3 ) n (M = Mg, Ca and Al)

Wang, K., Arcisauskaité, V., Jiao, J.-S., et al. (2014) · RSC Advances · doi:10.1039/c4ra00772g · Cited by 11

Lithium amidoborane hydrazinates: synthesis, structure and hydrogen storage properties

He, T., Wu, H., Wu, G., et al. (2015) · Journal of Materials Chemistry A · doi:10.1039/c5ta00985e · Cited by 11

Lithium imide systems for high temperature heat storage in concentrated solar thermal systems

Nguyen, T. T., Sheppard, D. A., & Buckley, C. E. (2017) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2017.04.208 · Cited by 11

Comparison of the thermochemical and mechanochemical transformations in the 2NaNH 2 –MgH 2 system

Pireddu, G., Valentoni, A., Minella, C. B., et al. (2014) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2014.11.145 · Cited by 10

Hydrogen absorption properties of the slurry system composed of liquid C6H6 and F-treated Mg2Ni

Chen, C., Cai, G., Chen, Y., et al. (2003) · Journal of Alloys and Compounds · doi:10.1016/s0925-8388(02)00967-2 · Cited by 9

Crystal and electronic structures of solid M(NH 2 BH 3 ) n (M = Li, Na, K) and the decomposition mechanisms

Wang, K., Zhang, J., & Zhang, T. (2014) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2014.01.162 · Cited by 8

Dehydrogenation mechanisms of Ca(NH2BH3)2: The less the charge transfer, the lower the barrier

Yuan, P., Wang, F., Sun, Q., et al. (2013) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2013.06.106 · Cited by 8

Synthesis, structure and the dehydrogenation mechanism of calcium amidoborane hydrazinates

Zhao, L., He, T., Wu, G., et al. (2015) · Physical Chemistry Chemical Physics · doi:10.1039/c5cp04257g · Cited by 8

The role of native defects in the transport of charge and mass and the decomposition of Li 4 BN 3 H 10

Hoang, K., Janotti, A., & de Walle, C. G. V. (2014) · Physical Chemistry Chemical Physics · doi:10.1039/c4cp03677h · Cited by 7

Structural, bonding and elastic properties of Mg(NH2BH3)2, Ca(NH2BH3)2 and Sr(NH2BH3)2

Chittari, B. L., & Tewari, S. P. (2014) · Materials Chemistry and Physics · doi:10.1016/j.matchemphys.2014.07.056 · Cited by 6

Production of ammonia via a chemical looping process based on metal imides as nitrogen carriers

Gao, W.-B., Guo, J.-P., Wang, P.-K., Wang, Q.-R., Chang, F., Pei, Q.-J., Zhang, W.-J., Liu, L., & Chen, P. (2018) · Nature Energy · doi:10.1038/s41560-018-0268-z

Technologies and perspectives for achieving carbon neutrality

Wang, F., Harindintwali, J. D., Yuan, Z., Wang, M., Wang, F., Li, S., Yin, Z., Huang, L., Fu, Y., Li, L., et al. (2021) · The Innovation · doi:10.1016/j.xinn.2021.100180 · Cited by 1,330

Untitled work

(2021) · doi:10.3390/en14185917 · Cited by 708

Review on Hydrogen Storage in Mg(BH_4)_2

Chen, P. (2011) · Cailiao kexue yu gongcheng xuebao · Cited by 1

Research on Preparation and Hydrogen Storage Properties of Mg_2Ni Hydrogen Storage Alloys

Xin-zi, X. (2005) · Journal of Chongqing University. English Edition

Mg/MgH2 hydrogen storage system destabilized by recyclable AlH3–NaBH4 composite

Lu, H., Li, J., Xie, T., Chen, Y., Lu, Y., Liu, Z., Li, Q., & Pan, F. (2022) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2022.08.156 · Cited by 38

Using Ball Milling for Modification of the Hydrogenation/Dehydrogenation Process in Magnesium-Based Hydrogen Storage Materials: An Overview

Lyu, J., Lider, A. M., & Kudiiarov, V. N. (2019) · Metals · doi:10.3390/met9070768 · Cited by 82

Effect of Pd Content on the Phase Formation and Hydrogen Storage Properties of Mg-Ni Based Hydrogen Storage Alloy

Sang, G. (2006) · Cailiao daobao