The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Ligand‐Exchange‐Induced Amorphization of Pd Nanomaterials for Highly Efficient Electrocatalytic Hydrogen Evolution Reaction
Open accessAbstract
Various kinds of amorphous materials, such as transition metal dichalcogenides, metal oxides, and metal phosphates, have demonstrated superior electrocatalytic performance compared with their crystalline counterparts. Compared to other materials for electrocatalysis, noble metals exhibit intrinsically high activity and excellent durability. However, it is still very challenging to prepare amorphous noble‐metal nanomaterials due to the strong interatomic metallic bonding. Herein, the discovery of a unique thiol molecule is reported, namely bismuthiol I, which can induce the transformation of Pd nanomaterials from face‐centered‐cubic (fcc) phase into amorphous phase without destroying their integrity. This ligand‐induced amorphization is realized by post‐synthetic ligand exchange under ambient conditions, and is applicable to fcc Pd nanomaterials with different capping ligands. Importantly, the obtained amorphous Pd nanoparticles exhibit remarkably enhanced activity and excellent stability toward electrocatalytic hydrogen evolution in acidic solution. This work provides a facile and effective method for preparing amorphous Pd nanomaterials, and demonstrates their promising electrocatalytic application.
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Cites
Nanostructured hydrotreating catalysts for electrochemical hydrogen evolution
Morales-Guio, C. G., Stern, L.-A., & Hu, X. (2014) · Chemical Society Reviews · doi:10.1039/c3cs60468c · Cited by 2,437
Ni–Mo Nanopowders for Efficient Electrochemical Hydrogen Evolution
McKone, J. R., Sadtler, B. F., Werlang, C. A., Lewis, N. S., & Gray, H. B. (2013) · ACS Catalysis · doi:10.1021/cs300691m · Cited by 798
Deng, Y., Ting, L. R. L., Neo, P. H. L., Zhang, Y.-J., Peterson, A. A., & Yeo, B. S. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b01848 · Cited by 270
Cited by
Descriptors for the Evaluation of Electrocatalytic Reactions: d‐Band Theory and Beyond
Jiao, S., Fu, X., & Huang, H. (2022) · Advanced Functional Materials · doi:10.1002/adfm.202107651 · Cited by 719
Recent Progress of Amorphous Nanomaterials
Kang, J., Yang, X., Hu, Q., Cai, Z., Liu, L.-M., & Guo, L. (2023) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00229 · Cited by 398
Lattice‐Strain Engineering for Heterogenous Electrocatalytic Oxygen Evolution Reaction
Hou, Z., Cui, C., Li, Y., Gao, Y., Zhu, D., Gu, Y., Pan, G., Zhu, Y., & Zhang, T. (2023) · Advanced Materials · doi:10.1002/adma.202209876 · Cited by 365
Do, V., Prabhu, P., Jose, V., Yoshida, T., Zhou, Y., Miwa, H., Kaneko, T., Uruga, T., Iwasawa, Y., & Lee, J. (2023) · Advanced Materials · doi:10.1002/adma.202208860 · Cited by 254
Xie, M., Zhang, B., Jin, Z., Li, P., & Yu, G. (2022) · ACS Nano · doi:10.1021/acsnano.2c05190 · Cited by 167
Metadata
- Authors
- Cheng, H., Yang, N., Liu, G., Ge, Y., Huang, J., Yun, Q., Du, Y., Sun, C., Chen, B., Liu, J., & Zhang, H.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2020-02-06
- Volume
- 32
- Issue
- 11
- Pages
- e1902964-e1902964
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W3004418178
- Cited by
- 245
- References
- 3
- FWCI
- 7.42
- Type
- journal article
- Language
- en
- Open access
- green
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- Cheng, H., Yang, N., Liu, G., Ge, Y., Huang, J., Yun, Q., Du, Y., Sun, C., Chen, B., Liu, J., & Zhang, H. (2020). Ligand‐Exchange‐Induced Amorphization of Pd Nanomaterials for Highly Efficient Electrocatalytic Hydrogen Evolution Reaction. Advanced Materials. https://doi.org/10.1002/adma.201902964
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