The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
Strain Regulation to Optimize the Acidic Water Oxidation Performance of Atomic‐Layer IrOx
Abstract
Strain regulation has become an important strategy to tune the surface chemistry and optimize the catalytic performance of nanocatalysts. Herein, the construction of atomic‐layer IrOx on IrCo nanodendrites with tunable IrO bond length by compressive strain effect for oxygen evolution reaction (OER) in acidic environment is demonstrated. Evidenced from in situ extended X‐ray absorption fine structure, it is shown that the compressive strain of the IrOx layer on the IrCo nanodendrites decreases gradually from 2.51% to the unstrained state with atomic layer growth (from ≈2 to ≈9 atomic layers of IrOx), resulting in the variation of the IrO bond length from shortened 1.94 Å to normal 1.99 Å. The ≈3 atomic‐layer IrOx on IrCo nanodendrites with an IrO bond length of 1.96 Å (1.51% strain) exhibits the optimal OER activity compared to the higher‐strained (2.51%, ≈2 atomic‐layer IrOx) and unstrained (>6 atomic‐layer IrOx) counterparts, with an overpotential of only 247 mV to achieve a current density of 10 mA cm−2. Density functional theory calculations reveal that the precisely tuned compressive strain effect balances the adsorbate–substrate interaction and facilitates the rate‐determining step to form HOO*, thus assuring the best performance of the three atomic‐layer IrOx for OER.
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Cites
Opportunities and challenges for a sustainable energy future
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Self-citationReier, T., Nong, H. N., Teschner, D., Schlögl, R., & Strasser, P. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201601275 · Cited by 1,253
Tuning the activity of Pt alloy electrocatalysts by means of the lanthanide contraction
Escudero-Escribano, M., Malacrida, P., Hansen, M. H., Vej-Hansen, U. G., Velázquez-Palenzuela, A., Tripkovic, V., Schiøtz, J., Rossmeisl, J., Stephens, I. E. L., & Chorkendorff, I. (2016) · Science · doi:10.1126/science.aad8892 · Cited by 1,057
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Li, J., Zhan, G., Yang, J., Quan, F., Mao, C., Liu, Y., Wang, B., Lei, F., Li, L., Chan, A. W. M., et al. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c00418 · Cited by 1,108
Understanding the structure-performance relationship of active sites at atomic scale
Li, R., & Wang, D. (2022) · Nano Research · doi:10.1007/s12274-022-4371-x · Cited by 537
Self-citationZhu, Y., Wang, J., Koketsu, T., Kroschel, M., Chen, J.-M., Hsu, S.-Y., Henkelman, G., Hu, Z., Strasser, P., & Ma, J. (2022) · Nature Communications · doi:10.1038/s41467-022-35426-8 · Cited by 420
Iridium-based nanomaterials for electrochemical water splitting
Chen, Z., Duan, X., Wei, W., Wang, S., & Ni, B.-J. (2020) · Nano Energy · doi:10.1016/j.nanoen.2020.105270 · Cited by 375
Lattice‐Strain Engineering for Heterogenous Electrocatalytic Oxygen Evolution Reaction
Hou, Z., Cui, C., Li, Y., Gao, Y., Zhu, D., Gu, Y., Pan, G., Zhu, Y., & Zhang, T. (2023) · Advanced Materials · doi:10.1002/adma.202209876 · Cited by 365
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Metadata
- Authors
- Meng, G., Sun, W., Mon, A. A., Wu, X., Xia, L., Han, A., Wang, Y., Zhuang, Z., Liu, J., Wang, D., & Li, Y.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2019-08-02
- Volume
- 31
- Issue
- 37
- Pages
- e1903616-e1903616
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2965421281
- Cited by
- 207
- References
- 7
- FWCI
- 4.17
- Type
- journal article
- Language
- en
- Open access
- closed
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- Meng, G., Sun, W., Mon, A. A., Wu, X., Xia, L., Han, A., Wang, Y., Zhuang, Z., Liu, J., Wang, D., & Li, Y. (2019). Strain Regulation to Optimize the Acidic Water Oxidation Performance of Atomic‐Layer IrOx. Advanced Materials. https://doi.org/10.1002/adma.201903616
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