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Strain Regulation to Optimize the Acidic Water Oxidation Performance of Atomic‐Layer IrOx

Meng, Ge, Sun, Wenming, Mon, Aye Aye, Wu, Xuan, Xia, Longyu, Han, Aijuan, Wang, Yu, Zhuang, Zhongbin, Liu, Junfeng, Wang, Dingsheng, Li, Yadong·2019·Advanced Materials

Abstract

Strain regulation has become an important strategy to tune the surface chemistry and optimize the catalytic performance of nanocatalysts. Herein, the construction of atomic‐layer IrOx on IrCo nanodendrites with tunable IrO bond length by compressive strain effect for oxygen evolution reaction (OER) in acidic environment is demonstrated. Evidenced from in situ extended X‐ray absorption fine structure, it is shown that the compressive strain of the IrOx layer on the IrCo nanodendrites decreases gradually from 2.51% to the unstrained state with atomic layer growth (from ≈2 to ≈9 atomic layers of IrOx), resulting in the variation of the IrO bond length from shortened 1.94 Å to normal 1.99 Å. The ≈3 atomic‐layer IrOx on IrCo nanodendrites with an IrO bond length of 1.96 Å (1.51% strain) exhibits the optimal OER activity compared to the higher‐strained (2.51%, ≈2 atomic‐layer IrOx) and unstrained (>6 atomic‐layer IrOx) counterparts, with an overpotential of only 247 mV to achieve a current density of 10 mA cm−2. Density functional theory calculations reveal that the precisely tuned compressive strain effect balances the adsorbate–substrate interaction and facilitates the rate‐determining step to form HOO*, thus assuring the best performance of the three atomic‐layer IrOx for OER.

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Metadata

Authors
Meng, G., Sun, W., Mon, A. A., Wu, X., Xia, L., Han, A., Wang, Y., Zhuang, Z., Liu, J., Wang, D., & Li, Y.
Venue
Advanced Materials
Publisher
Wiley
Published
2019-08-02
Volume
31
Issue
37
Pages
e1903616-e1903616
ISSN
  • 0935-9648 (ISSN-L)
  • 1521-4095
OpenAlex
W2965421281
Cited by
207
References
7
FWCI
4.17
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Strain Regulation to Optimize the Acidic Water Oxidation Performance of Atomic‐Layer IrOx. https://app.cochat.ai/papers/10.1002/adma.201903616
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Meng, G., Sun, W., Mon, A. A., Wu, X., Xia, L., Han, A., Wang, Y., Zhuang, Z., Liu, J., Wang, D., & Li, Y. (2019). Strain Regulation to Optimize the Acidic Water Oxidation Performance of Atomic‐Layer IrOx. Advanced Materials. https://doi.org/10.1002/adma.201903616

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