The DOI matches its Crossref record; 29 of the 29 references it cites were found in a registry or an index.
Subtle Molecular Tailoring Induces Significant Morphology Optimization Enabling over 16% Efficiency Organic Solar Cells with Efficient Charge Generation
Abstract
Manipulating charge generation in a broad spectral region has proved to be crucial for nonfullerene‐electron‐acceptor‐based organic solar cells (OSCs). 16.64% high efficiency binary OSCs are achieved through the use of a novel electron acceptor AQx‐2 with quinoxaline‐containing fused core and PBDB‐TF as donor. The significant increase in photovoltaic performance of AQx‐2 based devices is obtained merely by a subtle tailoring in molecular structure of its analogue AQx‐1. Combining the detailed morphology and transient absorption spectroscopy analyses, a good structure–morphology–property relationship is established. The stronger π–π interaction results in efficient electron hopping and balanced electron and hole mobilities attributed to good charge transport. Moreover, the reduced phase separation morphology of AQx‐2‐based bulk heterojunction blend boosts hole transfer and suppresses geminate recombination. Such success in molecule design and precise morphology optimization may lead to next‐generation high‐performance OSCs.
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Self-citationNon-fullerene acceptors for organic solar cells
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Self-citationFast charge separation in a non-fullerene organic solar cell with a small driving force
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Cited by
Renewed Prospects for Organic Photovoltaics
Zhang, G., Lin, F. R., Qi, F., Heumüller, T., Distler, A., Egelhaaf, H.-J., Li, N., Chow, P. C. Y., Brabec, C. J., Jen, A. K.-Y., et al. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00955 · Cited by 1,052
Recent progress in organic solar cells (Part I material science)
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Advantages, challenges and molecular design of different material types used in organic solar cells
Yi, J., Zhang, G., Yu, H., & Yan, H. (2023) · Nature Reviews Materials · doi:10.1038/s41578-023-00618-1 · Cited by 522
The role of charge recombination to triplet excitons in organic solar cells
Gillett, A. J., Privitera, A., Dilmurat, R., Karki, A., Qian, D., Pershin, A., Londi, G., Myers, W. K., Lee, J., Yuan, J., et al. (2021) · Nature · doi:10.1038/s41586-021-03840-5 · Cited by 450
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Metadata
- Authors
- Zhou, Z., Liu, W., Zhou, G., Zhang, M., Qian, D., Zhang, J., Chen, S., Xu, S., Yang, C., Gao, F., Zhu, H., Liu, F., & Zhu, X.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2019-12-09
- Volume
- 32
- Issue
- 4
- Pages
- e1906324-e1906324
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W2992292845
- Cited by
- 450
- References
- 29
- FWCI
- 22.73
- Type
- journal article
- Language
- en
- Open access
- closed
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- Zhou, Z., Liu, W., Zhou, G., Zhang, M., Qian, D., Zhang, J., Chen, S., Xu, S., Yang, C., Gao, F., Zhu, H., Liu, F., & Zhu, X. (2020). Subtle Molecular Tailoring Induces Significant Morphology Optimization Enabling over 16% Efficiency Organic Solar Cells with Efficient Charge Generation. Advanced Materials. https://doi.org/10.1002/adma.201906324
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