Simultaneous Piezoelectrocatalytic Hydrogen‐Evolution and Degradation of Water Pollutants by Quartz Microrods@Few‐Layered MoS2 Hierarchical Heterostructures
Abstract
Intense light attenuation in water/wastewater results in photocatalysts exhibiting a low quantum efficiency. This study develops a novel piezoelectrocatalysis system, which involves quartz microrods (MRs) abundantly decorated with active‐edge‐site MoS 2 nanosheets to form a quartz microrods@few‐layered MoS 2 hierarchical heterostructure (QMSH). Through theoretical calculations, it is found that the quartz MRs serve as a parallel‐plate capacitor, which is self‐powered to provide an internal electric field to the few‐layered MoS 2 nanosheets surrounding the quartz MR surfaces, and the piezoelectric potential (piezopotential) effectively facilitates redox reactions with the free carriers in MoS 2. The self‐powered quartz MRs in the QMSH present an internal bias to the MoS 2 nanosheets, thus yielding a piezoelectrocatalysis system. An efficient piezoelectrocatalytic hydrogen evolution reaction and decomposition of wastewater without light irradiation can be achieved simultaneously. The second‐order rate constant of the QMSH is ≈0.631 L mg−1 min−1, which is 650‐fold that of quartz MRs, indicating that the piezoelectric heterostructural catalysts display exceptionally high efficiency on piezoelectrocatalytic redox reactions rather than in the piezocatalytic process. The H 2‐production rate of QMSH catalysts approaches ≈6456 µmo1 g−1 h−1 and peaks at ≈16.8 mmol g−1 in 8 h. The piezoelectrocatalytic process may be a promising method for treating industrial wastewater and producing clean energy.
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A review of the REDOX properties of MoS2: From wastewater treatment to tumor therapy
Liang, L.-H., Cao, J.-Z., Huan, J.-L., & Xing, M.-Y. (2024) · Science China Materials · doi:10.1007/s40843-023-2722-y · Cited by 11 · see citing works
“[81] engineered an outstanding graded heterojunction by attaching edge-connected MoS 2 nanosheets onto the surface of quartz microcolumns, demonstrating excellent piezoelectric reduction effects.”
- Authors
- Lin, Y., Lai, S., & Wu, J. M.
- Affiliations
- National Tsing Hua University (TW)
- University of California, Los Angeles (US)
- Corresponding author
- Wu, Jyh Ming
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2020-07-21
- Volume
- 32
- Issue
- 34
- Pages
- e2002875-e2002875
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W3045108158
- Cited by
- 131
- References
- 0
- Citations by year
- 2026: 7 · 2025: 16 · 2024: 27 · 2023: 31 · 2022: 23 · 2021: 26 · 2020: 1
- FWCI
- 4.00
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Advanced Materials (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Advanced Photocatalysis Techniques
- Physical Sciences › Environmental Science › Water Science and Technology › Advanced oxidation water treatment
- Keywords
- hydrogen evolution reaction, MoS2 nanosheets, hierarchical heterostructure, piezopotential, wastewater treatment, pollutant degradation, edge sites, built-in electric field
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