The DOI matches its Crossref record; 39 of the 39 references it cites were found in a registry or an index.
Construction of N, P Co‐Doped Carbon Frames Anchored with Fe Single Atoms and Fe2P Nanoparticles as a Robust Coupling Catalyst for Electrocatalytic Oxygen Reduction
Abstract
A coupling catalyst of highly dispersed N, P co‐doped carbon frames (NPCFs) anchored with Fe single atoms (SAs) and Fe 2 P nanoparticles (NPs) is synthesized by a novel in situ doping–adsorption–phosphatization strategy for the electrocatalytic oxygen reduction reaction (ORR). The optimized Fe SAs‐Fe 2 P NPs/NPCFs‐2.5 catalyst shows a superior ORR activity and stability in 0.5 m H 2 SO 4 and 0.1 m KOH, respectively. Theoretical calculations reveal a synergistic effect, in that the existence of Fe 2 P weakens the adsorption of ORR intermediates on active sites and lowers the reaction free energy. The doped P atoms with a strong electron‐donating ability elevate the energy level of Fe‐3d orbitals and facilitate the adsorption of O 2. The active Fe atoms exist in a low oxidation state and are less positively charged, and they serve as an electron reservoir capable of donating and releasing electrons, thus improving the ORR activity. Operando and in situ characterization results indicate that the atomically dispersed FeN 4/FeP coupled active centers in the Fe SAs‐Fe 2 P NPs/NPCFs‐2.5 catalyst are characteristic of the different catalytic mechanisms in acidic and alkaline media. This work proposes a novel idea for constructing coupling catalysts with atomic‐level precision and provides a strong reference for the development of high‐efficiency ORR electrocatalysts for practical application.
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Self-citationIron Encapsulated within Pod‐like Carbon Nanotubes for Oxygen Reduction Reaction
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Cited by
He, J., He, J., Wu, X., He, B., Su, Z., Ding, W., Ma, X., Li, Z., Cao, Z., Liang, Y., et al. (2026) · Advanced Materials · doi:10.1002/adma.75270
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Metadata
- Authors
- Pan, Y., Ma, X., Wang, M., Yang, X., Liu, S., Chen, H., Zhuang, Z., Zhang, Y., Cheong, W., Zhang, C., Cao, X., Shen, R., Xu, Q., Zhu, W., Liu, Y., Wang, X., Zhang, X., Yan, W., Li, J., Chen, H. M., Chen, C., & Li, Y.
- Venue
- Advanced Materials
- Publisher
- Wiley
- Published
- 2022-06-16
- Volume
- 34
- Issue
- 29
- Pages
- e2203621-e2203621
- ISSN
- 0935-9648 (ISSN-L)
- 1521-4095
- OpenAlex
- W4281389696
- Cited by
- 285
- References
- 39
- FWCI
- 10.17
- Type
- journal article
- Language
- en
- Open access
- closed
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- Pan, Y., Ma, X., Wang, M., Yang, X., Liu, S., Chen, H., Zhuang, Z., Zhang, Y., Cheong, W., Zhang, C., Cao, X., Shen, R., Xu, Q., Zhu, W., Liu, Y., Wang, X., Zhang, X., Yan, W., Li, J., . . . Li, Y. (2022). Construction of N, P Co‐Doped Carbon Frames Anchored with Fe Single Atoms and Fe2P Nanoparticles as a Robust Coupling Catalyst for Electrocatalytic Oxygen Reduction. Advanced Materials. https://doi.org/10.1002/adma.202203621
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