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Cited by 285

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Construction of N, P Co‐Doped Carbon Frames Anchored with Fe Single Atoms and Fe2P Nanoparticles as a Robust Coupling Catalyst for Electrocatalytic Oxygen Reduction

Pan, Yuan, Ma, Xuelu, Wang, Minmin, Yang, Xuan, Liu, Shoujie, Chen, Hsiao‐Chien, Zhuang, Zeweng, Zhang, Yanhui, Cheong, Weng‐Chon, Zhang, Chao, Cao, Xing, Shen, Rongan, Xu, Qian, Zhu, Wei, Liu, Yunqi, Wang, Xingdong, Zhang, Xuejiang, Yan, Wensheng, Li, Jun, Chen, Hao Ming, Chen, Chen, Li, Yadong·2022·Advanced Materials

Abstract

A coupling catalyst of highly dispersed N, P co‐doped carbon frames (NPCFs) anchored with Fe single atoms (SAs) and Fe 2 P nanoparticles (NPs) is synthesized by a novel in situ doping–adsorption–phosphatization strategy for the electrocatalytic oxygen reduction reaction (ORR). The optimized Fe SAs‐Fe 2 P NPs/NPCFs‐2.5 catalyst shows a superior ORR activity and stability in 0.5 m H 2 SO 4 and 0.1 m KOH, respectively. Theoretical calculations reveal a synergistic effect, in that the existence of Fe 2 P weakens the adsorption of ORR intermediates on active sites and lowers the reaction free energy. The doped P atoms with a strong electron‐donating ability elevate the energy level of Fe‐3d orbitals and facilitate the adsorption of O 2. The active Fe atoms exist in a low oxidation state and are less positively charged, and they serve as an electron reservoir capable of donating and releasing electrons, thus improving the ORR activity. Operando and in situ characterization results indicate that the atomically dispersed FeN 4/FeP coupled active centers in the Fe SAs‐Fe 2 P NPs/NPCFs‐2.5 catalyst are characteristic of the different catalytic mechanisms in acidic and alkaline media. This work proposes a novel idea for constructing coupling catalysts with atomic‐level precision and provides a strong reference for the development of high‐efficiency ORR electrocatalysts for practical application.

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Metadata

Authors
Pan, Y., Ma, X., Wang, M., Yang, X., Liu, S., Chen, H., Zhuang, Z., Zhang, Y., Cheong, W., Zhang, C., Cao, X., Shen, R., Xu, Q., Zhu, W., Liu, Y., Wang, X., Zhang, X., Yan, W., Li, J., Chen, H. M., Chen, C., & Li, Y.
Venue
Advanced Materials
Publisher
Wiley
Published
2022-06-16
Volume
34
Issue
29
Pages
e2203621-e2203621
ISSN
  • 0935-9648 (ISSN-L)
  • 1521-4095
OpenAlex
W4281389696
Cited by
285
References
39
FWCI
10.17
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Construction of N, P Co‐Doped Carbon Frames Anchored with Fe Single Atoms and Fe2P Nanoparticles as a Robust Coupling Catalyst for Electrocatalytic Oxygen Reduction. https://app.cochat.ai/papers/10.1002/adma.202203621
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Pan, Y., Ma, X., Wang, M., Yang, X., Liu, S., Chen, H., Zhuang, Z., Zhang, Y., Cheong, W., Zhang, C., Cao, X., Shen, R., Xu, Q., Zhu, W., Liu, Y., Wang, X., Zhang, X., Yan, W., Li, J., . . . Li, Y. (2022). Construction of N, P Co‐Doped Carbon Frames Anchored with Fe Single Atoms and Fe2P Nanoparticles as a Robust Coupling Catalyst for Electrocatalytic Oxygen Reduction. Advanced Materials. https://doi.org/10.1002/adma.202203621

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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