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Phenol and Organic Bases Co‐Catalyzed Chemical Fixation of Carbon Dioxide with Terminal Epoxides to Form Cyclic Carbonates
Abstract
Phenol can efficiently catalyze the reactions of terminal epoxides with carbon dioxide in the presence of catalytic amounts of various organic bases such as 4‐dimethylaminopyridine (DMAP), pyridine, 1,8‐diazabicyclo[5.4.0]undec‐7‐ene, and triethylamine to give the corresponding five‐membered cyclic carbonate in high yields (initial pressure 3.57 MPa; reaction temperature 120 °C). p‐Methoxyphenol with DMAP is the best combination to give the cyclic carbonate in the highest yield.
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Shaikh, A.-A. G., & Sivaram, S. (1996) · Chemical Reviews · doi:10.1021/cr950067i · Cited by 1,381
Cited by
Sustainable conversion of carbon dioxide: the advent of organocatalysis
Fiorani, G., Guo, W., & Kleij, A. W. (2015) · Green Chemistry · doi:10.1039/c4gc01959h · Cited by 658
Alves, M., Grignard, B., Mereau, R., Jerome, C., Tassaing, T., & Detrembleur, C. (2017) · Catalysis Science & Technology · doi:10.1039/c7cy00438a · Cited by 531
Sun, J., Zhang, S., Cheng, W., & Ren, J. (2008) · Tetrahedron Letters · doi:10.1016/j.tetlet.2008.04.022 · Cited by 414
Recent advances in the synthesis of cyclic carbonates via CO2 cycloaddition to epoxides
Rehman, A., Saleem, F., Javed, F., Ikhlaq, A., Ahmad, S. W., & Harvey, A. (2021) · Journal of Environmental Chemical Engineering · doi:10.1016/j.jece.2021.105113 · Cited by 281
Metadata
- Authors
- Shen, Y., Duan, W., & Shi, M.
- Venue
- Advanced Synthesis & Catalysis
- Publisher
- Wiley
- Published
- 2003-03
- Volume
- 345
- Issue
- 3
- Pages
- 337-340
- ISSN
- 1615-4150 (ISSN-L)
- 1615-4169
- OpenAlex
- W2148066976
- Cited by
- 189
- References
- 1
- FWCI
- 7.38
- Type
- journal article
- Language
- en
- Open access
- closed
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- Shen, Y., Duan, W., & Shi, M. (2003). Phenol and Organic Bases Co‐Catalyzed Chemical Fixation of Carbon Dioxide with Terminal Epoxides to Form Cyclic Carbonates. Advanced Synthesis & Catalysis. https://doi.org/10.1002/adsc.200390035
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
