Organocatalyzed coupling of carbon dioxide with epoxides for the synthesis of cyclic carbonates: catalyst design and mechanistic studies
Abstract
The coupling of carbon dioxide (CO 2 ) with epoxides with the formation of cyclic carbonates is a highly attractive 100% atom economic reaction. It represents a greener and safer alternative to the conventional synthesis of cyclic carbonates from diols and toxic phosgene.
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Various useful reduction products such as CO, HCOOH, carboxylic acids, and cyclic carbonates have been successfully obtained through enzymatic and organometallic conversions.
“Various useful reduction products such as CO, HCOOH, carboxylic acids, and cyclic carbonates have been successfully obtained.330, 331, 332, 333”
From Technologies and perspectives for achieving carbon neutrality (2021) · cites this paper as [333]
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Technologies and perspectives for achieving carbon neutrality
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- Authors
- Alves, M., Grignard, B., Mereau, R., Jerome, C., Tassaing, T., & Detrembleur, C.
- Affiliations
- Center for Education and Research on Macromolecules (CERM)
- University of Liège (BE)
- Institut des Sciences Moléculaires
- Centre National de la Recherche Scientifique (FR)
- Corresponding author
- Tassaing, T.
- Detrembleur, C.
- Venue
- Catalysis Science & Technology
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2017
- Volume
- 7
- Issue
- 13
- Pages
- 2651-2684
- ISSN
- 2044-4753 (ISSN-L)
- 2044-4761
- OpenAlex
- W2609333415
- Cited by
- 531
- References
- 248
- Citations by year
- 2026: 26 · 2025: 56 · 2024: 47 · 2023: 61 · 2022: 70 · 2021: 64 · 2020: 82 · 2019: 59 · 2018: 53 · 2017: 13
- FWCI
- 17.47
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Catalysis Science & Technology (publishedVersion)
- HAL (submittedVersion)
- ORBi (University of Liège) (submittedVersion)
- Funders
- Fonds De La Recherche Scientifique - FNRS
- Federaal Wetenschapsbeleid (IAP 7/05 Functional Supramolecular Systems (FS2))
- Topics
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemistry › Organic Chemistry › Asymmetric Synthesis and Catalysis
- Keywords
- carbon dioxide coupling, epoxides, cyclic carbonates, organocatalysis, catalyst design, reaction mechanism, atom economy, phosgene-free synthesis, green chemistry
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