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Borrowing Hydrogen in the Activation of Alcohols
Abstract
Alcohols can be temporarily converted into carbonyl compounds by the metal‐catalysed removal of hydrogen. The carbonyl compounds are reactive in a wider range of transformations than the precursor alcohols and can react in situ to give imines, alkenes, and α‐functionalised carbonyl compounds. The metal catalyst, which had borrowed the hydrogen, then returns it to the transformed carbonyl compound, leading to an overall process in which alcohols can be converted into amines, compounds containing CC bonds and β‐functionalised alcohols.
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Citations
Cited by
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Stratakis, M., & Garcia, H. (2012) · Chemical Reviews · doi:10.1021/cr3000785 · Cited by 803
Alternative Monomers Based on Lignocellulose and Their Use for Polymer Production
Delidovich, I., Hausoul, P. J. C., Deng, L., Pfützenreuter, R., Rose, M., & Palkovits, R. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00354 · Cited by 773
Integration of chemical catalysis with extractive fermentation to produce fuels
Anbarasan, P., Baer, Z. C., Sreekumar, S., Gross, E., Binder, J. B., Blanch, H. W., Clark, D. S., & Toste, F. D. (2012) · Nature · doi:10.1038/nature11594 · Cited by 385
Metadata
- Authors
- Hamid, M. H. S. A., Slatford, P. A., & Williams, J. M. J.
- Venue
- Advanced Synthesis & Catalysis
- Publisher
- Wiley
- Published
- 2007-07-02
- Volume
- 349
- Issue
- 10
- Pages
- 1555-1575
- ISSN
- 1615-4150 (ISSN-L)
- 1615-4169
- OpenAlex
- W2169146772
- Cited by
- 1,136
- References
- 0
- FWCI
- 32.26
- Type
- journal article
- Language
- en
- Open access
- closed
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- Hamid, M. H. S. A., Slatford, P. A., & Williams, J. M. J. (2007). Borrowing Hydrogen in the Activation of Alcohols. Advanced Synthesis & Catalysis. https://doi.org/10.1002/adsc.200600638
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