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Cited by 498

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Oxygen‐Vacancy Abundant Ultrafine Co3O4/Graphene Composites for High‐Rate Supercapacitor Electrodes

Open access
Yang, Shuhua, Liu, Yuanyue, Hao, Yufeng, Yang, Xiaopeng, Goddard, William A., Zhang, Xiao Li, Cao, Bingqiang·2018·Advanced Science

Abstract

The metal oxides/graphene composites are one of the most promising supercapacitors (SCs) electrode materials. However, rational synthesis of such electrode materials with controllable conductivity and electrochemical activity is the topical challenge for high‐performance SCs. Here, the Co 3 O 4/graphene composite is taken as a typical example and develops a novel/universal one‐step laser irradiation method that overcomes all these challenges and obtains the oxygen‐vacancy abundant ultrafine Co 3 O 4 nanoparticles/graphene (UCNG) composites with high SCs performance. First‐principles calculations show that the surface oxygen vacancies can facilitate the electrochemical charge transfer by creating midgap electronic states. The specific capacitance of the UCNG electrode reaches 978.1 F g−1 (135.8 mA h g−1) at the current densities of 1 A g−1 and retains a high capacitance retention of 916.5 F g−1 (127.3 mA h g−1) even at current density up to 10 A g−1, showing remarkable rate capability (more than 93.7% capacitance retention). Additionally, 99.3% of the initial capacitance is maintained after consecutive 20 000 cycles, demonstrating enhanced cycling stability. Moreover, this proposed laser‐assisted growth strategy is demonstrated to be universal for other metal oxide/graphene composites with tuned electrical conductivity and electrochemical activity.

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Metadata

Authors
Yang, S., Liu, Y., Hao, Y., Yang, X., Goddard, W. A., Zhang, X. L., & Cao, B.
Venue
Advanced Science
Publisher
Wiley
Published
2018-01-15
Volume
5
Issue
4
Pages
1700659-1700659
ISSN
2198-3844 (ISSN-L)
OpenAlex
W2783896030
Cited by
498
References
62
FWCI
18.70
Type
journal article
Language
en
Open access
gold

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CoChat. (2026). Citation check: Oxygen‐Vacancy Abundant Ultrafine Co3O4/Graphene Composites for High‐Rate Supercapacitor Electrodes. https://app.cochat.ai/papers/10.1002/advs.201700659
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Yang, S., Liu, Y., Hao, Y., Yang, X., Goddard, W. A., Zhang, X. L., & Cao, B. (2018). Oxygen‐Vacancy Abundant Ultrafine Co3O4/Graphene Composites for High‐Rate Supercapacitor Electrodes. Advanced Science. https://doi.org/10.1002/advs.201700659

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