Cited by 75Advanced Sensor and Energy Harvesting MaterialsFerroelectric and Piezoelectric MaterialsInnovative Energy Harvesting Technologies

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Metal‐Free Perovskite Piezoelectric Nanogenerators for Human–Machine Interfaces and Self‐Powered Electrical Stimulation Applications

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Abstract

Single crystal metal‐free halide perovskites have received great attention in recent years owing to their excellent piezoelectric and ferroelectric properties. However, the nanotoxicity and piezoelectricity within the nanoscale of such materials have yet been reported for the demonstration of practical applications. In this work, the observation of intrinsic piezoelectricity in metal‐free perovskite (MDABCO‐NH 4 I 3 ) films using piezoresponse force microscopy (PFM) is reported. A cytotoxicity test is also performed on MDABCO‐NH 4 I 3 to evaluate its low‐toxic nature. The as‐synthesized MDABCO‐NH 4 I 3 is further integrated into a piezoelectric nanogenerator (PENG). The MDABCO‐NH 4 I 3 ‐based PENG (MN‐PENG) exhibits optimal output voltage and current of 15.9 V and 54.5 nA, respectively. In addition, the MN‐PENG can serve as a self‐powered strain sensor for human–machine interface applications or be adopted in in vitro electrical stimulation devices. This work demonstrates a path of perovskite‐based PENG with high performance, low toxicity, and multifunctionality for future advanced wearable sensors and portable therapeutic systems.

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Metadata

Authors
Wu, H., Wei, S., Chen, S., Pan, H., Pan, W., Huang, S., Tsai, M., & Yang, P.
Affiliations
  • Department of Materials Science and Engineering National Taiwan University of Science and Technology Taipei City 10607 Taiwan
  • National Central University (TW)
  • National Institutes of Applied Research (TW)
  • National Taiwan University of Science and Technology (TW)
Corresponding author
  • Tsai, Meng‐Lin
  • Yang, Po‐Kang
Venue
Advanced Science
Publisher
Wiley
Published
2022-04-20
Volume
9
Issue
18
Pages
e2105974-e2105974
ISSN
2198-3844 (ISSN-L)
OpenAlex
W4224213906
Cited by
75
References
2
Citations by year
2026: 8 · 2025: 13 · 2024: 25 · 2023: 20 · 2022: 9
FWCI
4.87
Type
journal article
Language
en
Open access
Locations
  • Advanced Science (publishedVersion, cc-by)
  • PubMed Central (publishedVersion, cc-by)
  • PubMed (publishedVersion)
  • DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion)
Funders
Ministry of Science and Technology, Taiwan (108‐2636‐E‐038‐003, 109‐2636‐E‐008‐010, 110‐2636‐E‐008‐009, 110‐2221‐E‐011‐076)
Topics
  • Physical Sciences › Engineering › Biomedical Engineering › Advanced Sensor and Energy Harvesting Materials
  • Physical Sciences › Materials Science › Materials Chemistry › Ferroelectric and Piezoelectric Materials
  • Physical Sciences › Engineering › Mechanical Engineering › Innovative Energy Harvesting Technologies
Keywords
metal-free perovskites, halide perovskites, piezoelectric nanogenerators, piezoelectric properties, ferroelectricity, cytotoxicity, human-machine interaction, electrical stimulation, wearable sensors, piezoresponse force microscopy
MeSH terms
Electric Stimulation, Humans, Oxides, Electric Power Supplies, Titanium, Calcium Compounds

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