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Lithium Fast‐Ionic Conduction in Complex Hydrides: Review and Prospects

Matsuo, Motoaki, Orimo, Shin‐ichi·2011·Advanced Energy Materials

Abstract

Complex hydrides exhibit various energy‐related functions such as hydrogen storage, microwave absorption, and neutron shielding. Furthermore, another novel energy‐related function was recently reported by the authors; lithium fast‐ionic conduction, which suggests that complex hydrides may be a potential candidate for solid electrolytes in lithium‐ion batteries. This review presents the recent progress in the development of lithium fast‐ionic conductors of complex hydrides. First, the fast‐ionic conduction in LiBH 4 as a result of clarifying the mechanism of microwave absorption is presented, and then the conceptual development of complex hydrides as a new type of solid‐state lithium fast‐ionic conductors in LiBH 4–, LiNH 2–, and LiAlH 4‐based complex hydrides is discussed. Finally, the future prospects of this study from both application and fundamental viewpoints are described: possible use as solid electrolytes for batteries, formation of ionic liquids in complex hydrides, and similarity between complex hydrides and Laves‐phase metal hydrides.

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Metadata

Authors
Matsuo, M., & Orimo, S.
Venue
Advanced Energy Materials
Publisher
Wiley
Published
2011-01-20
Volume
1
Issue
2
Pages
161-172
ISSN
  • 1614-6832 (ISSN-L)
  • 1614-6840
OpenAlex
W2027815635
Cited by
276
References
43
FWCI
6.68
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Lithium Fast‐Ionic Conduction in Complex Hydrides: Review and Prospects. https://app.cochat.ai/papers/10.1002/aenm.201000012
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Matsuo, M., & Orimo, S. (2011). Lithium Fast‐Ionic Conduction in Complex Hydrides: Review and Prospects. Advanced Energy Materials. https://doi.org/10.1002/aenm.201000012

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