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Rationally Designed Hierarchical TiO2@Fe2O3 Hollow Nanostructures for Improved Lithium Ion Storage

Luo, Jingshan, Xia, Xinhui, Luo, Yongsong, Guan, Cao, Liu, Jilei, Qi, Xiaoying, Ng, Chin Fan, Yu, Ting, Zhang, Hua, Fan, Hong Jin·2013·Advanced Energy Materials

Abstract

Hollow and hierarchical nanostructures have received wide attention in new‐generation, high‐performance, lithium ion battery (LIB) applications. Both TiO 2 and Fe 2 O 3 are under current investigation because of their high structural stability (TiO 2) and high capacity (Fe 2 O 3), and their low cost. Here, we demonstrate a simple strategy for the fabrication of hierarchical hollow TiO 2@Fe 2 O 3 nanostructures for the application as LIB anodes. Using atomic layer deposition (ALD) and sacrificial template‐assisted hydrolysis, the resulting nanostructure combines a large surface area with a hollow interior and robust structure. As a result, such rationally designed LIB anodes exhibit a high reversible capacity (initial value 840 mAh g−1), improved cycle stability (530 mAh g−1 after 200 cycles at the current density of 200 mA g−1), as well as outstanding rate capability. This ALD‐assisted fabrication strategy can be extended to other hierarchical hollow metal oxide nanostructures for favorable applications in electrochemical and optoelectronic devices.

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Metadata

Authors
Luo, J., Xia, X., Luo, Y., Guan, C., Liu, J., Qi, X., Ng, C. F., Yu, T., Zhang, H., & Fan, H. J.
Venue
Advanced Energy Materials
Publisher
Wiley
Published
2013-02-18
Volume
3
Issue
6
Pages
737-743
ISSN
  • 1614-6832 (ISSN-L)
  • 1614-6840
OpenAlex
W2151488581
Cited by
322
References
2
FWCI
25.96
Type
journal article
Language
en
Open access
closed

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Luo, J., Xia, X., Luo, Y., Guan, C., Liu, J., Qi, X., Ng, C. F., Yu, T., Zhang, H., & Fan, H. J. (2013). Rationally Designed Hierarchical TiO2@Fe2O3 Hollow Nanostructures for Improved Lithium Ion Storage. Advanced Energy Materials. https://doi.org/10.1002/aenm.201200953

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