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Lithium/Sulfur Batteries Upon Cycling: Structural Modifications and Species Quantification by In Situ and Operando X‐Ray Diffraction Spectroscopy
Abstract
A quantitative analysis of in situ and operando X-ray diffraction studies allows for deeper insight into the mechanism of Li2S formation and consumption. A two-step reaction process is proposed for both discharge and charge. Changing selectivity for Li2S formation is estimated, with solely Li2S being formed during the earliest step, followed by possible concurrent formation of Li2S2 intermediate in the further step of discharge.
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Citations
Cited by
Zhang, Z., Peng, H., Zhao, M., & Huang, J. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201707536 · Cited by 357
Interface engineering toward stable lithium–sulfur batteries
Guo, Y., Niu, Q., Pei, F., Wang, Q., Zhang, Y., Du, L., Zhang, Y., Zhang, Y., Zhang, Y., Fan, L., et al. (2024) · Energy & Environmental Science · doi:10.1039/d3ee04183b · Cited by 322
Lithium-Sulfur Battery Technology Readiness and Applications—A Review
Fotouhi, A., Auger, D., O’Neill, L., Cleaver, T., & Walus, S. (2017) · Energies · doi:10.3390/en10121937 · Cited by 180
Capacity Recovery Effect in Lithium Sulfur Batteries for Electric Vehicles
Maurer, C., Commerell, W., Hintennach, A., & Jossen, A. (2018) · World Electric Vehicle Journal · doi:10.3390/wevj9020034 · Cited by 9
Metadata
- Authors
- Waluś, S., Barchasz, C., Bouchet, R., Leprêtre, J., Colin, J., Martin, J., Elkaïm, E., Baehtz, C., & Alloin, F.
- Venue
- Advanced Energy Materials
- Publisher
- Wiley
- Published
- 2015-05-15
- Volume
- 5
- Issue
- 16
- ISSN
- 1614-6832 (ISSN-L)
- 1614-6840
- OpenAlex
- W2150746800
- Cited by
- 184
- References
- 0
- FWCI
- 9.78
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Lithium/Sulfur Batteries Upon Cycling: Structural Modifications and Species Quantification by In Situ and Operando X‐Ray Diffraction Spectroscopy. https://app.cochat.ai/papers/10.1002/aenm.201500165
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- Waluś, S., Barchasz, C., Bouchet, R., Leprêtre, J., Colin, J., Martin, J., Elkaïm, E., Baehtz, C., & Alloin, F. (2015). Lithium/Sulfur Batteries Upon Cycling: Structural Modifications and Species Quantification by In Situ and Operando X‐Ray Diffraction Spectroscopy. Advanced Energy Materials. https://doi.org/10.1002/aenm.201500165
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