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Multifunctional 0D–2D Ni2P Nanocrystals–Black Phosphorus Heterostructure

Luo, Zhong‐Zhen, Zhang, Yu, Zhang, Chaohua, Tan, Hui Teng, Li, Zhong, Abutaha, Anas, Wu, Xing‐Long, Xiong, Qihua, Khor, Khiam Aik, Hippalgaonkar, Kedar, Xu, Jianwei, Hng, Huey Hoon, Yan, Qingyu·2017·Advanced Energy Materials

Abstract

0D transition metal phosphides (TMPs) nanocrystals (NCs)–2D ultrathin black phosphorus (BP) heterostructure (Ni 2 P@BP) have been synthesized via a facile sonication‐assisted exfoliation followed by a solvothermal process. Compared with the bare BP, the specially designed Ni 2 P@BP architecture can enhance the electrical conductivity (from 2.12 × 10 2 to 6.25 × 10 4 S m–1), tune the charge carrier concentration (from 1.25 × 10 17 to 1.37 × 10 20 cm–3), and reduce the thermal conductivity (from 44.5 to 7.69 W m–1 K–1) at 300 K, which can be considered for multiple applications. As a result, the Ni 2 P@BP exhibits excellent Li storage properties and high hydrogen evolution reaction electrocatalytic activities. The Ni 2 P@BP shows improved Li diffusion kinetics (e.g., the Li ions diffusion coefficient increases from 1.14 × 10–14 cm 2 s–1 for pure BP nanosheets to 8.02 × 10–13 cm 2 s–1 for Ni 2 P@BP). In addition, the Ni 2 P@BP electrode sustains hydrogen production with almost unchanged activity over 3000 cycles, which indicates its good chemical stability when operating under strong reducing environment.

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Metadata

Authors
Luo, Z., Zhang, Y., Zhang, C., Tan, H. T., Li, Z., Abutaha, A., Wu, X., Xiong, Q., Khor, K. A., Hippalgaonkar, K., Xu, J., Hng, H. H., & Yan, Q.
Venue
Advanced Energy Materials
Publisher
Wiley
Published
2016-10-10
Volume
7
Issue
2
ISSN
  • 1614-6832 (ISSN-L)
  • 1614-6840
OpenAlex
W2531308625
Cited by
175
References
5
FWCI
8.44
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Multifunctional 0D–2D Ni2P Nanocrystals–Black Phosphorus Heterostructure. https://app.cochat.ai/papers/10.1002/aenm.201601285
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Luo, Z., Zhang, Y., Zhang, C., Tan, H. T., Li, Z., Abutaha, A., Wu, X., Xiong, Q., Khor, K. A., Hippalgaonkar, K., Xu, J., Hng, H. H., & Yan, Q. (2017). Multifunctional 0D–2D Ni2P Nanocrystals–Black Phosphorus Heterostructure. Advanced Energy Materials. https://doi.org/10.1002/aenm.201601285

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