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An Efficient and Earth‐Abundant Oxygen‐Evolving Electrocatalyst Based on Amorphous Metal Borides
Open accessAbstract
Cost‐effective and efficient oxygen‐evolving electrocatalysts are urgently required for energy storage and conversion technologies. In this work, an amorphous trimetallic boride nanocatalyst (Fe–Co–2.3Ni–B) prepared by a simple approach is reported as a highly efficient oxygen evolution reaction electrocatalyst. It exhibits an overpotential (η) of 274 mV to deliver a geometric current density (jgeo) of 10 mA cm−2, a small Tafel slope of 38 mV dec−1, and excellent long‐term durability at a mass loading of 0.3 mg cm−2. The impressive electrocatalytic performance originates from the unique amorphous multimetal–metalloid complex nanostructure. From application's point of view, this work holds great promise as this process is simple and allows for large‐scale production of cheap, yet efficient, material.
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Cites
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction
McCrory, C. C. L., Jung, S., Peters, J. C., & Jaramillo, T. F. (2013) · Journal of the American Chemical Society · doi:10.1021/ja407115p · Cited by 7,026
Homogeneously dispersed multimetal oxygen-evolving catalysts
Zhang, B., Zheng, X., Voznyy, O., Comin, R., Bajdich, M., García-Melchor, M., Han, L., Xu, J., Liu, M., Zheng, L., et al. (2016) · Science · doi:10.1126/science.aaf1525 · Cited by 2,447
Developments and perspectives of oxide-based catalysts for the oxygen evolution reaction
Fabbri, E., Habereder, A., Waltar, K., Kötz, R., & Schmidt, T. J. (2014) · Catal. Sci. Technol. · doi:10.1039/c4cy00669k · Cited by 1,303
Masa, J., Weide, P., Peeters, D., Sinev, I., Xia, W., Sun, Z., Somsen, C., Muhler, M., & Schuhmann, W. (2016) · Advanced Energy Materials · doi:10.1002/aenm.201502313 · Cited by 854
Zhang, C., Huang, Y., Yu, Y., Zhang, J., Zhuo, S., & Zhang, B. (2017) · Chemical Science · doi:10.1039/c6sc05687c · Cited by 273
Cited by
Fe-Based Electrocatalysts for Oxygen Evolution Reaction: Progress and Perspectives
Feng, C., Faheem, M. B., Fu, J., Xiao, Y., Li, C., & Li, Y. (2020) · ACS Catalysis · doi:10.1021/acscatal.9b05445 · Cited by 587
Advantageous crystalline–amorphous phase boundary for enhanced electrochemical water oxidation
Han, H., Choi, H., Mhin, S., Hong, Y.-R., Kim, K. M., Kwon, J., Ali, G., Chung, K. Y., Je, M., Umh, H. N., et al. (2019) · Energy & Environmental Science · doi:10.1039/c9ee00950g · Cited by 482
Highly Efficient Oxygen Reduction Reaction Activity of N‐Doped Carbon–Cobalt Boride Heterointerfaces
Jose, V., Nsanzimana, J. M. V., Hu, H., Choi, J., Wang, X., & Lee, J. (2021) · Advanced Energy Materials · doi:10.1002/aenm.202100157 · Cited by 294
Self-citationYuan, H., Wang, S., Ma, Z., Kundu, M., Tang, B., Li, J., & Wang, X. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2020.126474 · Cited by 217
Self-citationChen, Z., Zheng, R., Graś, M., Wei, W., Lota, G., Chen, H., & Ni, B.-J. (2021) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2021.120037 · Cited by 170
Metadata
- Authors
- Nsanzimana, J. M. V., Peng, Y., Xu, Y. Y., Thia, L., Wang, C., Xia, B. Y., & Wang, X.
- Venue
- Advanced Energy Materials
- Publisher
- Wiley
- Published
- 2017-09-04
- Volume
- 8
- Issue
- 1
- ISSN
- 1614-6832 (ISSN-L)
- 1614-6840
- OpenAlex
- W2751087297
- Cited by
- 387
- References
- 5
- FWCI
- 9.89
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Nsanzimana, J. M. V., Peng, Y., Xu, Y. Y., Thia, L., Wang, C., Xia, B. Y., & Wang, X. (2018). An Efficient and Earth‐Abundant Oxygen‐Evolving Electrocatalyst Based on Amorphous Metal Borides. Advanced Energy Materials. https://doi.org/10.1002/aenm.201701475
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