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Cited by 367

The DOI matches its Crossref record; 41 of the 41 references it cites were found in a registry or an index.

NiCoFe‐Layered Double Hydroxides/N‐Doped Graphene Oxide Array Colloid Composite as an Efficient Bifunctional Catalyst for Oxygen Electrocatalytic Reactions

Zhou, Daojin, Cai, Zhao, Lei, Xiaodong, Tian, Weiliang, Bi, Yongmin, Jia, Yin, Han, Nana, Gao, Tengfei, Zhang, Qian, Kuang, Yun, Pan, Junqing, Sun, Xiaoming, Duan, Xue·2018·Advanced Energy Materials

Abstract

Ternary NiCoFe‐layered double hydroxide (NiCo III Fe‐LDH) with Co 3+ is grafted on nitrogen‐doped graphene oxide (N‐GO) by an in situ growth route. The array‐like colloid composite of NiCo III Fe‐LDH/N‐GO is used as a bifunctional catalyst for both oxygen evolution/reduction reactions (OER/ORR). The NiCo III Fe‐LDH/N‐GO array has a 3D open structure with less stacking of LDHs and an enlarged specific surface area. The hierarchical structure design and novel material chemistry endow high activity propelling O 2 redox. By exposing more amounts of Ni and Fe active sites, the NiCo III Fe‐LDH/N‐GO illustrates a relatively low onset potential (1.41 V vs reversible hydrogen electrode) in 0.1 mol L−1 KOH solution under the OER process. Furthermore, by introducing high valence Co 3+, the onset potential of this material in ORR is 0.88 V. The overvoltage difference is 0.769 V between OER and ORR. The key factors for the excellent bifunctional catalytic performance are believed to be the Co with a high valence, the N‐doping of graphene materials, and the highly exposed Ni and Fe active sites in the array‐like colloid composite. This work further demonstrates the possibility to exploit the application potential of LDHs as OER and ORR bifunctional electrochemical catalysts.

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Research works printed but not linked: 10

  1. 10.1007/s00396-016-3922-7 · doi:10.1007/s00396-016-3922-7
  2. 10.1016/j.scriptamat.2008.01.047 · doi:10.1016/j.scriptamat.2008.01.047
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Metadata

Authors
Zhou, D., Cai, Z., Lei, X., Tian, W., Bi, Y., Jia, Y., Han, N., Gao, T., Zhang, Q., Kuang, Y., Pan, J., Sun, X., & Duan, X.
Venue
Advanced Energy Materials
Publisher
Wiley
Published
2017-12-08
Volume
8
Issue
9
ISSN
  • 1614-6832 (ISSN-L)
  • 1614-6840
OpenAlex
W2772953018
Cited by
367
References
41
FWCI
9.39
Type
journal article
Language
en
Open access
closed
Funders
National Natural Science Foundation of China (21676022)

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CoChat. (2026). Citation check: NiCoFe‐Layered Double Hydroxides/N‐Doped Graphene Oxide Array Colloid Composite as an Efficient Bifunctional Catalyst for Oxygen Electrocatalytic Reactions. https://app.cochat.ai/papers/10.1002/aenm.201701905
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Zhou, D., Cai, Z., Lei, X., Tian, W., Bi, Y., Jia, Y., Han, N., Gao, T., Zhang, Q., Kuang, Y., Pan, J., Sun, X., & Duan, X. (2018). NiCoFe‐Layered Double Hydroxides/N‐Doped Graphene Oxide Array Colloid Composite as an Efficient Bifunctional Catalyst for Oxygen Electrocatalytic Reactions. Advanced Energy Materials. https://doi.org/10.1002/aenm.201701905

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