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Cited by 382

The DOI matches its Crossref record; 36 of the 36 references it cites were found in a registry or an index.

Reducing Saturation‐Current Density to Realize High‐Efficiency Low‐Bandgap Mixed Tin–Lead Halide Perovskite Solar Cells

Open access
Li, Chongwen, Song, Zhaoning, Zhao, Dewei, Xiao, Chuanxiao, Subedi, Biwas, Shrestha, Niraj, Junda, Maxwell M., Wang, Changlei, Jiang, Chun‐Sheng, Al‐Jassim, Mowafak, Ellingson, Randy J., Podraza, Nikolas J., Zhu, Kai, Yan, Yanfa·2019·Advanced Energy Materials

Abstract

The unsatisfactory performance of low‐bandgap mixed tin (Sn)–lead (Pb) halide perovskite subcells has been one of the major obstacles hindering the progress of the power conversion efficiencies (PCEs) of all‐perovskite tandem solar cells. By analyzing dark‐current density and distribution, it is identified that charge recombination at grain boundaries is a key factor limiting the performance of low‐bandgap mixed Sn–Pb halide perovskite subcells. It is further found that bromine (Br) incorporation can effectively passivate grain boundaries and lower the dark current density by two–three orders of magnitude. By optimizing the Br concentration, low‐bandgap (1.272 eV) mixed Sn–Pb halide perovskite solar cells are fabricated with open‐circuit voltage deficits as low as 0.384 V and fill factors as high as 75%. The best‐performing device demonstrates a PCE of >19%. The results suggest an important direction for improving the performance of low‐bandgap mixed Sn–Pb halide perovskite solar cells.

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Metadata

Authors
Li, C., Song, Z., Zhao, D., Xiao, C., Subedi, B., Shrestha, N., Junda, M. M., Wang, C., Jiang, C., Al‐Jassim, M., Ellingson, R. J., Podraza, N. J., Zhu, K., & Yan, Y.
Venue
Advanced Energy Materials
Publisher
Wiley
Published
2018-11-27
Volume
9
Issue
3
ISSN
  • 1614-6832 (ISSN-L)
  • 1614-6840
OpenAlex
W2903393784
Cited by
382
References
36
FWCI
14.11
Type
journal article
Language
en
Open access
green

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CoChat. (2026). Citation check: Reducing Saturation‐Current Density to Realize High‐Efficiency Low‐Bandgap Mixed Tin–Lead Halide Perovskite Solar Cells. https://app.cochat.ai/papers/10.1002/aenm.201803135
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Li, C., Song, Z., Zhao, D., Xiao, C., Subedi, B., Shrestha, N., Junda, M. M., Wang, C., Jiang, C., Al‐Jassim, M., Ellingson, R. J., Podraza, N. J., Zhu, K., & Yan, Y. (2019). Reducing Saturation‐Current Density to Realize High‐Efficiency Low‐Bandgap Mixed Tin–Lead Halide Perovskite Solar Cells. Advanced Energy Materials. https://doi.org/10.1002/aenm.201803135

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