The DOI matches its Crossref record; 53 of the 53 references it cites were found in a registry or an index.
Heteroatom‐Doped Mesoporous Hollow Carbon Spheres for Fast Sodium Storage with an Ultralong Cycle Life
Abstract
Carbon materials have attracted significant attention as anode materials for sodium ion batteries (SIBs). Developing a carbon anode with long‐term cycling stability under ultrahigh rate is essential for practical application of SIBs in energy storage systems. Herein, sulfur and nitrogen codoped mesoporous hollow carbon spheres are developed, exhibiting high rate performance of 144 mA h g−1 at 20 A g−1, and excellent cycling durability under ultrahigh current density. Interestingly, during 7000 cycles at a current density of 20 A g−1, the capacity of the electrode gradually increases to 180 mA h g−1. The mechanisms for the superior electrochemical performance and capacity improvement of the cells are studied by electrochemical tests, ex situ transmission electron microscopy, X‐ray diffraction, X‐ray photoelectron spectroscopy, and Raman analysis of fresh and cycled electrodes. The unique and robust structure of the material can enhance transport kinetics of electrons and sodium ions, and maintain fast sodium storage from the capacitive process under high rate. The self‐rearrangement of the carbon structure, induced by continuous discharge and charge, lead to the capacity improvement with cycles. These results demonstrate a new avenue to design advanced anode materials for SIBs.
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Cites
Raman Spectrum of Graphene and Graphene Layers
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Towards greener and more sustainable batteries for electrical energy storage
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Pseudocapacitive Contributions to Electrochemical Energy Storage in TiO2 (Anatase) Nanoparticles
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Cited by
Tang, Y., Cen, Z., Ma, Q., Zheng, B., Cai, Z., Liu, S., & Wu, D. (2023) · Advanced Science · doi:10.1002/advs.202206924 · Cited by 27
Metadata
- Authors
- Ni, D., Sun, W., Wang, Z., Bai, Y., Lei, H., Lai, X., & Sun, K.
- Venue
- Advanced Energy Materials
- Publisher
- Wiley
- Published
- 2019-03-26
- Volume
- 9
- Issue
- 19
- ISSN
- 1614-6832 (ISSN-L)
- 1614-6840
- OpenAlex
- W2924563523
- Cited by
- 298
- References
- 53
- FWCI
- 14.45
- Type
- journal article
- Language
- en
- Open access
- closed
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- Ni, D., Sun, W., Wang, Z., Bai, Y., Lei, H., Lai, X., & Sun, K. (2019). Heteroatom‐Doped Mesoporous Hollow Carbon Spheres for Fast Sodium Storage with an Ultralong Cycle Life. Advanced Energy Materials. https://doi.org/10.1002/aenm.201900036
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