The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Membrane‐Free Zn/MnO2 Flow Battery for Large‐Scale Energy Storage
Open accessAbstract
The traditional Zn/MnO 2 battery has attracted great interest due to its low cost, high safety, high output voltage, and environmental friendliness. However, it remains a big challenge to achieve long‐term stability, mainly owing to the poor reversibility of the cathode reaction. Different from previous studies where the cathode redox reaction of MnO 2/MnOOH is in solid state with limited reversibility, here a new aqueous rechargeable Zn/MnO 2 flow battery is constructed with dissolution–precipitation reactions in both cathodes (Mn 2+/MnO 2) and anodes (Zn 2+/Zn), which allow mixing of anolyte and catholyte into only one electrolyte and remove the requirement for an ion selective membrane for cost reduction. Impressively, this new battery exhibits a high discharge voltage of ≈1.78 V, good rate capability (10C discharge), and excellent cycling stability (1000 cycles without decay) at the areal capacity ranging from 0.5 to 2 mAh cm‐2. More importantly, this battery can be readily enlarged to a bench scale flow cell of 1.2 Ah with good capacity retention of 89.7% at the 500th cycle, displaying great potential for large‐scale energy storage.
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Cites
Opportunities and challenges for a sustainable energy future
Chu, S., & Majumdar, A. (2012) · Nature · doi:10.1038/nature11475 · Cited by 12,550
“Water-in-salt” electrolyte enables high-voltage aqueous lithium-ion chemistries
Suo, L., Borodin, O., Gao, T., Olguin, M., Ho, J., Fan, X., Luo, C., Wang, C., & Xu, K. (2015) · Science · doi:10.1126/science.aab1595 · Cited by 3,821
Cited by
Rechargeable Batteries for Grid Scale Energy Storage
Zhu, Z., Jiang, T., Ali, M., Meng, Y., Jin, Y., Cui, Y., & Chen, W. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00289 · Cited by 1,769
Self-citationDesign of a Solid Electrolyte Interphase for Aqueous Zn Batteries
Li, D., Cao, L., Deng, T., Liu, S., & Wang, C. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202103390 · Cited by 466
Historical development and novel concepts on electrolytes for aqueous rechargeable batteries
Chen, S., Zhang, M., Zou, P., Sun, B., & Tao, S. (2022) · Energy & Environmental Science · doi:10.1039/d2ee00004k · Cited by 308
Metadata
- Authors
- Li, G., Chen, W., Zhang, H., Gong, Y., Shi, F., Wang, J., Zhang, R., Chen, G., Jin, Y., Wu, T., Tang, Z., & Cui, Y.
- Venue
- Advanced Energy Materials
- Publisher
- Wiley
- Published
- 2020-01-31
- Volume
- 10
- Issue
- 9
- ISSN
- 1614-6832 (ISSN-L)
- 1614-6840
- OpenAlex
- W3003941775
- Cited by
- 184
- References
- 2
- FWCI
- 9.54
- Type
- journal article
- Language
- en
- Open access
- green
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- Li, G., Chen, W., Zhang, H., Gong, Y., Shi, F., Wang, J., Zhang, R., Chen, G., Jin, Y., Wu, T., Tang, Z., & Cui, Y. (2020). Membrane‐Free Zn/MnO2 Flow Battery for Large‐Scale Energy Storage. Advanced Energy Materials. https://doi.org/10.1002/aenm.201902085
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